Version и revision date :  5 07.10.2013.         Remplaced:  15.09.2011.        

S a f e t y     D a t a     S h e e t

в соответствии с Regulation (EC) 1907/2006

1.      Определение the соединен./mixture и the company/undertaking

1.1  Product identifier

Название:

Ацетон

Synonym:

2-Propanone, ß-Ketopropane, Dimethylketone, Pyroacetic Эфир

CAS: [67-64-1]

REACH Registration Number: 01-2119471330-49-XXXX

1.2  Relevant identified uses вещества или mixture:

Production вещества.

Distribution Соединен..

Mixing, preparation и repackaging.

Use как laboratory chemicals.

Use в coatings.

Use как binders и release agents.

Production и processing Резина.

Manufacture polymers.

Polymer processing.

Blowing agents.

Mining chemicals.

Agrochemical use.

De-icing и anti-icing применение.

1.3  Определение the company или firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

2.    Виды опасного воздействия

2.1  Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

Классификация (67/548/CEE или 1999/45/CE).

2.2  Label элементы:

Hazard Pictograms

Signal word

 Danger

  Hazard statements

H225  Легко воспламеняем жидкость и vapour.

H319  Causes serious eye irritation.

EUH066  Repeated exposure may cause skin dryness или cracking.

H336  May cause drowsiness или dizziness.

  Precautionary statements

P210  Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233  Keep container tightly closed.

P241  Use explosion-proof electrical/ventilating/lighting/equipment.

P303+P361+P353  IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с вода/shower.

P304+P340  IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P501  Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

For the full text the R-выражения mentioned в this section, see section 16.

2.3  Др. hazards:

No further relevant information available.

3.       Состав/information on ingredients

Название: Ацетон

Формула: CH3COCH3        M.=  58,08    CAS [67-64-1]

Номер ЕС (EINECS): 200-662-2

ЕС индекс: 606-001-00-8

REACH Registration Number: 01-2119471330-49-XXXX

4.       Первая помощь measures

4.1  General indications:

Never provide drink или Вызвать рвоту в the event loss consciousness.

4.2  Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed immediately до provide artificial respiration. Seek immediate medical assistance.

4.3  Contact с the skin:

Wash с plenty soap и вода. Remove contaminated clothing.

4.4  Глаза:

Промыть большим количеством воды, keeping eyelids open. Обратиться за медицинской помощью.

4.5  Попадание Внутрь:

Немедленно промыть ротовую полость. Drink large amounts вода. Do not Вызвать рвоту. Seek immediate medical assistance.

· Most важно symptoms и effects, both acute и delayed:

See Section 11 for more information.

· Indication any immediate medical attention и special treatment needed:

No further relevant information available.

5.      Firefighting measures

5.1  Suitable extinguishing среда:

Спирт resistant пена. Песок.

5.2  Unsuitable extinguishing среда:

Running вода. 

5.3  Special hazards arising from the соединен. или mixture:

Горючее Вещество. Keep away from sources ignition.  The fumes are heavier than air, so they may spreaD при floor level.  Auf Rückzündung achten  Существует риск воспламенения из-за образования электростатических разрядов.  В случае возгорания могут образовываться токсичные пары: CO y CO2. 

5.4  Advice for firefighters:

Use complete Средства индивидуальной защиты. Self-contained breathing equipment. Cool the recipients с водой.

6.       Accidental release measures

6.1  Personal precautions, Средства индивидуальной защиты и emergency procedures:

Не вдыхать пары. Protect the respiratory tracts. Обеспечить хорошую вентиляцию Use personal protective equipment как required. Evacuate all non-essential personnel. Avoid sources ignition. Do not smoke.

6.2  Environmental precautions:

Do not allow it до enter the drainage system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3  Methods и material for containment и cleaning up:

Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода.

7.       Правила обращения и хранения

7.1 Precautions for safe обращение:

Avoid the formation electrostatic charges. Ensure good ventilation и renewal the air в the premises. Possible formation pressure inside the container. Avoid breathing dust, fume, gas, mist, vapours или spray. Avoid Контакт с кожей, глаза или clothing. Use personal Средства индивидуальной защиты как required.

7.2 Conditions for safe хранение, including any incompatibilities:

В запечатанных контейнерах. В хорошо проветриваемом помещении. Вдали от источников возгорания и тепла. Restricted access, only authorized до technicians.

Recommended хранение temperature: Room temperature.

· Хранение class: 3

Technical instructions (air): Легко воспламеняем.

7.3 Specific end use(s):

No further relevant information available.

8.       Exposure controls/personal protection

8.1  Exposure controls:

Ensure good ventilation и renewal the air в the premises.

8.2 Control parameters:

VLA-ED: 500 ppm = 1.210 мг/м3 

ECTLV: 500 ppm = 1.210 мг/м3 

Derived No Effect Level (DNEL)

Workers Dermal, long exposure (local):   186mg/kg bw/24h

Workers Inhalation, acute (local): 2.420 мг/м3 

Workers Inhalation, long term (local): 1.210 мг/м3 

Population, oral, long term (systemic):   62mg/kg bw/24h

Population, Dermal, long exposure (systemic):   62mg/kg bw/24h

Population Inhalation, long term (systemic): 200 мг/м3 

Predicted No Effect Концентрация (PNEC)

Marine вода:   1,06mg/l

Freshwater:   10,6mg/l

Freshwater Sediment:   30,4mg/l

Marine вода Sediment:   3,04mg/l

Soil:   0,112mg/l

Sewage treatment plant:   29,5mg/l

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр AX. Фильтр P3.

8.4 Защита рук:

The glove material has до be impermeable и resistant до the product/ the соединен./ the preparation.

Selection the glove material on consideration the penetration times, rates diffusion и the degradation

· Material gloves

The selection the suitable gloves does not only depend on the material, but also on further marks quality и varies from manufacturer до manufacturer.

· Penetration time glove material

The exact break through time has до be found out by the manufacturer the protective gloves и has до be

observed.

· For the permanent contact gloves made the following materials are suitable:

Material: Butyl резина. Recommended thickness the material: >= 0,7 mm Breakthrough time: >= 480 min.

· Как protection from splashes gloves made the following materials are suitable:

Material: Natural резина latex. Recommended thickness the material: >= 0,7 mm Breakthrough time: >= 10 min.

8.5 Eye/face protection:

Use safety glasses.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use suitable work clothing. Wash hands before breaks и when the job is done.

8.7 Контроль воздействия на окружающую среду:

Avoid pollution the soil, вода supplies и drains.

9.      Physical и chemical properties

Внешний Вид: жидкость

Цвета:

N/A

Granulometry: N/A

Запах: Характерный.

pH:  

N/A

точка плавления/Температура замерзания: -94 °C

Initial Точка кипения и Интервал температур кипения: 56,5 °C 

Точка воспламенения:  - 20 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 12,8 %(V) / 2,2 %(V)

Давление пара: 233 hPa  (20 °C)

Vapour плотность: N/A

Relative плотность:

Insertar Aquí Grupo de repeticion

 (20/4) 0,791 g/ml

Растворимость:  в вода (   )  (   )   Смешивается с водой и most the solvents

Partition coefficient: н-октанол/вода:

N/A

Auto-ignition temperature:  465 °C

Decomposition temperature:  N/A

Кинематич. вязк.:  N/A

Динамич. вязк.: 0,31 mPa.s (25 °C)

10.  Стабильность и реакционноспособность

10.1  Conditions до avoid: 

Высокий temperatures.  

10.2   Incompatible materials:

Strong Окислители.

10.3  Hazardous decomposition products:

 No specific data.

10.4  Chemical stability:

Exposure до light и air encourages the formation пероксиды.  The gases/fumes can form explosive mixtures с the air. 

11.  Токсикологическая информация

11.1          Acute toxicity:

LD50 oral rat  :  5.800 мг/кг      

11.2          Dangerous effects for health:

Skin corrosion/irritation: irritations, slight Serious eye damage/irritation: Strongly irritant в rabbits. Respiratory или skin sensitisation: Нет данных. Germ кювета mutagenicity: No evidence. Carcinogenicity: Нет данных. Reproductive toxicity: Conclusions are lacking regarding evaluation a damaging effect on the foetus. STOT- single exposure: narcosis STOT-repeated exposure: Нет данных. Aspiration hazard: Нет данных.

·Most важно symptoms и effects acute: Irritations до the skin и глаза., Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract., drowsiness, vertigo, тошнота, рвота, headaches, effects on the central nervous system, Upon Контакт с кожей:, Can de-moisturize и dehydrate it, producing irritation и dermatitis.

12.  Информация по окружающей среде

12.1  Toxicity:

Acute toxicity for Algae: 

(Ulva pertusa) EC50 20,565 mg/l (96h)

Acute toxicity for aquatic invertebrates: 

(Gammarus pulex) LC50 6000000 ug/l (48h)

(Daphnia magna) LC50 10000 ug/l (48h)

Acute toxicity for рыбы: 

(Pimephales Promelas) LC50 >100000 ug/l (96h)

Chronic toxicity for aquatic invertebrates: 

(Daphnia magna) NOEC 0,1 mg/l (21d)

12.2  Persistence и Период Распада :

Легко biodegradable product.

12.3  Bioaccumulative potential:

Low

12.4  Мобильность в soil :

Product has a low potential for adsorption.

12.5 Assessment PBT и MPMB :

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria for PBT (persistent / bioaccumulative / токсично).

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria vPvB (very persistent / very bioaccumulative).

12.6  Др. adverse effects:

Environmental risks cannot be excluded if used и/или disposed inappropriately.

12.7 General notes:

· Вода hazard class:

(German Regulation) (Assessment by list):

1  слабо опасная доза for вода.

(Dutch Regulation):

10 May cause long-term adverse effects в the aquatic environment.

13. Disposal considerations

13.1  Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

 В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2  Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste.

.

14.  Transport information

Автотранспорт (ADR):

Техническое название: ACETONE

UN   1090       Класс: 3      Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: ACETONE

UN   1090       Класс: 3      Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Ацетон

UN   1090       Класс: 3       Группа: II

Инструкция по упаковке:    CAO 364     PAX 353

15.  Regulatory information

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

For this product a chemical safety assessment was carried out.

16.  Дополнительная информация

  Др. precautionary statements

P235  Keep cool.

Labelling (65/548/CEE или 1999/45/CE)

Version и revision date : 5 07.10.2013

Remplaced: 15.09.2011

В respect the previous review, changes have been made до the following sections: 1,2,4,5,6,7,8,10,11,12,15

The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed.