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Version and revision date :  5 07.10.2013.         Remplaced:  15.09.2011.        

 

 

S a f e t y     D a t a     S h e e t

According to Regulation (EC) 1907/2006

 

1007  Acetone 

 

1.      Identification of the substance/mixture and of the company/undertaking

1.1  Product identifier

Name:

Acetone

 

Synonym:

2-Propanone, ß-Ketopropane, Dimethylketone, Pyroacetic Ether

 

CAS: [67-64-1]

 

REACH Registration Number: 01-2119471330-49-XXXX

 

1.2  Relevant identified uses of the substance or mixture:

 

Production of the substance.

Distribution of Substance.

Mixing, preparation and repackaging.

Use as laboratory chemicals.

Use in coatings.

Use as binders and release agents.

Production and processing of Rubber.

Manufacture of polymers.

Polymer processing.

Blowing agents.

Mining chemicals.

Agrochemical use.

De-icing and anti-icing applications.

 

1.3  Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Identification of dangers

2.1  Classification of the substance or the mixture.

 

 

 

Classification Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

 

 

Classification (67/548/CEE or 1999/45/CE).

 

F   Highly flammable

Xi   Irritant

 

R11

R36

R66

R67

 

2.2  Label elements:

 

Hazard Pictograms

 

 

Signal word

 Danger

     

 

  Hazard statements

H225  Highly flammable liquid and vapour.

H319  Causes serious eye irritation.

EUH066  Repeated exposure may cause skin dryness or cracking.

H336  May cause drowsiness or dizziness.

 

 

  Precautionary statements

P210  Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233  Keep container tightly closed.

P241  Use explosion-proof electrical/ventilating/lighting/equipment.

P303+P361+P353  IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340  IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P501  Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

 

 

 

 

For the full text of the R-phrases mentioned in this section, see section 16.

2.3  Other hazards:

 

No further relevant information available.

 

 

3.       Composition/information on ingredients

 

 

Name: Acetone

Formula: CH3COCH3        M.=  58,08    CAS [67-64-1]

EC number (EINECS): 200-662-2

EC index number: 606-001-00-8

REACH Registration Number: 01-2119471330-49-XXXX

 

 

4.       First aid measures

 

4.1  General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

 

4.2  Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

 

Version и revision date :  5 07.10.2013.         Remplaced:  15.09.2011.        

 

 

S a f e t y     D a t a     S h e e t

в соответствии с Regulation (EC) 1907/2006

 

1007  Ацетон 

 

1.      Определение the соединен./mixture и the company/undertaking

1.1  Product identifier

Название:

Ацетон

 

Synonym:

2-Propanone, ß-Ketopropane, Dimethylketone, Pyroacetic Эфир

 

CAS: [67-64-1]

 

REACH Registration Number: 01-2119471330-49-XXXX

 

1.2  Relevant identified uses вещества или mixture:

 

Production вещества.

Distribution Соединен..

Mixing, preparation и repackaging.

Use как laboratory chemicals.

Use в coatings.

Use как binders и release agents.

Production и processing Резина.

Manufacture polymers.

Polymer processing.

Blowing agents.

Mining chemicals.

Agrochemical use.

De-icing и anti-icing применение.

 

1.3  Определение the company или firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Виды опасного воздействия

2.1  Классификация вещества или the mixture.

 

 

 

Классификация Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

 

 

Классификация (67/548/CEE или 1999/45/CE).

 

F   Легко воспламеняем

Xi   Irritant

 

R11

R36

R66

R67

 

2.2  Label элементы:

 

Hazard Pictograms

 

 

Signal word

 Danger

     

 

  Hazard statements

H225  Легко воспламеняем жидкость и vapour.

H319  Causes serious eye irritation.

EUH066  Repeated exposure may cause skin dryness или cracking.

H336  May cause drowsiness или dizziness.

 

 

  Precautionary statements

P210  Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233  Keep container tightly closed.

P241  Use explosion-proof electrical/ventilating/lighting/equipment.

P303+P361+P353  IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с вода/shower.

P304+P340  IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P501  Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

 

 

 

 

For the full text the R-выражения mentioned в this section, see section 16.

2.3  Др. hazards:

 

No further relevant information available.

 

 

3.       Состав/information on ingredients

 

 

Название: Ацетон

Формула: CH3COCH3        M.=  58,08    CAS [67-64-1]

Номер ЕС (EINECS): 200-662-2

ЕС индекс: 606-001-00-8

REACH Registration Number: 01-2119471330-49-XXXX

 

 

4.       Первая помощь measures

 

4.1  General indications:

Never provide drink или Вызвать рвоту в the event loss consciousness.

 

4.2  Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed immediately до provide artificial respiration. Seek immediate medical assistance.

 

4.3  Contact с the skin:

Wash с plenty soap и вода. Remove contaminated clothing.

 

4.4  Глаза:

Промыть большим количеством воды, keeping eyelids open. Обратиться за медицинской помощью.

 

4.5  Попадание Внутрь:

Немедленно промыть ротовую полость. Drink large amounts вода. Do not Вызвать рвоту. Seek immediate medical assistance.

· Most важно symptoms и effects, both acute и delayed:

See Section 11 for more information.

· Indication any immediate medical attention и special treatment needed:

No further relevant information available.

 

5.      Firefighting measures

 

5.1  Suitable extinguishing среда:

Спирт resistant пена. Песок.

 

5.2  Unsuitable extinguishing среда:

Running вода. 

 

5.3  Special hazards arising from the соединен. или mixture:

Горючее Вещество. Keep away from sources ignition.  The fumes are heavier than air, so they may spreaD при floor level.  Auf Rückzündung achten  Существует риск воспламенения из-за образования электростатических разрядов.  В случае возгорания могут образовываться токсичные пары: CO y CO2. 

 

5.4  Advice for firefighters:

Use complete Средства индивидуальной защиты. Self-contained breathing equipment. Cool the recipients с водой.

 

6.       Accidental release measures

 

6.1  Personal precautions, Средства индивидуальной защиты и emergency procedures:

Не вдыхать пары. Protect the respiratory tracts. Обеспечить хорошую вентиляцию Use personal protective equipment как required. Evacuate all non-essential personnel. Avoid sources ignition. Do not smoke.

 

6.2  Environmental precautions:

Do not allow it до enter the drainage system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

 

6.3  Methods и material for containment и cleaning up:

Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода.

 

7.       Правила обращения и хранения

 

7.1 Precautions for safe обращение:

Avoid the formation electrostatic charges. Ensure good ventilation и renewal the air в the premises. Possible formation pressure inside the container. Avoid breathing dust, fume, gas, mist, vapours или spray. Avoid Контакт с кожей, глаза или clothing. Use personal Средства индивидуальной защиты как required.

 

7.2 Conditions for safe хранение, including any incompatibilities:

В запечатанных контейнерах. В хорошо проветриваемом помещении. Вдали от источников возгорания и тепла. Restricted access, only authorized до technicians.

Recommended хранение temperature: Room temperature.

· Хранение class: 3

Technical instructions (air): Легко воспламеняем.

7.3 Specific end use(s):

No further relevant information available.

 

8.       Exposure controls/personal protection

 

8.1  Exposure controls:

Ensure good ventilation и renewal the air в the premises.

 

8.2 Control parameters:

VLA-ED: 500 ppm = 1.210 мг/м3 

ECTLV: 500 ppm = 1.210 мг/м3 

 

Derived No Effect Level (DNEL)

  

Workers Dermal, long exposure (local):   186mg/kg bw/24h

Workers Inhalation, acute (local): 2.420 мг/м3 

Workers Inhalation, long term (local): 1.210 мг/м3 

Population, oral, long term (systemic):   62mg/kg bw/24h

Population, Dermal, long exposure (systemic):   62mg/kg bw/24h

Population Inhalation, long term (systemic): 200 мг/м3 

 

Predicted No Effect Концентрация (PNEC)

  

Marine вода:   1,06mg/l

Freshwater:   10,6mg/l

Freshwater Sediment:   30,4mg/l

Marine вода Sediment:   3,04mg/l

Soil:   0,112mg/l

Sewage treatment plant:   29,5mg/l

 

 

 

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр AX. Фильтр P3.

 

8.4 Защита рук:

The glove material has до be impermeable и resistant до the product/ the соединен./ the preparation.

Selection the glove material on consideration the penetration times, rates diffusion и the degradation

· Material gloves

The selection the suitable gloves does not only depend on the material, but also on further marks quality и varies from manufacturer до manufacturer.

· Penetration time glove material

The exact break through time has до be found out by the manufacturer the protective gloves и has до be

observed.

· For the permanent contact gloves made the following materials are suitable:

Material: Butyl резина. Recommended thickness the material: >= 0,7 mm Breakthrough time: >= 480 min.

· Как protection from splashes gloves made the following materials are suitable:

Material: Natural резина latex. Recommended thickness the material: >= 0,7 mm Breakthrough time: >= 10 min.

 

8.5 Eye/face protection:

Use safety glasses.

 

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use suitable work clothing. Wash hands before breaks и when the job is done.

 

8.7 Контроль воздействия на окружающую среду:

Avoid pollution the soil, вода supplies и drains.

 

9.      Physical и chemical properties

 

Внешний Вид: жидкость

Цвета:

N/A

Granulometry: N/A

Запах: Характерный.

pH:  

N/A

точка плавления/Температура замерзания: -94 °C

Initial Точка кипения и Интервал температур кипения: 56,5 °C 

Точка воспламенения:  - 20 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 12,8 %(V) / 2,2 %(V)

Давление пара: 233 hPa  (20 °C)

Vapour плотность: N/A

Relative плотность:

 

Insertar Aquí Grupo de repeticion

 

 (20/4) 0,791 g/ml

Растворимость:  в вода (   )  (   )   Смешивается с водой и most the solvents

Partition coefficient: н-октанол/вода:

N/A

Auto-ignition temperature:  465 °C

Decomposition temperature:  N/A

Кинематич. вязк.:  N/A

Динамич. вязк.: 0,31 mPa.s (25 °C)

10.  Стабильность и реакционноспособность

 

10.1  Conditions до avoid: 

Высокий temperatures.  

 

10.2   Incompatible materials:

Strong Окислители.

 

10.3  Hazardous decomposition products:

 No specific data.

 

10.4  Chemical stability:

Exposure до light и air encourages the formation пероксиды.  The gases/fumes can form explosive mixtures с the air. 

 

11.  Токсикологическая информация

 

11.1          Acute toxicity:

LD50 oral rat  :  5.800 мг/кг      

 

11.2          Dangerous effects for health:

Skin corrosion/irritation: irritations, slight Serious eye damage/irritation: Strongly irritant в rabbits. Respiratory или skin sensitisation: Нет данных. Germ кювета mutagenicity: No evidence. Carcinogenicity: Нет данных. Reproductive toxicity: Conclusions are lacking regarding evaluation a damaging effect on the foetus. STOT- single exposure: narcosis STOT-repeated exposure: Нет данных. Aspiration hazard: Нет данных.

·Most важно symptoms и effects acute: Irritations до the skin и глаза., Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract., drowsiness, vertigo, тошнота, рвота, headaches, effects on the central nervous system, Upon Контакт с кожей:, Can de-moisturize и dehydrate it, producing irritation и dermatitis.

 

12.  Информация по окружающей среде

 

12.1  Toxicity:

Acute toxicity for Algae: 

(Ulva pertusa) EC50 20,565 mg/l (96h)

Acute toxicity for aquatic invertebrates: 

(Gammarus pulex) LC50 6000000 ug/l (48h)

(Daphnia magna) LC50 10000 ug/l (48h)

Acute toxicity for рыбы: 

(Pimephales Promelas) LC50 >100000 ug/l (96h)

Chronic toxicity for aquatic invertebrates: 

(Daphnia magna) NOEC 0,1 mg/l (21d)

 

12.2  Persistence и Период Распада :

Легко biodegradable product.

 

12.3  Bioaccumulative potential:

Low

 

12.4  Мобильность в soil :

Product has a low potential for adsorption.

 

12.5 Assessment PBT и MPMB :

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria for PBT (persistent / bioaccumulative / токсично).

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria vPvB (very persistent / very bioaccumulative).

 

 

12.6  Др. adverse effects:

Environmental risks cannot be excluded if used и/или disposed inappropriately.

 

12.7 General notes:

 

· Вода hazard class:

 

(German Regulation) (Assessment by list):

1  слабо опасная доза for вода.

 

(Dutch Regulation):

10 May cause long-term adverse effects в the aquatic environment.

 

 

13. Disposal considerations

 

13.1  Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

 В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste.

.

 

13.2  Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste.

.

 

14.  Transport information

 

Автотранспорт (ADR):

Техническое название: ACETONE

UN   1090       Класс: 3      Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: ACETONE

UN   1090       Класс: 3      Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Ацетон

UN   1090       Класс: 3       Группа: II

Инструкция по упаковке:    CAO 364     PAX 353

15.  Regulatory information

 

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

For this product a chemical safety assessment was carried out.

 

 

16.  Дополнительная информация

 

  Др. precautionary statements

P235  Keep cool.

 

 

Labelling (65/548/CEE или 1999/45/CE)

 

R-phrase(s):

R11   Highly воспламеняем.

R36   Irritating до глаза.

R66   Repeated exposure may cause skin dryness или cracking.

R67   Vapours may cause drowsiness и dizziness.

 

S-phrase(s):

S9   Keep container в a well-ventilated place.

S16   Keep away from sources ignition - Не курить.

S26   В case contact с глаза, rinse immediately с plenty вода и seek medical advice.

S46   If swallowed, seek medical advice immediately и show this container или lable.

 

 

Version и revision date : 5 07.10.2013

Remplaced: 15.09.2011

В respect the previous review, changes have been made до the following sections: 1,2,4,5,6,7,8,10,11,12,15

The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed.

 

 

 

 




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