S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
2376 Phenylhydrazine
Identification of the substance/preparation and of the company or firm | ||||
1.1 Identification of the substance or preparation Name: Phenylhydrazine
Synonym:
REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: | ||||
For laboratory utilisation, analysis, research and fine chemistry.
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008.
Carc. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 STOT RE 1 Muta. 2 Aquatic Acute 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H400 Very toxic to aquatic life.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Classification (67/548/CEE or 1999/45/CE).
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For the full text of the R-phrases mentioned in this section, see section 16. | ||||
Component Composition/Information | ||||
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Name: Phenylhydrazine Formula: C6H8N2 M.= 108,14 CAS [100-63-0] EC number (EINECS): 202-873-5 EC index number: 612-023-00-9 | ||||
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First aid
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4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water (for at least 15 minutes), keeping eyelids open.
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4.5 Swallowing: Drink large amounts of water. Induce vomiting. Administer a solution of medical-usage active charcoal. Seek immediate medical assistance.
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Fire-fighting means
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5.1 Suitable fire-extinguishing means: Dry powder. Carbon dioxide (CO2). Foam.
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5.2 Fire-fighting means which must NOT be used: No specific data.
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5.3 Special risks: Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. In the event of fire, toxic fumes may form: NOx.
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5.4 Protective equipment: Suitable clothing and footwear.
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: Do not inhale the fumes.
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6.2 Precautions for care of the environment: Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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Handling and storage
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7.1 Handling: No special indications.
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7.2 Storage: Well sealed containers.In well ventilated premises.Room temperature.Restricted access, only authorized to technicians.Away from sources of ignition and heat.
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Staff exposure/protection controls
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8.1 Technical protective measures: No special indications.
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8.2 Exposure limit control: TLV-TWA: 0,1 ppm - 0,44 mg/m3 dermal resorption VLA-ED: 0,1 ppm - 0,45 mg/m3 dermal resorption
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8.3 Respiratory protection: In the event of fumes forming/aerosols, use suitable respiratory protection. Filter A. Filter P3.
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8.4 Hand protection: Use suitable gloves
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done. Do not eat, drink or smoke in the workplace.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | ||||
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Physical and chemical properties
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Appearance: liquid | ||||
Colour: N/A | ||||
Granulometry: N/A | ||||
Odour: Characteristic. | ||||
pH: 8 | ||||
Melting point/freezing point: 19,5 °C | ||||
Initial boiling point and boiling range: 243,5 °C | ||||
Flash point: 89 °C | ||||
Flammability (solid, gas): N/A | ||||
Upper/lower flammability or explosive limits: / 1,1 %(V) | ||||
Vapour pressure: 10 hPa (100 °C) | ||||
Vapour density: N/A | ||||
Relative density: (20/4) 1,099 | ||||
Solubility: in Very slightly soluble in water. | ||||
Partition coefficient: n-octanol/water: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: above243 °C | ||||
Viscosity: N/A | ||||
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Stability and reactivity
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10.1 Conditions which should be avoided: High temperatures.
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10.2 Matter which should be avoided: Strong oxidant agents. Metal oxides. Air Halogenated hydrocarbons. Sulphides.
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10.3 Hazardous decomposition products: Nitrous fumes.
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10.4 Complementary information: The gases/fumes can form explosive mixtures with the air.
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Toxicological information
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LD L0 oral mus : 175 mg/kg LD50 oral rbt : 80 mg/kg LD50 oral rat : 188 mg/kg LD50 ipr mus : 170 mg/kg
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If inhaled: coughing breathing difficulties Irritations to the mucosae and respiratory tracts. Upon contact with the skin: irritations Risk of cutaneous absorption. Risk of sensitization allergic reaction Through contact with the eyes: irritations If swallowed: Can cause hypotension metahemoglobinemia with headaches spasms breathing difficulties cyanosis Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
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12.1 Toxicity: 12.1.1 - EC50 test (mg/l): Bacteria (Photobacterium phosphoreum) 73 mg/l Classification: Extr. toxic Crustaceans (Daphnia magna) 5 mg/l Classification: Extr. toxic Fish (B.serio) 0,25 mg/l Classification: Extr. toxic 12.1.2. - Receptor medium: Risk for the water environment Risk for the land environment 12.1.3. - Observations: Bactericide effect. Generally toxic for water organisms.
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12.2 Persistence and Degradability : 12.2.1 - Test: 12.2.2. - Biotic degradation classification: BOD5/COD Biodegradability 12.2.3. - Abiotic degradation depending on pH: 12.2.4. - Observations: Data not available.
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12.3 Bioaccumulative potential: 12.3.1. - Test: 12.3.2. - Bioaccumulation: Risk 12.3.3. - Observations: Data not available.
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12.4 Mobility in soil : Repartition: log P(oct)= 1,9
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12.5 Assessment PBT and MPMB : Data not available.
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12.6 Other possible effects on the environment: Do not allow it to enter soils or water channels.
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Considerations regarding elimination
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13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
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Overland (ADR): Technical name: PHENYLHYDRAZINE UN 2572 Class: 6.1 PELIG.M.AMB Packaging group: II (D/E) | ||||
By sea (IMDG): Technical name: PHENYLHYDRAZINE UN 2572 Class: 6.1 PELIG.M.AMB Packaging group: II | ||||
By air (ICAI-IATA): Technical name: Phenylhydrazine UN 2572 Class: 6.1 PELIG.M.AMB Packaging group: II | ||||
Packaging instructions: CAO 662 PAX 654 | ||||
Regulatory information
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This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
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Other information
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Other precautionary statements P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Labelling (65/548/CEE or 1999/45/CE) | ||||
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Review number and date: 4 15.09.2011 Date published: 15.09.2011 In respect of the previous review, changes have been made to the following sections: 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
2376 Phenylhydrazine
Определение вещества/preparation и the company или firm | ||||
1.1 Определение вещества или preparation Название: Phenylhydrazine
Synonym:
REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use вещества/preparation: | ||||
Для общелабораторного использования, анализов, исследований и тонкой химии.
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1.3 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
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Классификация вещества или the mixture.
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Классификация Regulation (CE) nº 1272/2008.
Carc. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 STOT RE 1 Muta. 2 Aquatic Acute 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H350 May cause cancer <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H331 Токсично if inhaled. H311 Токсично в contact с skin. H301 Токсично При попадании внутрь. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H400 Очень токсично до aquatic life.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация (67/548/CEE или 1999/45/CE).
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For the full text the R-выражения mentioned в this section, see section 16. | ||||
Сведения о компонентах и состав | ||||
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Название: Phenylhydrazine Формула: C6H8N2 M.= 108,14 CAS [100-63-0] Номер ЕС (EINECS): 202-873-5 ЕС индекс: 612-023-00-9 | ||||
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Первая помощь
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4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми.
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. Administer a раствор medical-usage активн. уголь. Обратиться немедленно за медицинской помощью.
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Меры и средства обеспечения пожаро- и взрывобезопасности
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5.1 Пригодные средства пожаротушения: Песок. Углекислый газ (CO2). Пена.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used: No specific data.
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5.3 Особая опасность: Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. В случае возгорания могут образовываться токсичные пары: NOx.
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5.4 Средства индивидуальной защиты: Специальная одежда и обувь.
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
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6.1 Индивидуальные меры предосторожности: Не вдыхать пары.
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6.2 Меры по защите окружающей среды: Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.
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Правила обращения и хранения
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7.1 Обращение: Специальные указания отсутствуют.
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7.2 Хранение: В запечатанных контейнерах.В хорошо проветриваемом помещении.Room temperature.Ограничить право доступа к веществу, предоставив его только специалистам.Вдали от источников возгорания и тепла.
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Требования по охране труда и меры по обеспечению безопасности персонала
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8.1 Технические меры защиты: Специальные указания отсутствуют.
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8.2 Контроль предельно допустимого уровня воздействия: TLV-TWA: 0,1 ppm - 0,44 мг/м3 dermal resorption VLA-ED: 0,1 ppm - 0,45 мг/м3 dermal resorption
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A. Фильтр P3.
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8.4 Защита рук: Использовать защитные перчатки
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8.5 Защита глаз: Использовать защитные очки.
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы. Do not eat, drink или smoke в the workplace.
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8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | ||||
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Физико-химические свойства
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Внешний Вид: жидкость | ||||
Цвета: N/A | ||||
Granulometry: N/A | ||||
Запах: Характерный. | ||||
pH: 8 | ||||
точка плавления/Температура замерзания: 19,5 °C | ||||
Initial Точка кипения и Интервал температур кипения: 243,5 °C | ||||
Точка воспламенения: 89 °C | ||||
Flammability (solid, gas): N/A | ||||
Верхний/нижний flammability или explosive показатели: / 1,1 %(V) | ||||
Давление пара: 10 hPa (100 °C) | ||||
Vapour плотность: N/A | ||||
Relative плотность: (20/4) 1,099 | ||||
Растворимость: в Very слабо растворяется в воде. | ||||
Partition coefficient: n-октанол/вода: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: above243 °C | ||||
Вязк.: N/A | ||||
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Стабильность и реакционноспособность
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10.1 Условия, которых следует избегать: Высокий temperatures.
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10.2 Вещества, которых следует избегать: Strong Окислители. Металл oxides. Air Halogenated углеводороды. Sulphides.
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10.3 Опасные продукты разложения: Nitrous fumes.
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10.4 Общая информация: The gases/fumes can form explosive mixtures с the air.
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Токсикологическая информация
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LD L0 oral mus : 175 мг/кг LD50 oral rbt : 80 мг/кг LD50 oral rat : 188 мг/кг LD50 ipr mus : 170 мг/кг
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If inhaled: coughing затруднение дыхания Irritations до the mucosae и respiratory tracts. Upon Контакт с кожей: irritations Cуществует риск попадания в кровоток через кожные покровы. Риск sensitization allergic reaction Контакт с глазами: irritations При попадании внутрь: Can cause hypotension metahemoglobinemia с headaches spasms затруднение дыхания cyanosis Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
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Информация по окружающей среде
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12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): Бактерии (Photobacterium phosphoreum) 73 mg/l Классификация: Extr. токсично Crustaceans (Daphnia magna) 5 mg/l Классификация: Extr. токсично Рыбы (B.serio) 0,25 mg/l Классификация: Extr. токсично 12.1.2. - Воздействие на окружающую среду: Риск для водной среды Риск для земли 12.1.3. - Наблюдения: Bactericide effect. Generally токсично for вода organisms.
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12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Классификация биотического периода распада: BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от рН: 12.2.4. - Наблюдения: Нет данных.
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения: Нет данных.
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12.4 Мобильность в soil : Repartition: log P(oct)= 1,9
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12.5 Assessment PBT и MPMB : Нет данных.
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12.6 Другие возможные воздействия на окружающую среду: Избегать попаданию вещества в почву и воду.
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Правила утилизации
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13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
.
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13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
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Информация относительно транспорта
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Автотранспорт (ADR): Техническое название: PHENYLHYDRAZINE UN 2572 Класс: 6.1 PELIG.M.AMB Группа: II (D/E) | ||||
Морской транспорт (IMDG): Техническое название: PHENYLHYDRAZINE UN 2572 Класс: 6.1 PELIG.M.AMB Группа: II | ||||
Авиа транспорт (ICAI-IATA): Техническое название: Phenylhydrazine UN 2572 Класс: 6.1 PELIG.M.AMB Группа: II | ||||
Инструкция по упаковке: CAO 662 PAX 654 | ||||
Regulatory information
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This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.
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Дополнительная информация
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Др. precautionary statements P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P272 Contaminated work clothing should not be allowed out the workplace. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal Средства индивидуальной защиты как required. P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P308+P313 IF exposed или concerned: Get medical advice/attention. P311 Call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P362 Take off contaminated clothing и wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Labelling (65/548/CEE или 1999/45/CE) | ||||
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Номер рецензии и дата: 4 15.09.2011 Date published: 15.09.2011 Относительно предыдущего обзора изменения были произведены в следующих разделах: 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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