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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

5650 Silan-Sterol-1

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Silan-Sterol-1

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

Skin Irrit. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

F Highly flammable

R36/38

R20/21/22

R11

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Silan-Sterol-1

Composition:

0001: Hexamethyldisilazane

Formula: (CH3)3SiNHSi(CH3)3 M.= 161,41 CAS [999-97-3]

EC number (EINECS): 213-668-5

Content: <= 25 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

F Highly flammable

R36/37/38 Irritating to eyes, respiratory system and skin.

RE20/21/22 Also harmful by inhalation, in contact with skin and if swallowed.

R11 Highly flammable.

0002: Pyridine

Formula: C5H5N M.= 79,10 CAS [110-86-1]

EC number (EINECS): 203-809-9

EC index number: 613-002-00-7

REACH Registration Number: 01-2119493105-40-XXXX

Content: >= 25 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H302 Harmful if swallowed.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P322 Specific measures (see on this label).

P330 Rinse mouth.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

F Highly flammable

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R11 Highly flammable.

0003: Chlorotrimethylsilane

Formula: (CH3)3SiCl M.= 108,64 CAS [75-77-4]

EC number (EINECS): 200-900-5

Content: >= 5 % <= 10 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Skin Corr. 1A

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

EUH014 Reacts violently with water.

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

F Highly flammable

R37 Irritating to respiratory system.

R35 Causes severe burns.

R14 Reacts violently with water.

R11 Highly flammable.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed to provide artificial respiration.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Avoid vomiting. Risk of aspiration. Seek medical assistance. Avoid stomach lavage. Do not drink milk.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air. Risk of inflammation due to accumulation of electrostatic charges. In the event of fire, toxic fumes may form: NOx.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.In well ventilated premises.Away from sources of ignition and heat.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter A. Filter P.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour:

N/A

Granulometry: N/A

Odour: Unpleasant, characteristic.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility:

N/A

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Nitric acid. Anhydrides. Fluorine. Halogen halides. Chromates. Perchromates. Nitrogen oxides. Sulphur oxides.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

Hygroscopic. The gases/fumes can form explosive mixtures with the air.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 891 mg/kg

LD50 skn rbt : 1.121 mg/kg

LC L0 inh rat : 4000 ppm (V) 4h

  • Dangerous effects for health:

Upon contact with the skin: Irritations to the skin and mucosae. If swallowed: nausea vomiting headaches anxiety insomnia In high concentrations: cardiovascular disorders collapse narcosis Risk of cutaneous absorption. Chronic effects hepatic problems kidney problems Easily detectable due to its characteristic unpleasant smell, tolerable at low levels.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 2120 mg/l

Classification:

Very toxic

Algae (M. aeruginosa) EC0 28

Classification:

Extr. toxic

Algae (Sc. cuadricauda) EC0 120

Classification: Highly toxic

Crustaceans (Daphnia magna) 240 mg/l

Classification: Highly toxic

Fish (Leuciscus Idus) 225 mg/l

Classification: Highly toxic

Protozoa (E. sulcatum) EC0 240

Classification: Highly toxic

12.1.2. - Receptor medium: Risk for the water environment

Medium Risk for the land environment

Low 12.1.3. - Observations:

Ecotoxicity in line with the dumping concentration. Low chronic ecotoxicity.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Product with a low bioaccumulative potential.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Pollutant product.

Do not allow it to enter soils or water channels.

Risk of formation of explosive fumes on the surface of the water.

DATA BASED on the components of the preparation.

(Major component:

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: FLAMMABLE LIQUID, N.O.S.

UN 1993 Class: 3 Packaging group: II (D/E)

By sea (IMDG):

Technical name: FLAMMABLE LIQUID, N.O.S.

UN 1993 Class: 3 Packaging group: II

By air (ICAI-IATA):

Technical name: Flammable liquid, n.o.s.

UN 1993 Class: 3 Packaging group: II

Packaging instructions: CAO 364 PAX 353

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R36/38 Irritating to eyes and skin.

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R11 Highly flammable.

S-phrase(s):

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S28a After contact with skin, wash immediately with plenty of water.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

5650 Silan-Sterol-1

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Silan-Sterol-1

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

Skin Irrit. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H332 Вредный if inhaled.

H312 Вредный в contact с skin.

H302 Вредный При попадании внутрь.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

F Легко воспламеняем

R36/38

R20/21/22

R11

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Silan-Sterol-1

Состав:

0001: Hexamethyldisilazane

Формула: (CH3)3SiNHSi(CH3)3 M.= 161,41 CAS [999-97-3]

Номер ЕС (EINECS): 213-668-5

Content: <= 25 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H332 Вредный if inhaled.

H312 Вредный в contact с skin.

H302 Вредный При попадании внутрь.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

F Легко воспламеняем

R36/37/38 Вызывает раздражение глаз, respiratory system и skin.

RE20/21/22 Also Избегать контактов с кожей. Вреден при вдыхании и при употреблении во внутрь.

R11 Легко воспламеняем.

0002: Пиридин

Формула: C5H5N M.= 79,10 CAS [110-86-1]

Номер ЕС (EINECS): 203-809-9

ЕС индекс: 613-002-00-7

REACH Registration Number: 01-2119493105-40-XXXX

Content: >= 25 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H332 Вредный if inhaled.

H312 Вредный в contact с skin.

H302 Вредный При попадании внутрь.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P322 Specific measures (see on this label).

P330 Rinse mouth.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P235 Store в a well-ventilated place. Keep cool.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

F Легко воспламеняем

R20/21/22 Избегать контактов с кожей. Вреден при вдыхании и при употреблении во внутрь.

R11 Легко воспламеняем.

0003: Хлортриметилсилан

Формула: (CH3)3SiCl M.= 108,64 CAS [75-77-4]

Номер ЕС (EINECS): 200-900-5

Content: >= 5 % <= 10 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Skin Corr. 1A

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

EUH014 Reacts violently с водой.

H314 Causes severe skin ожоги и eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

F Легко воспламеняем

R37 Irritating до respiratory system.

R35 Causes severe ожоги.

R14 Reacts violently с водой.

R11 Легко воспламеняем.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed до provide artificial respiration.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Avoid рвота. Риск aspiration. Обратиться за медицинской помощью. Avoid stomach lavage. Do not drink milk.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом. Существует риск воспламенения из-за образования электростатических разрядов. В случае возгорания могут образовываться токсичные пары: NOx.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

: Нет данных.

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A. Фильтр P.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета:

N/A

Granulometry: N/A

Запах: Unpleasant, характерный.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость:

N/A

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Азотная кислота. Anhydrides. Fluorine. Halogen галиды. Chromates. Perchromates. оксиды азота. Sulphur oxides.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

Гигроскопичный. The gases/fumes can form explosive mixtures с the air.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 891 мг/кг

LD50 skn rbt : 1.121 мг/кг

LC L0 inh rat : 4000 ppm (V) 4h

  • Опасное воздействие на здоровье:

Upon Контакт с кожей: Irritations до the skin и mucosae. При попадании внутрь: тошнота рвота headaches anxiety insomnia В высокий concentrations: cardiovascular disorders collapse narcosis Cуществует риск попадания в кровоток через кожные покровы. Chronic effects hepatic problems kidney problems Легко detectable due до its характерный unpleasant smell, tolerable при low levels.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 2120 mg/l

Классификация:

Очень токсично

Algae (M. aeruginosa) EC0 28

Классификация:

Extr. токсично

Algae (Sc. cuadricauda) EC0 120

Классификация: Highly токсично

Crustaceans (Daphnia magna) 240 mg/l

Классификация: Highly токсично

Рыбы (Leuciscus Idus) 225 mg/l

Классификация: Highly токсично

Protozoa (E. sulcatum) EC0 240

Классификация: Highly токсично

12.1.2. - Воздействие на окружающую среду: Риск для водной среды

Средний Риск для земли

Low 12.1.3. - Наблюдения:

Экотоксичность в line с the dumping концентрация. Low chronic экотоксичность.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Product с a low bioaccumulative potential.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Продукт загрязнения.

Избегать попаданию вещества в почву и воду.

Риск formation explosive fumes on the surface the вода.

DATA BASED on the components the preparation.

(Major component:

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: FLAMMABLE LIQUID, N.O.S.

UN 1993 Класс: 3 Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: FLAMMABLE LIQUID, N.O.S.

UN 1993 Класс: 3 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Воспламеняем жидкость, n.o.s.

UN 1993 Класс: 3 Группа: II

Инструкция по упаковке: CAO 364 PAX 353

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P235 Store в a well-ventilated place. Keep cool.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R36/38 Вызывает раздражение глаз и skin.

R20/21/22 Избегать контактов с кожей. Вреден при вдыхании и при употреблении во внутрь.

R11 Легко воспламеняем.

S-phrase(s):

S36/37/39 Wear suitable protective clothing, gloves и eye/face protection.

S28a После contact с skin, wash immediately с plenty вода.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Date published: 3.11.10

Номер рецензии и дата: 3 3.11.10




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