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Version and revision date : 4 08.07.2013. Remplaced: 03.11.2010.

S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

6462 Histofix ® Preservative ready to use

Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Name:

Histofix ® Preservative ready to use

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Relevant identified uses of the substance or mixture:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Carc. 2

Skin Sens. 1

Hazard Pictograms

Signal word

Warning

Hazard statements

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H317 May cause an allergic skin reaction.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P261 Avoid breathing dust, fume, gas, mist, vapours or spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves, protective clothing, eye protection or face protection.

P281 Use personal protective equipment as required.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

R43

R40

For the full text of the R-phrases mentioned in this section, see section 16.

Composition/information on ingredients

Name: Histofix ® Preservative ready to use

Composition:

0001: Methanol

Formula: CH3OH M.= 32,04 CAS [67-56-1]

EC number (EINECS): 200-659-6

EC index number: 603-001-00-X

REACH Registration Number: 01-2119433307-44-XXXX

Content: <= 3 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H370 Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust, fume, gas, mist, vapours or spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves, protective clothing, eye protection or face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

F Highly flammable

T Toxic

R11 Highly flammable.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

0002: Formaldehyde 30-40% *stabilized with methanol

Formula: CH2O M.= 30,03 CAS [50-00-0]

EC number (EINECS): 200-001-8

EC index number: 605-001-00-5

REACH Registration Number: 01-2119488953-20-XXXX

Content: >= 3,7 % <= 4 %

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Skin Corr. 1B

Carc. 2

Skin Sens. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H331 Toxic if inhaled.

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves, protective clothing, eye protection or face protection.

P281 Use personal protective equipment as required.

P202 Do not handle until all safety precautions have been read and understood.

P201 Obtain special instructions before use.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P261 Avoid breathing dust, fume, gas, mist, vapours or spray.

P264 Wash...thoroughly after handling.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

T Toxic

R43 May cause sensitisation by skin contact.

R40 Limited evidence of a carcinogenic effect.

R34 Causes burns.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

First aid measures

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Firefighting measures

5.1 Suitable extinguishing media:

Dry powder. Foam. Carbon dioxide (CO2). Water.

5.2 Unsuitable extinguishing media:

No specific data.

5.3 Special hazards arising from the substance or mixture:

Combustible. Keep away from sources of ignition.

5.4 Advice for firefighters:

Suitable clothing and footwear.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Do not inhale the fumes.

6.2 Environmental precautions:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods and material for containment and cleaning up:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water. Neutralize with excess sodium bisulphite solution.

Handling and storage

7.1 Precautions for safe handling:

No special indications.

7.2 Conditions for safe storage, including any incompatibilities:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Room temperature.Restricted access, only authorized to technicians.Do not store in metal containers.

Exposure controls/personal protection

8.1 Exposure controls:

Ensure good ventilation and renewal of the air in the premises.

8.2 Control parameters:

VLA-EC(Formaldehyde): 0,37 mg/m3 ,

VLA-EC(Formaldehyde): 0,3 ppm ,

MAK (Formaldehyde) 0,5 ml/m3; 0,6 mg/m3(methanol) 200 ml/m3; 260 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter B. Filter P3.

8.4 Hand protection:

Use suitable gloves

8.5 Eye/face protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use complete protective equipment. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Piquant.

pH: 6,8 - 7,2

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 1,019

Solubility: in ( )Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Kinematic viscosity:N/A

Dynamic viscosity:

N/A

Stability and reactivity

10.1 Conditions to avoid:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Incompatible materials:

Polymerization initiators. Alkaline metals. Acids. Nitrogen oxides. Hydrogen peroxide. Oxidant agents. Performic acid.

10.3 Hazardous decomposition products:

No specific data.

10.4 Chemical stability:

No specific data.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 100 mg/kg referred to the pure substance

LD50 skn rbt : 270 mg/kg referred to the pure substance

LC50 inh rat : 203 mg/m3

  • Dangerous effects for health:

Taking the preparation' components into account, the likely dangerous characteristics are as follows: If fumes inhaled: Irritations to the respiratory tracts. Upon contact with the skin: irritations May cause allergic reaction Through contact with the eyes: irritations If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

- EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 8,5 mg/l

Classification:

Extr. toxic (CH2O 30-40%)

Bacteria (Ps. putida) EC0 14 mg/l

Classification: Extr. toxic

(CH2O 30-40%)

Algae (M. aeruginosa) EC0 0,4 mg/l

Classification: Extr. toxic

(CH2O 30-40%)

Crustaceans (Daphnia magna) 42 mg/l

Classification: Extr. toxic

Fish (Salmo gairdneri) 214 mg/l

Classification:

Highly toxic (CH2O 30-40%)

- Receptor medium:

Risk for the water environment High

Risk for the land environment High

- Observations:

Extremely toxic.

Inhibits active sludges.

Bactericide effect. Generally toxic for water organisms.

Protoplasmatic toxic.

12.2 Persistence and Degradability :

- Test:

- Biotic degradation classification:

DOC 1,06 g/g(CH2O 30-40%)

BOD5/COD Biodegradability =

ThOD 1,068 g/g(CH2O 30-40%)

High, over 1/3

- Abiotic degradation depending on pH:

BOD5 0,728 g/g(CH2O 30-40%)

- Observations:

Biodegradable product.

12.3 Bioaccumulative potential:

Non-bioaccumulable product.

12.4 Mobility in soil :

Repartition: log P(oct)= 0,00 (CH2O 30-40%)

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other adverse effects:

Corrosive product, even in diluted form.

Do not allow it to enter soils or water channels.

Disposal considerations

13.1 Waste treatment methods:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Transport information

Not classified as dangerous in the meaning of transport regulations.

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R40 Limited evidence of a carcinogenic effect.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Version and revision date : 4 08.07.2013

Remplaced: 03.11.2010

In respect of the previous review, changes have been made to the following sections: 3

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

Version и revision date : 4 08.07.2013. Remplaced: 03.11.2010.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

6462 Histofix ® Preservative ready до use

Определение вещества/mixture и the company/undertaking

1.1 Product identifier

Название:

Histofix ® Preservative ready до use

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Relevant identified uses вещества или mixture:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Carc. 2

Skin Sens. 1

Hazard Pictograms

Signal word

Warning

Hazard statements

H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>.

H317 May cause an allergic skin reaction.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P261 Avoid breathing dust, fume, gas, mist, vapours или spray.

P272 Contaminated work clothing should not be allowed out the workplace.

P280 Wear protective gloves, protective clothing, Защита глаз или face protection.

P281 Use personal Средства индивидуальной защиты как required.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

R43

R40

For the full text the R-выражения mentioned в this section, see section 16.

Состав/information on ingredients

Название: Histofix ® Preservative ready до use

Состав:

0001: Метанол

Формула: CH3OH M.= 32,04 CAS [67-56-1]

Номер ЕС (EINECS): 200-659-6

ЕС индекс: 603-001-00-X

REACH Registration Number: 01-2119433307-44-XXXX

Content: <= 3 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H370 Causes damage до organs <или state all organs affected, if known> <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust, fume, gas, mist, vapours или spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves, protective clothing, Защита глаз или face protection.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

F Легко воспламеняем

T Токсично

R11 Легко воспламеняем.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

R39/23/24/25 Токсично: danger very serious irreversible effects through inhalation, в contact с skin и При попадании внутрь.

0002: Формальдегид 30-40% *стабилизированный метанолом

Формула: CH2O M.= 30,03 CAS [50-00-0]

Номер ЕС (EINECS): 200-001-8

ЕС индекс: 605-001-00-5

REACH Registration Number: 01-2119488953-20-XXXX

Content: >= 3,7 % <= 4 %

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Skin Corr. 1B

Carc. 2

Skin Sens. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H301 Токсично При попадании внутрь.

H311 Токсично в contact с skin.

H314 Causes severe skin ожоги и eye damage.

H317 May cause an allergic skin reaction.

H331 Токсично if inhaled.

H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P272 Contaminated work clothing should not be allowed out the workplace.

P280 Wear protective gloves, protective clothing, Защита глаз или face protection.

P281 Use personal Средства индивидуальной защиты как required.

P202 Do not handle until all safety precautions have been чтение и understood.

P201 Obtain special instructions before use.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P261 Avoid breathing dust, fume, gas, mist, vapours или spray.

P264 Wash...thoroughly после обращение.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

T Токсично

R43 May cause sensitisation by skin contact.

R40 Limited evidence a carcinogenic effect.

R34 Может вызвать ожоги.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

Первая помощь measures

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Firefighting measures

5.1 Suitable extinguishing среда:

Песок. Пена. Углекислый газ (CO2). Вода.

5.2 Unsuitable extinguishing среда:

No specific data.

5.3 Special hazards arising from the соединен. или mixture:

Горючее Вещество. Держать на расстоянии от источников возгорания.

5.4 Advice for firefighters:

Специальная одежда и обувь.

Accidental release measures

6.1 Personal precautions, Средства индивидуальной защиты и emergency procedures:

Не вдыхать пары.

6.2 Environmental precautions:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Methods и material for containment и cleaning up:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды. Neutralize с excess натрия bisulphite раствор.

Правила обращения и хранения

7.1 Precautions for safe обращение:

Специальные указания отсутствуют.

7.2 Conditions for safe хранение, including any incompatibilities:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.Ограничить право доступа к веществу, предоставив его только специалистам.Do not store в металл containers.

Exposure controls/personal protection

8.1 Exposure controls:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Control parameters:

VLA-EC(Формальдегид): 0,37 мг/м3 ,

VLA-EC(Формальдегид): 0,3 ppm ,

MAK (Формальдегид) 0,5 ml/m3; 0,6 мг/м3(метанол) 200 ml/m3; 260 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр B. Фильтр P3.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Eye/face protection:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use complete Средства индивидуальной защиты. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Piquant.

pH: 6,8 - 7,2

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность: (20/4) 1,019

Растворимость: в ( )Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Кинематич. вязк.:N/A

Динамич. вязк.:

N/A

Стабильность и реакционноспособность

10.1 Conditions до avoid:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Incompatible materials:

Polymerization initiators. Щелочных металлы. Кислоты. оксиды азота. Водорода пероксид. Окислители. Performic кислота.

10.3 Опасные продукты разложения:

No specific data.

10.4 Chemical stability:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 100 мг/кг referred до the pure соединен.

LD50 skn rbt : 270 мг/кг referred до the pure соединен.

LC50 inh rat : 203 мг/м3

  • Опасное воздействие на здоровье:

Taking the preparation' components into account, the likely dangerous characteristics are как follows: If fumes inhaled: Irritations до the respiratory tracts. Upon Контакт с кожей: irritations May cause allergic reaction Контакт с глазами: irritations При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

- EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 8,5 mg/l

Классификация:

Extr. токсично (CH2O 30-40%)

Бактерии (Ps. putida) EC0 14 mg/l

Классификация: Extr. токсично

(CH2O 30-40%)

Algae (M. aeruginosa) EC0 0,4 mg/l

Классификация: Extr. токсично

(CH2O 30-40%)

Crustaceans (Daphnia magna) 42 mg/l

Классификация: Extr. токсично

Рыбы (Salmo gairdneri) 214 mg/l

Классификация:

Highly токсично (CH2O 30-40%)

- Воздействие на окружающую среду:

Риск для водной среды Высокий

Риск для земли Высокий

- Наблюдения:

Extremely токсично.

Inhibits активн. sludges.

Bactericide effect. Generally токсично for вода organisms.

Protoplasmatic токсично.

12.2 Persistence и Период Распада :

- Тест:

- Классификация биотического периода распада:

DOC 1,06 g/g(CH2O 30-40%)

BOD5/COD Биоразложение =

ThOD 1,068 g/g(CH2O 30-40%)

Высокий, над 1/3

- Абиотический период распада зависит от рН:

BOD5 0,728 g/g(CH2O 30-40%)

- Наблюдения:

Biodegradable product.

12.3 Bioaccumulative potential:

Non-bioaccumulable product.

12.4 Мобильность в soil :

Repartition: log P(oct)= 0,00 (CH2O 30-40%)

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Др. adverse effects:

Коррозионное Вещество product, even в diluted form.

Избегать попаданию вещества в почву и воду.

Disposal considerations

13.1 Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Transport information

Not classified как dangerous в the meaning ТРАНСПОРТНЫЕ ПОЛОЖЕНИЯ.

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R40 Limited evidence a carcinogenic effect.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Version и revision date : 4 08.07.2013

Remplaced: 03.11.2010

Относительно предыдущего обзора изменения были произведены в следующих разделах: 3

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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