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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

2921 Silica Gel 0,5-1,2 mm *with indicator (with cobalt chloride)

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Silica Gel 0,5-1,2 mm *with indicator (with cobalt chloride)

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Carc. 1B

Acute Tox. 4

Aquatic Chronic 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P273 Avoid release to the environment.

P281 Use personal protective equipment as required.

Classification (67/548/CEE or 1999/45/CE).

T Toxic

R53

R52

RE22

R49

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Silica Gel 0,5-1,2 mm *with indicator (with cobalt chloride)

CAS [112926-00-8]

EC number (EINECS): 231-545-4

Composition:

0001: Non-indicating Silica gel 1-3 mm (bags)

CAS [112926-00-8]

EC number (EINECS): 231-545-4

Content: >= 94 %

No hazardous substance as specified in Regulation (CE) 1272/2008.

No hazardous substance as specified in Classification (67/548/CEE or 1999/45/CE).

0002: Cobalt(II) Chloride anhydrous

Formula: CoCl2 M.= 129,84 CAS [7646-79-9]

EC number (EINECS): 231-589-4

EC index number: 027-004-00-5

Content: >= 0,5 % <= 1 %

Classification Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 1B

Acute Tox. 4

Resp. Sens 1

Skin Sens. 1

Muta. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H360F May damage fertility.

H302 Harmful if swallowed.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P285 In case of inadequate ventilation wear respiratory protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T Toxic

R42/43 May cause sensitisation by inhalation and skin contact.

RE22 Also harmful if swallowed.

R60 May impair fertility.

R49 May cause cancer by inhalation.

R68 Possible risk of irreversible effects.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

No special indications.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

TLV-TWA(ACGIH):

TLV-TWA(ACGIH):

VLA-ED: 10 mg/m3

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Wash hands before breaks and when the job is done. Remove contaminated clothing.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: Blue

Granulometry: N/A

Odour: Odourless.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: in Insoluble in water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Hydrogen halides Halogen oxides Light metals Heat

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

Hygroscopic.

Toxicological information

  • Acute toxicity:

LD L0 oral rbt : 1.272 mg/kg CoCl2

LD50 oral rat : 80 mg/kg CoCl2

  • Dangerous effects for health:

Symptoms due to acute intoxication of (Co): gastro-intestinal disorders loss of appetite alteration of the body temperature hypotension kidney problems cardiovascular disorders pancreas disorders Risk of sensitization allergic reaction Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) (Co) 16 mg/l

Classification: Extr. toxic

Fish (Co) 4.0 mg/l

Classification: Extr. toxic

Bacteria (Co) 6,2 mg/l

Classification: Extr. toxic

Mammals (Co) 5.0 mg/l

Classification: Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

Extremely toxic in water supplies and soils. Ecotoxicity acute and chronic.

12.2 Persistence and Degradability :

12.2.1 - Test:

BOD5

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Product insoluble in water.

DATA BASED on the components of the preparation.

(Soluble compounds of cobalt II)

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Not classified as dangerous in the meaning of transport regulations.

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P330 Rinse mouth.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R53 May cause long-term adverse effects in the aquatic environment.

R52 Harmful to aquatic organisms.

RE22 Also harmful if swallowed.

R49 May cause cancer by inhalation.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

2921 Силикагель 0,5-1,2 mm *с индикатором (с кобальт хлорид)

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Силикагель 0,5-1,2 mm *с индикатором (с кобальт хлорид)

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Carc. 1B

Acute Tox. 4

Aquatic Chronic 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H302 Вредный При попадании внутрь.

H412 Вредный до aquatic life с long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P273 Avoid release до the environment.

P281 Use personal Средства индивидуальной защиты как required.

Классификация (67/548/CEE или 1999/45/CE).

T Токсично

R53

R52

RE22

R49

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Силикагель 0,5-1,2 mm *с индикатором (с кобальт хлорид)

CAS [112926-00-8]

Номер ЕС (EINECS): 231-545-4

Состав:

0001: Non-indicating Силикагель 1-3 mm (bags)

CAS [112926-00-8]

Номер ЕС (EINECS): 231-545-4

Content: >= 94 %

Неопасное вещество в соответствии с регламентом (CE) 1272/2008.

Неопасное вещество как specified в Классификация (67/548/CEE или 1999/45/CE).

0002: Кобальт(II) Хлорид безводный

Формула: CoCl2 M.= 129,84 CAS [7646-79-9]

Номер ЕС (EINECS): 231-589-4

ЕС индекс: 027-004-00-5

Content: >= 0,5 % <= 1 %

Классификация Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 1B

Acute Tox. 4

Resp. Sens 1

Skin Sens. 1

Muta. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H360F May damage fertility.

H302 Вредный При попадании внутрь.

H334 May cause allergy или asthma symptoms или затруднение дыхания if inhaled.

H317 May cause an allergic skin reaction.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H410 Очень токсично до aquatic life с long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P272 Contaminated work clothing should not be allowed out the workplace.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P285 В case inadequate ventilation wear Защита органов дыхания.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P304+P341 IF INHALED: If breathing is difficult, remove victim до fresh air и keep при rest в a position comfortable for breathing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER или doctor/physician.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T Токсично

R42/43 May cause sensitisation by inhalation и skin contact.

RE22 Also вредный При попадании внутрь.

R60 May impair fertility.

R49 May cause cancer by inhalation.

R68 Possible риск irreversible effects.

R50/53 Очень токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Специальные указания отсутствуют.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Collect up безводн.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Room temperature.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

TLV-TWA(ACGIH):

TLV-TWA(ACGIH):

VLA-ED: 10 мг/м3

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Мыть руки перед перерывами в работе и после окончания работы. Избавиться от загрязненной одежды.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Синий

Granulometry: N/A

Запах: Без Запаха.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: в Не Растворяется в воде

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Водород галиды оксиды галогенов Light металлы Heat

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

Гигроскопичный.

Токсикологическая информация

  • Высокая токсичность:

LD L0 oral rbt : 1.272 мг/кг CoCl2

LD50 oral rat : 80 мг/кг CoCl2

  • Опасное воздействие на здоровье:

Symptoms due до acute intoxication (Co): gastro-intestinal disorders loss appetite alteration the body temperature hypotension kidney problems cardiovascular disorders pancreas disorders Риск sensitization allergic reaction Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) (Co) 16 mg/l

Классификация: Extr. токсично

Рыбы (Co) 4.0 mg/l

Классификация: Extr. токсично

Бактерии (Co) 6,2 mg/l

Классификация: Extr. токсично

Mammals (Co) 5.0 mg/l

Классификация: Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

Extremely токсично в воде supplies и soils. Экотоксичность acute и chronic.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

BOD5

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Product не растворяется в воде.

DATA BASED on the components the preparation.

(Растворяется соединен. кобальт II)

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Not classified как dangerous в the meaning ТРАНСПОРТНЫЕ ПОЛОЖЕНИЯ.

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P330 Rinse mouth.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R53 May cause long-term adverse effects в the aquatic environment.

R52 Вредный до aquatic organisms.

RE22 Also вредный При попадании внутрь.

R49 May cause cancer by inhalation.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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