S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Lead(II) Hydroxideacetate solution

Synonym:

Lead Subacetate, Lead(II) Acetate Basic

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Repr. 1A

STOT RE 2

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H360Df May damage the unborn child. Suspected of damaging fertility.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

P281 Use personal protective equipment as required.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Lead(II) Hydroxideacetate solution

CAS [1335-32-6]

EC number (EINECS): 215-630-3

EC index number: 082-007-00-9

Composition:

CAS [1335-32-6]

EC number (EINECS): 215-630-3

EC index number: 082-007-00-9

Content: >= 15 % <= 30 %

Classification Regulation (CE) nº 1272/2008.

Repr. 1A

STOT RE 2

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H360Df May damage the unborn child. Suspected of damaging fertility.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

P281 Use personal protective equipment as required.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P391 Collect spillage.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek immediate medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Restricted access, only authorized to technicians.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

Avoid exposure during handling and transfer.

8.2 Exposure limit control:

VLA-ED(Pb): 0,1 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Wash hands and face before breaks and when the job is done. Use suitable work clothing.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Odourless.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 1,2

Solubility: in Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

No specific data.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

• Acute toxicity:

: Data not available.

• Dangerous effects for health:

For lead compounds in general : In high concentrations: The product is absorbed with difficulty in the gastro-intestinal tract, which can cause acute toxicity. After a period of latency: Metallic taste nausea vomiting intestinal disorders shock Chronic effects muscular disorders blood alterations effects on the central nervous system Pregnant women must not be allowed to come into contact with the product. Possible risk of adverse effects to the foetus during pregnacy. Possible risk of impaired fertility. If swallowed in large quantities: nausea vomiting Other dangerous characteristics are not discarded.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Ps. putida) (Pb) 1,4 mg/l

Classification: Extr. toxic

Algae (Sc. cuadricauda) (Pb) 3,7 mg/l

Classification: Extr. toxic

Algae (M. aeruginosa) (Pb) 0,45 mg/l

Classification: Extr. toxic

Protozoa (E. sulcatum) (Pb) 0,02 mg/l

Classification: Extr. toxic

Protozoa (U. parduczi). (Pb) 0,07 mg/l

Classification: Extr. toxic

Crustaceans (Daphnia magna) (Pb) 2,5 mg/l

Classification: Extr. toxic

Fish (Salmo gairdneri) (Pb) 0,14 mg/l

Classification: Extr. toxic

Fish (Leuciscus Idus) (Pb) 546 mg/l

Classification: Highly toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Bioaccumulable product.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Water-pollutant product.

Dangerous for drinking water.

Data refer to the pure substance.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III (E)

By sea (IMDG):

Technical name: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Toxic liquid, organic, n.o.s.

UN 2810 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 663 PAX 655

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P308+P313 IF exposed or concerned: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P391 Collect spillage.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.