S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
5306 Platinum(IV) Chloride anhydrous
Identification of the substance/preparation and of the company or firm | ||||
1.1 Identification of the substance or preparation Name: Platinum(IV) Chloride anhydrous
Synonym: Tetrachloroplatinate
REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: | ||||
For laboratory utilisation, analysis, research and fine chemistry.
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008.
Acute Tox. 4 Skin Corr. 1B Skin Sens. 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.
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Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection.
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Classification (67/548/CEE or 1999/45/CE).
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For the full text of the R-phrases mentioned in this section, see section 16. | ||||
Component Composition/Information | ||||
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Name: Platinum(IV) Chloride anhydrous Formula: PtCl4 M.= 336,90 CAS [13454-96-1] EC number (EINECS): 236-645-1 | ||||
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First aid
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4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water, keeping eyelids open. Seek immediate medical assistance.
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4.5 Swallowing: Drink large amounts of water. Induce vomiting. Seek immediate medical assistance.
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Fire-fighting means
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5.1 Suitable fire-extinguishing means: Water. Carbon dioxide (CO2). Foam. Dry powder.
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5.2 Fire-fighting means which must NOT be used: No specific data.
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5.3 Special risks: Encourages fire to break out. Keep away from combustible substances. In the event of fire, toxic fumes may form:
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5.4 Protective equipment: Suitable clothing and footwear.
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: Avoid contact with the skin, eyes or clothing.
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6.2 Precautions for care of the environment: Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water. Carry out the operation with maximum precaution.
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Handling and storage
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7.1 Handling: Handle under an extractor fan.
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7.2 Storage: Well sealed containers.Dry atmosphere.Restricted access, only authorized to technicians.
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Staff exposure/protection controls
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8.1 Technical protective measures: No special indications.
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8.2 Exposure limit control: TLV-TWA(Pt): 0,002 mg/m3
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8.3 Respiratory protection: If dust forms, use suitable respiratory protection.
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8.4 Hand protection: Use suitable gloves
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | ||||
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Physical and chemical properties
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Appearance: solid | ||||
Colour: Reddish-brown | ||||
Granulometry: N/A | ||||
Odour: N/A | ||||
pH: 7 | ||||
Melting point/freezing point: N/A | ||||
Initial boiling point and boiling range: N/A | ||||
Flash point: N/A | ||||
Flammability (solid, gas): N/A | ||||
Upper/lower flammability or explosive limits: N/A | ||||
Vapour pressure: N/A | ||||
Vapour density: N/A | ||||
Relative density: N/A | ||||
Solubility: 587 g/l in water25 °C | ||||
Partition coefficient: n-octanol/water: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Viscosity: N/A | ||||
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Stability and reactivity
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10.1 Conditions which should be avoided: The product is chemically stable under standar ambient conditions (room temperature).
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10.2 Matter which should be avoided: Steel. Aluminium.
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10.3 Hazardous decomposition products: Chlorine.
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10.4 Complementary information: No specific data.
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Toxicological information
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LD50 oral rat : 276 mg/kg
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If dust inhaled: Irritations to the mucosae and respiratory tracts. Upon contact with the skin: irritations Can cause burns Through contact with the eyes: irritations Can cause burns Symptoms due to acute intoxication of (Pt): hepatic problems kidney problems sensitization allergic reaction Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
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12.1 Toxicity: 12.1.1 - EC50 test (mg/l): 12.1.2. - Receptor medium: Risk for the water environment Risk for the land environment Due to its low solubility, no ecotoxicity problems are to be anticipated.
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12.2 Persistence and Degradability : 12.2.1 - Test: 12.2.2. - Biotic degradation classification: BOD5/COD Biodegradability 12.2.3. - Abiotic degradation depending on pH: 12.2.4. - Observations:
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12.3 Bioaccumulative potential: 12.3.1. - Test: 12.3.2. - Bioaccumulation: Risk 12.3.3. - Observations:
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12.4 Mobility in soil : Data not available.
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12.5 Assessment PBT and MPMB : Data not available.
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12.6 Other possible effects on the environment: Environmental risks cannot be excluded if used and/or disposed of inappropriately. DATA BASED on the components of the preparation. (Soluble copper compounds)
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Considerations regarding elimination
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13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
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Overland (ADR): Technical name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. UN 3260 Class: 8 CONTAM. MAR Packaging group: II (E) | ||||
By sea (IMDG): Technical name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. UN 3260 Class: 8 CONTAM. MAR Packaging group: II | ||||
By air (ICAI-IATA): Technical name: Corrosive solid, acidic, inorganic, n.o.s UN 3260 Class: 8 CONTAM. MAR Packaging group: II | ||||
Packaging instructions: CAO 863 PAX 859 | ||||
Regulatory information
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This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
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Other information
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Other precautionary statements P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see on this label). P330 Rinse mouth. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P338 Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Labelling (65/548/CEE or 1999/45/CE) | ||||
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Review number and date: 3 3.11.10 Date published: 3.11.10 In respect of the previous review, changes have been made to the following sections: 2, 3, 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
5306 Platinum(IV) Хлорид безводный
Определение вещества/preparation и the company или firm | ||||
1.1 Определение вещества или preparation Название: Platinum(IV) Хлорид безводный
Synonym: Tetrachloroplatinate
REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use вещества/preparation: | ||||
Для общелабораторного использования, анализов, исследований и тонкой химии.
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1.3 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
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Классификация вещества или the mixture.
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Классификация Regulation (CE) nº 1272/2008.
Acute Tox. 4 Skin Corr. 1B Skin Sens. 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H302 Вредный При попадании внутрь. H314 Causes severe skin ожоги и eye damage. H317 May cause an allergic skin reaction.
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Precautionary statements P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P270 Do no eat, drink или smoke when using this product. P272 Contaminated work clothing should not be allowed out the workplace. P280 Wear protective gloves/protective clothing/Защита глаз/face protection.
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Классификация (67/548/CEE или 1999/45/CE).
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For the full text the R-выражения mentioned в this section, see section 16. | ||||
Сведения о компонентах и состав | ||||
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Название: Platinum(IV) Хлорид безводный Формула: PtCl4 M.= 336,90 CAS [13454-96-1] Номер ЕС (EINECS): 236-645-1 | ||||
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Первая помощь
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4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. Обратиться немедленно за медицинской помощью.
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Меры и средства обеспечения пожаро- и взрывобезопасности
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5.1 Пригодные средства пожаротушения: Вода. Углекислый газ (CO2). Пена. Песок.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used: No specific data.
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5.3 Особая опасность: Encourages fire до break out. Keep away from горючее вещество соединения. В случае возгорания могут образовываться токсичные пары:
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5.4 Средства индивидуальной защиты: Специальная одежда и обувь.
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
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6.1 Индивидуальные меры предосторожности: Avoid Контакт с кожей, глаза или clothing.
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6.2 Меры по защите окружающей среды: Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды. Carry out the operation с maximum precaution.
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Правила обращения и хранения
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7.1 Обращение: Handle under an extractor fan.
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7.2 Хранение: В запечатанных контейнерах.Сухая атмосфера.Ограничить право доступа к веществу, предоставив его только специалистам.
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Требования по охране труда и меры по обеспечению безопасности персонала
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8.1 Технические меры защиты: Специальные указания отсутствуют.
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8.2 Контроль предельно допустимого уровня воздействия: TLV-TWA(Pt): 0,002 мг/м3
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8.3 Защита органов дыхания: If dust forms, use suitable Защита органов дыхания.
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8.4 Защита рук: Использовать защитные перчатки
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8.5 Защита глаз: Использовать защитные очки.
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.
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8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | ||||
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Физико-химические свойства
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Внешний Вид: solid | ||||
Цвета: Reddish-brown | ||||
Granulometry: N/A | ||||
Запах: N/A | ||||
pH: 7 | ||||
точка плавления/Температура замерзания: N/A | ||||
Initial Точка кипения и Интервал температур кипения: N/A | ||||
Точка воспламенения: N/A | ||||
Flammability (solid, gas): N/A | ||||
Верхний/нижний flammability или explosive показатели: N/A | ||||
Давление пара: N/A | ||||
Vapour плотность: N/A | ||||
Relative плотность: N/A | ||||
Растворимость: 587 г/л в воде25 °C | ||||
Partition coefficient: n-октанол/вода: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Вязк.: N/A | ||||
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Стабильность и реакционноспособность
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10.1 Условия, которых следует избегать: The product is chemically stable under standar ambient conditions (room temperature).
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10.2 Вещества, которых следует избегать: Steel. Алюминий.
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10.3 Опасные продукты разложения: Хлор.
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10.4 Общая информация: No specific data.
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Токсикологическая информация
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LD50 oral rat : 276 мг/кг
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If dust inhaled: Irritations до the mucosae и respiratory tracts. Upon Контакт с кожей: irritations Can cause ожоги Контакт с глазами: irritations Can cause ожоги Symptoms due до acute intoxication (Pt): hepatic problems kidney problems sensitization allergic reaction Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
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Информация по окружающей среде
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12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): 12.1.2. - Воздействие на окружающую среду: Риск для водной среды Риск для земли Due до its low растворимость, no экотоксичность problems are до be anticipated.
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12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Классификация биотического периода распада: BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от рН: 12.2.4. - Наблюдения:
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения:
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12.4 Мобильность в soil : Нет данных.
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12.5 Assessment PBT и MPMB : Нет данных.
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12.6 Другие возможные воздействия на окружающую среду: Environmental risks cannot be excluded if used и/или disposed inappropriately. DATA BASED on the components the preparation. (Растворяется медь соединен.)
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Правила утилизации
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13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
.
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13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
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Информация относительно транспорта
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Автотранспорт (ADR): Техническое название: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. UN 3260 Класс: 8 CONTAM. MAR Группа: II (E) | ||||
Морской транспорт (IMDG): Техническое название: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. UN 3260 Класс: 8 CONTAM. MAR Группа: II | ||||
Авиа транспорт (ICAI-IATA): Техническое название: Коррозионное Вещество solid, acidic, неорганический, n.o.s UN 3260 Класс: 8 CONTAM. MAR Группа: II | ||||
Инструкция по упаковке: CAO 863 PAX 859 | ||||
Regulatory information
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This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.
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Дополнительная информация
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Др. precautionary statements P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P310 Immediately call a POISON CENTER или doctor/physician. P321 Specific treatment (see on this label). P330 Rinse mouth. P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P338 Remove contact lenses, if present и easy до do. Continue rinsing. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Labelling (65/548/CEE или 1999/45/CE) | ||||
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Номер рецензии и дата: 3 3.11.10 Date published: 3.11.10 Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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