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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

5253 Electrode-Reactivating Solution

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Electrode-Reactivating Solution

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal in contact with skin.

H300 Fatal if swallowed.

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R35

R26/27/28

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Electrode-Reactivating Solution

Composition:

0001: Hydrochloric Acid 37%

Formula: HCl M.= 36,46 CAS [7647-01-0]

EC number (EINECS): 231-595-7

EC index number: 017-002-01-X

REACH Registration Number: 01-2119484862-27-XXXX

Content: <= 5 %

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R34 Causes burns.

R37 Irritating to respiratory system.

0002: Hydrofluoric Acid 48%

Formula: HF M.= 20,01 CAS [7664-39-3]

EC number (EINECS): 231-634-8

EC index number: 009-003-00-1

REACH Registration Number: 01-2119458860-33-XXXX

Content: >= 10 % <= 15 %

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal in contact with skin.

H300 Fatal if swallowed.

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 Wear respiratory protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

T+ Very toxic

R35 Causes severe burns.

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.

First aid

4.1 General indications:

The first-aider must be protected. Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing. Seek immediate medical assistance.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.

4.5 Swallowing:

Risk of perforation. Drink large amounts of water or milk. Avoid vomiting. Seek immediate medical assistance. Indications for the doctor: subsequent application, calcium gluconate.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible. Upon contact with metals, hydrogen gas may form (there is a risk of explosion). In the event of fire, toxic fumes may form. Cool the recipients with water. Precipitate fumes formed with water. Do not allow extinguishing water into surface or underground water courses.

5.4 Protective equipment:

Suitable clothing and footwear. Self-contained breathing equipment.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water. Treat with a mixture of lime in sodium carbonate solution (a precipitate of calcium fluoride is formed).

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from light.In a cool place.Store in plastic containers.Do not store in glass containers.Do not store in metal containers.Restricted access, only authorized to technicians.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

VLA-EC(HF): 2,5 mg/m3

VLA-EC(HF): 3 ppm

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter B. Filter P3.

8.4 Hand protection:

Use suitable gloves neopren

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use complete protective equipment. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Piquant.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

Alkaline compounds. Metals. Alkaline metals. Glass. Silicon compounds.

10.3 Hazardous decomposition products:

Hydrogen fluoride - fumes.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

If fumes inhaled: Irritations to the respiratory tracts. Very corrosive substance. Can cause bronchitis bronchopneumonia pulmonary oedema Upon contact with the skin: burns The following cannot be ruled out: necrosis Penetration of the product causes injuries which are hard to cure. Through contact with the eyes: burns blindness (irreversible injury of the optic nerve) If swallowed: Burns in the oesophagus and stomach. Severe pains, with risk of perforation. vomiting spasms Systemic effects: collapse Due to absorption: lethal effect Has latent effects. It is imperative to take countermeasures straight away. Other dangerous characteristics are not discarded.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Fish (HF) 40 - 60 mg/l

Classification:

Highly toxic

Algae (Elodea densa) (HF) 8 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

High

12.1.3. - Observations:

Ecotoxic for water and land organisms due to the pH deviation. Major acute effects in the dumping area.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Does not consume oxygen biologically.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Non-bioaccumulable product.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Generally, its effect is acutely considerable in the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

Do not allow it to enter soils or water channels.

The treatment is neutralization.

DATA BASED on the components of the preparation.

(Major component:

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

UN 3264 Class: 8 CONTAM. MAR Packaging group: II (E)

By sea (IMDG):

Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

UN 3264 Class: 8 CONTAM. MAR Packaging group: II

By air (ICAI-IATA):

Technical name: Corrosive liquid, acidic, inorganic, n.o.s.

UN 3264 Class: 8 CONTAM. MAR Packaging group: II

Packaging instructions: CAO 855 PAX 851

Regulatory information

The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.

Other information

Other precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 Wear respiratory protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R35 Causes severe burns.

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S36/37 Wear suitable protective clothing and gloves.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S7/9 Keep container tightly closed and in a well-ventilated place.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

5253 Electrode-Reactivating Раствор

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Electrode-Reactivating Раствор

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal в contact с skin.

H300 Fatal При попадании внутрь.

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P262 Do not get в глаза, on skin, или on clothing.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R35

R26/27/28

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Electrode-Reactivating Раствор

Состав:

0001: Соляная Кислота 37%

Формула: HCl M.= 36,46 CAS [7647-01-0]

Номер ЕС (EINECS): 231-595-7

ЕС индекс: 017-002-01-X

REACH Registration Number: 01-2119484862-27-XXXX

Content: <= 5 %

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R34 Может вызвать ожоги.

R37 Irritating до respiratory system.

0002: Hydrofluoric Кислота 48%

Формула: HF M.= 20,01 CAS [7664-39-3]

Номер ЕС (EINECS): 231-634-8

ЕС индекс: 009-003-00-1

REACH Registration Number: 01-2119458860-33-XXXX

Content: >= 10 % <= 15 %

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal в contact с skin.

H300 Fatal При попадании внутрь.

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P262 Do not get в глаза, on skin, или on clothing.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P284 Wear Защита органов дыхания.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P302+P350 IF ON SKIN: Gently wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

T+ Очень токсично

R35 Causes severe ожоги.

R26/27/28 Очень токсично by inhalation, в contact с skin и При попадании внутрь.

Первая помощь

4.1 Общие указания:

The first-aider must be protected. Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды. Обратиться немедленно за медицинской помощью.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.

4.5 Попадание Внутрь:

Риск perforation. Выпить большое количество воды или milk. Avoid рвота. Обратиться немедленно за медицинской помощью. Indications for the doctor: subsequent application, кальций gluconate.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible. Upon contact с металлы, водород gas may form (there is a риск explosion). В случае возгорания могут образовываться токсичные пары. Cool the recipients с водой. Precipitate fumes formed с водой. Do not allow extinguishing вода into surface или underground вода courses.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь. Средства индивидуальной защиты дыхательных путей.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды. Treat с a mixture lime в натрия карбонат раствор (a precipitate кальций фторид is formed).

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Away from light.В прохладном помещении.Store в plastic containers.Do not store в glass containers.Do not store в металл containers.Ограничить право доступа к веществу, предоставив его только специалистам.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC(HF): 2,5 мг/м3

VLA-EC(HF): 3 ppm

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр B. Фильтр P3.

8.4 Защита рук:

Использовать защитные перчатки neopren

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use complete Средства индивидуальной защиты. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Piquant.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Высокий temperatures.

10.2 Вещества, которых следует избегать:

Щелочных соединен.. Металлы. Щелочных металлы. Glass. Кремний соединен..

10.3 Опасные продукты разложения:

Водород фторид - fumes.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the respiratory tracts. Very коррозионное вещество соединен.. Can cause bronchitis bronchopneumonia pulmonary oedema Upon Контакт с кожей: ожоги The following cannot be ruled out: necrosis Penetration the product causes injuries which are hard до cure. Контакт с глазами: ожоги blindness (irreversible injury the optic nerve) При попадании внутрь: Ожоги в the oesophagus и stomach. Severe pains, с риск perforation. рвота spasms Systemic effects: collapse Due до absorption: lethal effect Has latent effects. It is imperative до take countermeasures straight away. Другие опасные характеристики данного вещества не обнаружены.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Рыбы (HF) 40 - 60 mg/l

Классификация:

Highly токсично

Algae (Elodea densa) (HF) 8 mg/l

Классификация:

Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Высокий

12.1.3. - Наблюдения:

Ecotoxic for вода и land organisms due до the pH deviation. Major acute effects в the dumping area.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Does not consume oxygen biologically.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Non-bioaccumulable product.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Generally, its effect is acutely considerable в the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

Избегать попаданию вещества в почву и воду.

The treatment is neutralization.

DATA BASED on the components the preparation.

(Major component:

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

UN 3264 Класс: 8 CONTAM. MAR Группа: II (E)

Морской транспорт (IMDG):

Техническое название: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

UN 3264 Класс: 8 CONTAM. MAR Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Коррозионное Вещество жидкость, acidic, неорганический, n.o.s.

UN 3264 Класс: 8 CONTAM. MAR Группа: II

Инструкция по упаковке: CAO 855 PAX 851

Regulatory information

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

Дополнительная информация

Др. precautionary statements

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P284 Wear Защита органов дыхания.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P302+P350 IF ON SKIN: Gently wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R35 Causes severe ожоги.

R26/27/28 Очень токсично by inhalation, в contact с skin и При попадании внутрь.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S36/37 Использовать специальную защитную одежду и перчатки.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

S7/9 Keep container tightly closed и в a well-ventilated place.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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