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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

2698 Petroleum Ether 25-40°C

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Petroleum Ether 25-40°C

Synonym:

Ligroin, Naphta, Petroleum Benzine

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 1

Skin Irrit. 2

Aquatic Chronic 2

Repr. 2

Asp. Tox. 1

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H224 Extremely flammable liquid and vapour.

H315 Causes skin irritation.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H411 Toxic to aquatic life with long lasting effects.

H361f Suspected of damaging fertility.

H304 May be fatal if swallowed and enters airways.

H336 May cause drowsiness or dizziness.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

Xn Harmful

F+ Extremely flammable

R51/53

R48/20

R38

R12

R62

R65

R67

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Mixture of hydrocarbons, chiefly consisting of:

n-pentane. iso-pentane.

Name: Petroleum Ether 25-40°C

CAS [64742-49-0]

EC number (EINECS): 265-151-9

EC index number: 649-328-00-1

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed to provide artificial respiration.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Risk of aspiration. Seek medical assistance. Administer Vaseline oil as a laxative (3 ml/kg). Administer a solution of medical-usage active charcoal. Do not drink milk. Avoid stomach lavage. Do not administer digestive oils.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

Avoid the formation of electrostatic charges.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Room temperature.Do not store in plastic containers.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Characteristic.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range: 25 - 40 °C

Flash point: - 40 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits: 8 %(V) / 0,6 %(V)

Vapour pressure: 350 hPa (20 °C)

Vapour density: N/A

Relative density: (20/4) 0,62

Solubility: Inmiscible with water.

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

Strong oxidant agents.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

The gases/fumes can form explosive mixtures with the air.

Toxicological information

  • Acute toxicity:

LC50 inh rat : 3400 ppm 4h

  • Dangerous effects for health:

If fumes inhaled: Irritations to the respiratory tracts. If swallowed: nausea Risk of aspiration upon vomiting. Can cause pneumonia. Due to absorption: headaches vertigo anxiety spasms loss of consciousness cardiovascular failure respiratory paralysis Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Fish (Leuciscus Idus) 159 mg/l

Classification:

Highly toxic

Animals for fish food 70 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

Acute ecotoxicity in line with the dumping concentration.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Hardly pollutant product.

Risk of formation of explosive fumes on the surface of the water.

Dangerous for drinking water.

Do not allow it to enter soils or water channels.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: PETROLEUM DISTILLATES, N.O.S.

UN 1268 Class: 3 CONTAM. MAR PELIG.M.AMB Packaging group: I (D/E)

By sea (IMDG):

Technical name: PETROLEUM DISTILLATES, N.O.S.

UN 1268 Class: 3 CONTAM. MAR PELIG.M.AMB Packaging group: I

By air (ICAI-IATA):

Technical name: Petroleum distillates, n.o.s.

UN 1268 Class: 3 CONTAM. MAR PELIG.M.AMB Packaging group: I

Packaging instructions: CAO 361 PAX 351

Regulatory information

Categorized as hydrocarbon substance.

Other information

Other precautionary statements

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P331 Do NOT induce vomiting.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P370+P378 In case of fire: Use for extinction.

P391 Collect spillage.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

R38 Irritating to skin.

R12 Extremely flammable.

R62 Possible risk of impaired fertility.

R65 Harmful: may cause lung damage if swallowed.

R67 Vapours may cause drowsiness and dizziness.

S-phrase(s):

S33 Take precautionary measures against static discharges.

S24 Avoid contact with skin.

S23c Do not breathe vapour.

S16 Keep away from sources of ignition - No smoking.

S36/37 Wear suitable protective clothing and gloves.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

2698 Петролейн. Эфир 25-40°C

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Петролейн. Эфир 25-40°C

Synonym:

Ligroin, Naphta, Петролейн. Benzine

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 1

Skin Irrit. 2

Aquatic Chronic 2

Repr. 2

Asp. Tox. 1

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H224 Extremely воспламеняем жидкость и vapour.

H315 Causes skin irritation.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H411 Токсично до aquatic life с long lasting effects.

H361f Suspected damaging fertility.

H304 May be fatal При попадании внутрь и enters airways.

H336 May cause drowsiness или dizziness.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

Xn Вредный

F+ Extremely воспламеняем

R51/53

R48/20

R38

R12

R62

R65

R67

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Mixture углеводороды, chiefly consisting :

н-пентан. iso-пентан.

Название: Петролейн. Эфир 25-40°C

CAS [64742-49-0]

Номер ЕС (EINECS): 265-151-9

ЕС индекс: 649-328-00-1

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed до provide artificial respiration.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Риск aspiration. Обратиться за медицинской помощью. Administer Вазелинов. Масло как a laxative (3 ml/kg). Administer a раствор medical-usage активн. уголь. Do not drink milk. Avoid stomach lavage. Do not administer digestive oils.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Избегать образования электростатических разрядов.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.Не хранить в пластиковых контейнерах.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Контроль предельно допустимого уровня воздействия:

: Нет данных.

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения: 25 - 40 °C

Точка воспламенения: - 40 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 8 %(V) / 0,6 %(V)

Давление пара: 350 hPa (20 °C)

Vapour плотность: N/A

Relative плотность: (20/4) 0,62

Растворимость: Inmiscible с водой.

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Высокий temperatures.

10.2 Вещества, которых следует избегать:

Strong Окислители.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

The gases/fumes can form explosive mixtures с the air.

Токсикологическая информация

  • Высокая токсичность:

LC50 inh rat : 3400 ppm 4h

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the respiratory tracts. При попадании внутрь: тошнота Риск aspiration upon рвота. Can cause pneumonia. Due до absorption: headaches vertigo anxiety spasms loss consciousness cardiovascular failure respiratory paralysis Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Рыбы (Leuciscus Idus) 159 mg/l

Классификация:

Highly токсично

Animals for рыбы food 70 mg/l

Классификация:

Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

Acute экотоксичность в line с the dumping концентрация.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Hardly Продукт загрязнения.

Риск formation explosive fumes on the surface the вода.

Dangerous for drinking вода.

Избегать попаданию вещества в почву и воду.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: PETROLEUM DISTILLATES, N.O.S.

UN 1268 Класс: 3 CONTAM. MAR PELIG.M.AMB Группа: I (D/E)

Морской транспорт (IMDG):

Техническое название: PETROLEUM DISTILLATES, N.O.S.

UN 1268 Класс: 3 CONTAM. MAR PELIG.M.AMB Группа: I

Авиа транспорт (ICAI-IATA):

Техническое название: Петролейн. distillates, n.o.s.

UN 1268 Класс: 3 CONTAM. MAR PELIG.M.AMB Группа: I

Инструкция по упаковке: CAO 361 PAX 351

Regulatory information

Categorized как hydrocarbon соединен..

Дополнительная информация

Др. precautionary statements

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P331 Do NOT Вызвать рвоту.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P370+P378 В case fire: Use for extinction.

P391 Collect spillage.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R51/53 Токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

R48/20 Вредный: danger serious damage до health by prolonged exposure through inhalation.

R38 Irritating до skin.

R12 Extremely воспламеняем.

R62 Possible риск impaired fertility.

R65 Вредный: may cause lung damage При попадании внутрь.

R67 Vapours may cause drowsiness и dizziness.

S-phrase(s):

S33 Take precautionary measures against static discharges.

S24 Avoid contact с skin.

S23c Do not breathe vapour.

S16 Держать на расстоянии от источников возгорания - Не курить.

S36/37 Использовать специальную защитную одежду и перчатки.

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S62 При попадании внутрь, do not Вызвать рвоту: seek medical advice immediately и show this container или label.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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