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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1478 Lead(II) Sulphate

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Lead(II) Sulphate

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Repr. 1A

Acute Tox. 4

Acute Tox. 4

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H360Df May damage the unborn child. Suspected of damaging fertility.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T Toxic

R62

R33

R20/22

R61

R50/53

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Lead(II) Sulphate

Formula: PbSO4 M.= 303,25 CAS [7446-14-2]

EC number (EINECS): 231-198-9

EC index number: 082-001-00-6

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek immediate medical assistance. Laxatives: sodium sulphate (1 soup-spoonful in 250 ml of water). Administer a solution of medical-usage active charcoal. Stomach lavage.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Room temperature.Dry atmosphere.Restricted access, only authorized to technicians.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

TLV-TWA(Pb): 0,15 mg/m3

VLA-ED(Pb): 0,1 mg/m3

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Wash hands before breaks and when the job is done. Use suitable work clothing.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: White

Granulometry: N/A

Odour: Odourless.

pH:

N/A

Melting point/freezing point: 1.170 °C

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: 0,045 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Strong bases.

10.3 Hazardous decomposition products:

Sulphur oxides.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LD L0 oral guinea pig : 30.000 mg/kg

  • Dangerous effects for health:

If inhaled: Irritations to the respiratory tracts. Causes coughing breathing difficulties oedemas in the respiratory tract Can cause laryngitis spasms pulmonary oedema Upon contact with the skin: irritations Through contact with the eyes: irritations For lead compounds in general : In high concentrations: The product is absorbed with difficulty in the gastro-intestinal tract, which can cause acute toxicity. After a period of latency: Metallic taste nausea vomiting intestinal disorders shock Chronic effects muscular disorders blood alterations effects on the central nervous system Pregnant women must not be allowed to come into contact with the product. Possible risk of adverse effects to the foetus during pregnacy. Possible risk of impaired fertility. If swallowed: nausea vomiting headaches Other dangerous characteristics are not discarded.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Ps. putida) (Pb) 1,4 mg/l

Classification: Extr. toxic

Algae (Sc. cuadricauda) (Pb) 3,7 mg/l

Classification: Extr. toxic

Algae (M. aeruginosa) (Pb) 0,45 mg/l

Classification: Extr. toxic

Protozoa (E. sulcatum) (Pb) 0,02 mg/l

Classification: Extr. toxic

Protozoa (U. parduczi). (Pb) 0,07 mg/l

Classification: Extr. toxic

Crustaceans (Daphnia magna) (Pb) 2,5 mg/l

Classification: Extr. toxic

Fish (Salmo gairdneri) (Pb) 0,14 mg/l

Classification: Extr. toxic

Fish (Leuciscus Idus) (Pb) 546 mg/l

Classification: Highly toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Bioaccumulable product.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Water-pollutant product.

The ecotoxic effect of lead is reduced due to the compound's low solubility.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: LEAD COMPOUND, SOLUBLE, N.O.S.

UN 2291 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III (E)

By sea (IMDG):

Technical name: LEAD COMPOUND, SOLUBLE, N.O.S.

UN 2291 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Lead compound, soluble, n.o.s.

UN 2291 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 677 PAX 670

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P281 Use personal protective equipment as required.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P330 Rinse mouth.

P391 Collect spillage.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R62 Possible risk of impaired fertility.

R33 Danger of cumulative effects.

R20/22 Harmful by inhalation and if swallowed.

R61 May cause harm to the unborn child.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s):

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S60 This material and its container must be disposed of as hazardous waste.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1478 Свинец(II) Сульфат

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Свинец(II) Сульфат

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Repr. 1A

Acute Tox. 4

Acute Tox. 4

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H360Df May damage the unborn child. Suspected damaging fertility.

H332 Вредный if inhaled.

H302 Вредный При попадании внутрь.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H410 Очень токсично до aquatic life с long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T Токсично

R62

R33

R20/22

R61

R50/53

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Свинец(II) Сульфат

Формула: PbSO4 M.= 303,25 CAS [7446-14-2]

Номер ЕС (EINECS): 231-198-9

ЕС индекс: 082-001-00-6

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться немедленно за медицинской помощью. Laxatives: натрия сульфат (1 soup-spoonful в 250 ml вода). Administer a раствор medical-usage активн. уголь. Stomach lavage.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Room temperature.Сухая атмосфера.Ограничить право доступа к веществу, предоставив его только специалистам.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

TLV-TWA(Pb): 0,15 мг/м3

VLA-ED(Pb): 0,1 мг/м3

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Мыть руки перед перерывами в работе и после окончания работы. Использовать специальную одежду.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Белый

Granulometry: N/A

Запах: Без Запаха.

pH:

N/A

точка плавления/Температура замерзания: 1.170 °C

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: 0,045 г/л в воде20 °C

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Сильные основания.

10.3 Опасные продукты разложения:

Sulphur oxides.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD L0 oral guinea pig : 30.000 мг/кг

  • Опасное воздействие на здоровье:

If inhaled: Irritations до the respiratory tracts. Causes coughing затруднение дыхания oedemas в the respiratory tract Can cause laryngitis spasms pulmonary oedema Upon Контакт с кожей: irritations Контакт с глазами: irritations For свинец соединен. в general : В высокий concentrations: The product is absorbed с difficulty в the gastro-intestinal tract, which can cause Высокая токсичность. После a period latency: Metallic taste тошнота рвота intestinal disorders shock Chronic effects muscular disorders blood alterations effects on the central nervous system Pregnant women must not be allowed до come into contact с the product. Possible риск adverse effects до the foetus during pregnacy. Possible риск impaired fertility. При попадании внутрь: тошнота рвота headaches Другие опасные характеристики данного вещества не обнаружены.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Ps. putida) (Pb) 1,4 mg/l

Классификация: Extr. токсично

Algae (Sc. cuadricauda) (Pb) 3,7 mg/l

Классификация: Extr. токсично

Algae (M. aeruginosa) (Pb) 0,45 mg/l

Классификация: Extr. токсично

Protozoa (E. sulcatum) (Pb) 0,02 mg/l

Классификация: Extr. токсично

Protozoa (U. parduczi). (Pb) 0,07 mg/l

Классификация: Extr. токсично

Crustaceans (Daphnia magna) (Pb) 2,5 mg/l

Классификация: Extr. токсично

Рыбы (Salmo gairdneri) (Pb) 0,14 mg/l

Классификация: Extr. токсично

Рыбы (Leuciscus Idus) (Pb) 546 mg/l

Классификация: Highly токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Bioaccumulable product.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Вода-Продукт загрязнения.

The ecotoxic effect свинец is восстановлен. due до the compound's low растворимость.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: LEAD COMPOUND, SOLUBLE, N.O.S.

UN 2291 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III (E)

Морской транспорт (IMDG):

Техническое название: LEAD COMPOUND, SOLUBLE, N.O.S.

UN 2291 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Свинец compound, растворяется, n.o.s.

UN 2291 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Инструкция по упаковке: CAO 677 PAX 670

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P271 Use only outdoors или в a well-ventilated area.

P273 Avoid release до the environment.

P281 Use personal Средства индивидуальной защиты как required.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P330 Rinse mouth.

P391 Collect spillage.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R62 Possible риск impaired fertility.

R33 Danger cumulative effects.

R20/22 Вреден при вдыхании и При попадании внутрь.

R61 May cause harm до the unborn child.

R50/53 Очень токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

S-phrase(s):

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S60 This material и its container must be disposed как опасная доза waste.

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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