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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3172 Barium *standard solution Ba=1,000+-0,002 g/l

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Barium *standard solution Ba=1,000+-0,002 g/l

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

Xi Irritant

R36/37/38

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Barium *standard solution Ba=1,000+-0,002 g/l

Composition:

0001: Nitric Acid 69%

Formula: HNO3 M.= 63,01 CAS [7697-37-2]

EC number (EINECS): 231-714-2

EC index number: 007-004-00-1

REACH Registration Number: 01-2119487297-23-XXXX

Content: >= 1 % <= 5 %

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Ox. Sol. 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

H272 May intensify fire; oxidiser.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P220 Keep/Store away from clothing/combustible materials.

P221 Take any precaution to avoid mixing with combustibles.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R35 Causes severe burns.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible. In the event of fire, toxic fumes may form:

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-EC(HNO3): 4 ppm - 10 mg/m3

VLA-ED(HNO3): 5,2 mg/m3

VLA-ED(HNO3): 2 ppm

VLA-ED(Ba): 0,5 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Use suitable work clothing. Remove contaminated clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour:

N/A

Granulometry: N/A

Odour: Odourless.

pH: 0,5

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Metals and metal alloys.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Through contact with the eyes: irritations Upon contact with the skin: irritations If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Can cause nausea dizziness diarrhoea stomach pains saliva flow Systemic effects: arrhythmia cardiovascular disorders blood alterations shock collapse muscular disorders metahemoglobinemia with headaches Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Algae (Sc. cuadricauda) (Ba) 34 mg/l

Classification: Extr. toxic

Crustaceans (Daphnia magna) (Ba) 29 mg/l

Classification: Extr. toxic

Fish (Salmo gairdneri) (Ba) 158 mg/l

Classification:

Highly toxic

Fish (Leuciscus Idus) (Ba) 870 mg/l

Classification:

Highly toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

The ecotoxicity is due to the ion Ba++.

The ecotoxicity is due to the pH deviation.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk = ----

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Encourages eotrophy in rivers and water channels.

Do not allow it to enter soils or water channels.

Dangerous for drinking water.

Ecotoxic effects due to the pH variation.

DATA BASED on the components of the preparation.

(Major component:

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III (E)

By sea (IMDG):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III

By air (ICAI-IATA):

Technical name: Corrosive liquid, n.o.s

UN 1760 Class: 8 Packaging group: III

Packaging instructions: CAO 856 PAX 852

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R36/37/38 Irritating to eyes, respiratory system and skin.

S-phrase(s):

S36 Wear suitable protective clothing.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3172 Барий *стандартный раствор Ba=1,000+-0,002 г/л

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Барий *стандартный раствор Ba=1,000+-0,002 г/л

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

Xi Irritant

R36/37/38

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Барий *стандартный раствор Ba=1,000+-0,002 г/л

Состав:

0001: Азотная кислота 69%

Формула: HNO3 M.= 63,01 CAS [7697-37-2]

Номер ЕС (EINECS): 231-714-2

ЕС индекс: 007-004-00-1

REACH Registration Number: 01-2119487297-23-XXXX

Content: >= 1 % <= 5 %

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Ox. Sol. 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

H272 May intensify fire; oxidiser.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P220 Keep/Store away from clothing/горючее вещество materials.

P221 Take any precaution до avoid mixing с combustibles.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R35 Causes severe ожоги.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible. В случае возгорания могут образовываться токсичные пары:

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Room temperature.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC(HNO3): 4 ppm - 10 мг/м3

VLA-ED(HNO3): 5,2 мг/м3

VLA-ED(HNO3): 2 ppm

VLA-ED(Ba): 0,5 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Использовать специальную одежду. Избавиться от загрязненной одежды. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета:

N/A

Granulometry: N/A

Запах: Без Запаха.

pH: 0,5

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Металлы и металл alloys.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Контакт с глазами: irritations Upon Контакт с кожей: irritations При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Can cause тошнота dizziness diarrhoea stomach pains saliva flow Systemic effects: arrhythmia cardiovascular disorders blood alterations shock collapse muscular disorders metahemoglobinemia с headaches Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Algae (Sc. cuadricauda) (Ba) 34 mg/l

Классификация: Extr. токсично

Crustaceans (Daphnia magna) (Ba) 29 mg/l

Классификация: Extr. токсично

Рыбы (Salmo gairdneri) (Ba) 158 mg/l

Классификация:

Highly токсично

Рыбы (Leuciscus Idus) (Ba) 870 mg/l

Классификация:

Highly токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

The экотоксичность is due до the ion Ba++.

The экотоксичность is due до the pH deviation.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск = ----

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Encourages eotrophy в rivers и вода channels.

Избегать попаданию вещества в почву и воду.

Dangerous for drinking вода.

Ecotoxic effects due до the pH variation.

DATA BASED on the components the preparation.

(Major component:

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: CORROSIVE LIQUID, N.O.S.

UN 1760 Класс: 8 Группа: III (E)

Морской транспорт (IMDG):

Техническое название: CORROSIVE LIQUID, N.O.S.

UN 1760 Класс: 8 Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Коррозионное Вещество жидкость, n.o.s

UN 1760 Класс: 8 Группа: III

Инструкция по упаковке: CAO 856 PAX 852

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R36/37/38 Вызывает раздражение глаз, respiratory system и skin.

S-phrase(s):

S36 Wear suitable protective clothing.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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