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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3368

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

1.2 Synonym:

1.3 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.4 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Skin Irrit. 2

STOT RE 2

Repr. 2

Asp. Tox. 1

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H315 Causes skin irritation.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H361d Suspected of damaging the unborn child.

H304 May be fatal if swallowed and enters airways.

H336 May cause drowsiness or dizziness.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

F Highly flammable

R63

R48/20

R38

R11

R65

R67

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Formula: C6H5CH3 M.= 92,14 CAS [108-88-3]

EC number (EINECS): 203-625-9

EC index number: 601-021-00-3

First aid

4.1 General indications:

4.2 Inhaling:

4.3 Contact with the skin:

4.4 Eyes:

4.5 Swallowing:

Fire-fighting means

5.1 Suitable fire-extinguishing means:

5.2 Fire-fighting means which must NOT be used:

5.3 Special risks:

5.4 Protective equipment:

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

6.2 Precautions for care of the environment:

6.3 Methods for collection/cleaning:

Handling and storage

7.1 Handling:

7.2 Storage:

Staff exposure/protection controls

8.1 Technical protective measures:

8.2 Exposure limit control:

8.3 Respiratory protection:

8.4 Hand protection:

8.5 Eye protection:

8.6 Individual hygiene measures:

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance:

Colour:

Granulometry:

Odour:

pH:

Melting point/freezing point:

Initial boiling point and boiling range:

Flash point:

Flammability (solid, gas):

Upper/lower flammability or explosive limits:

Vapour pressure:

Vapour density:

Relative density:

Solubility:

Partition coefficient: n-octanol/water:

Auto-ignition temperature:

Decomposition temperature:

Viscosity:

Stability and reactivity

10.1 Conditions which should be avoided:

10.2 Matter which should be avoided:

10.3 Hazardous decomposition products:

10.4 Complementary information:

Toxicological information

  • Acute toxicity:

  • Dangerous effects for health:

Environmental information

12.1 Mobility:

12.2 Ecotoxicity:

12.3 Degradability:

12.4 Accumulation:

12.5 Other possible effects on the environment:

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: TOLUENE

UN 1294 Class: 3 Packaging group: II (D/E)

By sea (IMDG):

Technical name: TOLUENE

UN 1294 Class: 3 Packaging group: II

By air (ICAI-IATA):

Technical name: Toluene

UN 1294 Class: 3 Packaging group: II

Packaging instructions: CAO 307 PAX 305

Regulatory information

The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.

Categorized as hydrocarbon substance.

Other information

Other precautionary statements

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P331 Do NOT induce vomiting.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R63 Possible risk of harm to the unborn child.

R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

R38 Irritating to skin.

R11 Highly flammable.

R65 Harmful: may cause lung damage if swallowed.

R67 Vapours may cause drowsiness and dizziness.

S-phrase(s):

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

S36/37 Wear suitable protective clothing and gloves.

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3368

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

1.2 Synonym:

1.3 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.4 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Skin Irrit. 2

STOT RE 2

Repr. 2

Asp. Tox. 1

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H315 Causes skin irritation.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H361d Suspected damaging the unborn child.

H304 May be fatal При попадании внутрь и enters airways.

H336 May cause drowsiness или dizziness.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

F Легко воспламеняем

R63

R48/20

R38

R11

R65

R67

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Формула: C6H5CH3 M.= 92,14 CAS [108-88-3]

Номер ЕС (EINECS): 203-625-9

ЕС индекс: 601-021-00-3

Первая помощь

4.1 Общие указания:

4.2 Вдыхание:

4.3 Контакт с кожей:

4.4 Глаза:

4.5 Попадание Внутрь:

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

5.3 Особая опасность:

5.4 Средства индивидуальной защиты:

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

6.2 Меры по защите окружающей среды:

6.3 Методы нейтрализации и очистки:

Правила обращения и хранения

7.1 Обращение:

7.2 Хранение:

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

8.2 Контроль предельно допустимого уровня воздействия:

8.3 Защита органов дыхания:

8.4 Защита рук:

8.5 Защита глаз:

8.6 Индивидуальные средства гигиены:

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид:

Цвета:

Granulometry:

Запах:

pH:

точка плавления/Температура замерзания:

Initial Точка кипения и Интервал температур кипения:

Точка воспламенения:

Flammability (solid, gas):

Верхний/нижний flammability или explosive показатели:

Давление пара:

Vapour плотность:

Relative плотность:

Растворимость:

Partition coefficient: n-октанол/вода:

Auto-ignition temperature:

Decomposition temperature:

Вязк.:

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

10.2 Вещества, которых следует избегать:

10.3 Опасные продукты разложения:

10.4 Общая информация:

Токсикологическая информация

  • Высокая токсичность:

  • Опасное воздействие на здоровье:

Информация по окружающей среде

12.1 Мобильность:

12.2 Экотоксичность:

12.3 Период Распада:

12.4 Аккумуляция:

12.5 Другие возможные воздействия на окружающую среду:

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: TOLUENE

UN 1294 Класс: 3 Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: TOLUENE

UN 1294 Класс: 3 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Toluene

UN 1294 Класс: 3 Группа: II

Инструкция по упаковке: CAO 307 PAX 305

Regulatory information

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

Categorized как hydrocarbon соединен..

Дополнительная информация

Др. precautionary statements

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P331 Do NOT Вызвать рвоту.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R63 Возможный риск вреда будущему ребенку.

R48/20 Вредный: danger serious damage до health by prolonged exposure through inhalation.

R38 Irritating до skin.

R11 Легко воспламеняем.

R65 Вредный: may cause lung damage При попадании внутрь.

R67 Vapours may cause drowsiness и dizziness.

S-phrase(s):

S62 При попадании внутрь, do not Вызвать рвоту: seek medical advice immediately и show this container или label.

S36/37 Использовать специальную защитную одежду и перчатки.

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Date published: 3.11.10

Номер рецензии и дата: 3 3.11.10




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