S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

DERQUIM OXY (Substitute of Chromic Mixture) SOLID

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Ox. Sol. 2

Acute Tox. 4

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Resp. Sens 1

Skin Sens. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P220 Keep/Store away from clothing/combustible materials.

P221 Take any precaution to avoid mixing with combustibles.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

Classification (67/548/CEE or 1999/45/CE).

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: DERQUIM OXY (Substitute of Chromic Mixture) SOLID

CAS [7727-54-0]

EC number (EINECS): 231-786-5

EC index number: 016-060-00-6

Composition:

Formula: (NH4)2S2O8 M.= 228,20 CAS [7727-54-0]

EC number (EINECS): 231-786-5

Content: >= 50 %

Classification Regulation (CE) nº 1272/2008.

Ox. Sol. 2

Acute Tox. 4

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Resp. Sens 1

Skin Sens. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P220 Keep/Store away from clothing/combustible materials.

P221 Take any precaution to avoid mixing with combustibles.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P285 In case of inadequate ventilation wear respiratory protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of soap and water. Remove contaminated clothing. In the event of irritation, seek medical assistance.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Encourages fire to break out. Keep away from combustible substances. In the event of fire, toxic fumes may form: Do not allow extinguishing water into surface or underground water courses.

5.4 Protective equipment:

Suitable clothing and footwear. Self-contained breathing equipment.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing. Ensure adequate ventilation. Do not inhale the dust.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

Ensure good ventilation and renewal of the air in the premises. Possible formation of pressure inside the container.

7.2 Storage:

Well sealed containers.In a cool, dry, well ventilated place.Room temperature.Keep away from flammable substances, sources of ignition and heat.Store separately or in an enclosure exclusively set aside for substances which are likely to ignite.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Wash hands and face before breaks and when the job is done. Use suitable work clothing. Avoid the formation of dust. Do not eat, drink or smoke in the workplace. Do not inhale the substance.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: White

Granulometry: N/A

Odour: Odourless.

pH: 3,2 ((10% sol.))

Melting point/freezing point: 120 °C

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: 582 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

Alkaline hydroxides. Flammable substances. Zinc. Aluminium. Magnesium. Iron. Copper. Hydrogen peroxide. Peroxides. Silver compounds. Metals (powder).

10.3 Hazardous decomposition products:

Carbon monoxide. Carbon dioxide. Nitrogen oxides. Sulphoxides (in case of fire).

10.4 Complementary information:

No specific data.

Toxicological information

• Acute toxicity:

LD50 oral rat : 495 mg/kg

• Dangerous effects for health:

If inhaled: Irritations to the mucosae coughing breathing difficulties Can cause spasms inflammation and oedema of the larynx, bronchi and lungs. Risk of sensitization Upon contact with the skin: irritations Risk of sensitization Through contact with the eyes: irritations If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Crustaceans (Daphnia magna) EC50 120 mg/l/48h

Classification: Very toxic

Bacteria (Ps. putida) EC10

12.1.2. - Receptor medium:

Risk for the water environment

Risk for the land environment

12.1.3. - Observations:

Ecotoxic in water environment.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Do not allow it to enter the sewage system.

Despite dilution, the compound produces toxic mixtures with water.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: AMMONIUM PERSULPHATE

UN 1444 Class: 5.1 Packaging group: III (E)

By sea (IMDG):

Technical name: AMMONIUM PERSULPHATE

UN 1444 Class: 5.1 Packaging group: III

By air (ICAI-IATA):

Technical name: Ammonium persulphate

UN 1444 Class: 5.1 Packaging group: III

Packaging instructions: CAO 563 PAX 559

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P285 In case of inadequate ventilation wear respiratory protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10