Показать русскую версию

S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

4573 Alkaline Solution (Potassium SodiumTartrate) 0,886 mol/l

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Alkaline Solution (Potassium SodiumTartrate) 0,886 mol/l

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R35

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Aqueous solution

Name: Alkaline Solution (Potassium SodiumTartrate) 0,886 mol/l

Composition:

0001: Potassium Sodium Tartrate 4-hydrate

Formula: NaK(COO)2(CHOH)2.4H2O M.= 282,23 CAS [6381-59-5]

EC number (EINECS): 206-156-8

Content: >= 1 % <= 10 %

No hazardous substance as specified in Regulation (CE) 1272/2008.

No hazardous substance as specified in Classification (67/548/CEE or 1999/45/CE).

0002: Sodium Hydroxide pellets

Formula: NaOH M.= 40,00 CAS [1310-73-2]

EC number (EINECS): 215-185-5

EC index number: 011-002-00-6

REACH Registration Number: 01-2119457892-27-XXXX

Content: >= 5 % <= 10 %

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R35 Causes severe burns.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing. Take the product out with cotton wool soaked in polyethylene-glycol 400.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.

4.5 Swallowing:

Drink large amounts of water. Avoid vomiting (there is a risk of perforation). Seek immediate medical assistance. Do not neutralize.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible. Upon contact with metals, hydrogen gas may form (there is a risk of explosion).

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes. Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water. Neutralize with diluted sulphuric acid.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.Protected from air.Room temperature.Keep away from acids.Do not store in metal containers.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

TLV-TWA(NaOH): 2 mg/m3

VLA-EC(NaOH): 2 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter P.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: N/A

Colour:

N/A

Granulometry: N/A

Odour: Odourless.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: in Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Metals. Light metals Formation of hydrogen (risk of explosion) Acids. Ammoniacal compounds (Formation of Ammonia.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

Taking the preparation' components into account, the likely dangerous characteristics are as follows: If inhaled: Burns in the mucosae. Upon contact with the skin: burns necrosis Through contact with the eyes: burns necrosis Risk of blindness (irreversible injury of the optic nerve) If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Risk of perforation in the oesophagus and stomach. Systemic effects: collapse death Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Fish (NaOH) 189 mg/l

Classification: Highly toxic

12.1.2. - Receptor medium:

Risk for the water environment

Medium

Risk for the land environment

Low

12.1.3. - Observations:

Ecotoxic for water and land organisms due to the pH deviation. Major acute effects in the dumping area.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

The treatment is neutralization.

Highly purifiable.

Do not allow it to enter soils or water channels.

Highly corrosive product.

DATA BASED on the components of the preparation.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

UN 3266 Class: 8 Packaging group: II (E)

By sea (IMDG):

Technical name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

UN 3266 Class: 8 Packaging group: II

By air (ICAI-IATA):

Technical name: Corrosive liquid, basic, inorganic, n.o.s.

UN 3266 Class: 8 Packaging group: II

Packaging instructions: CAO 855 PAX 851

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R35 Causes severe burns.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S37/39 Wear suitable gloves and eye/face protection.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

4573 Щелочных Раствор (Калий SodiumTartrate) 0,886 моль/л

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Щелочных Раствор (Калий SodiumTartrate) 0,886 моль/л

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R35

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Водный раствор

Название: Щелочных Раствор (Калий SodiumTartrate) 0,886 моль/л

Состав:

0001: Калий Натрия Тартрат 4-водный

Формула: NaK(COO)2(CHOH)2.4H2O M.= 282,23 CAS [6381-59-5]

Номер ЕС (EINECS): 206-156-8

Content: >= 1 % <= 10 %

Неопасное вещество в соответствии с регламентом (CE) 1272/2008.

Неопасное вещество как specified в Классификация (67/548/CEE или 1999/45/CE).

0002: Натрия гидроксид гранулы

Формула: NaOH M.= 40,00 CAS [1310-73-2]

Номер ЕС (EINECS): 215-185-5

ЕС индекс: 011-002-00-6

REACH Registration Number: 01-2119457892-27-XXXX

Content: >= 5 % <= 10 %

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R35 Causes severe ожоги.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды. Соберите продукт ваткой, смоченной в полиэтилен-гликоле 400.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Avoid рвота (there is a риск perforation). Обратиться немедленно за медицинской помощью. Do not neutralize.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible. Upon contact с металлы, водород gas may form (there is a риск explosion).

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары. Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды. Neutralize с diluted серная кислота.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Protected from air.Room temperature.Keep away from кислоты.Do not store в металл containers.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

TLV-TWA(NaOH): 2 мг/м3

VLA-EC(NaOH): 2 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр P.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: N/A

Цвета:

N/A

Granulometry: N/A

Запах: Без Запаха.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: в Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Металлы. Light металлы Formation водород (риск explosion) Кислоты. Ammoniacal соединен. (Formation Аммиак.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

Taking the preparation' components into account, the likely dangerous characteristics are как follows: If inhaled: Ожоги в the mucosae. Upon Контакт с кожей: ожоги necrosis Контакт с глазами: ожоги necrosis Риск blindness (irreversible injury the optic nerve) При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Риск perforation в the oesophagus и stomach. Systemic effects: collapse death Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Рыбы (NaOH) 189 mg/l

Классификация: Highly токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Средний

Риск для земли

Low

12.1.3. - Наблюдения:

Ecotoxic for вода и land organisms due до the pH deviation. Major acute effects в the dumping area.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

The treatment is neutralization.

Highly purifiable.

Избегать попаданию вещества в почву и воду.

Highly коррозионное вещество product.

DATA BASED on the components the preparation.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

UN 3266 Класс: 8 Группа: II (E)

Морской транспорт (IMDG):

Техническое название: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

UN 3266 Класс: 8 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Коррозионное Вещество жидкость, основн., неорганический, n.o.s.

UN 3266 Класс: 8 Группа: II

Инструкция по упаковке: CAO 855 PAX 851

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R35 Causes severe ожоги.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S37/39 Wear suitable gloves и eye/face protection.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




chevron-up