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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3594 Papanicolaou's Solution EA 50

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Papanicolaou's Solution EA 50

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H370 Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

Xn Harmful

F Highly flammable

R39/23/24/25

R23/24/25

R11

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Dyestuff solution

Name: Papanicolaou's Solution EA 50

Composition:

0001: Acetic Acid glacial

Formula: CH3COOH M.= 60,05 CAS [64-19-7]

EC number (EINECS): 200-580-7

EC index number: 607-002-00-6

REACH Registration Number: 01-2119475328-30-XXXX

Content: <= 0,5 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 3, Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour.

H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R10 Flammable.

R35 Causes severe burns.

0002: Methanol

Formula: CH3OH M.= 32,04 CAS [67-56-1]

EC number (EINECS): 200-659-6

EC index number: 603-001-00-X

REACH Registration Number: 01-2119433307-44-XXXX

Content: >= 80 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H370 Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

F Highly flammable

T Toxic

R11 Highly flammable.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Take the person out into the fresh air. Induce vomiting. Drink ethyl alcohol (25 ml at 50%). Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air. Risk of inflammation due to accumulation of electrostatic charges. In the event of fire, toxic fumes may form.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Room temperature.Restricted access, only authorized to technicians.Do not store in light-metal containers.Do not store in plastic containers.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-EC(methanol): 333 mg/m3

VLA-ECdermal resorption: 250 ppm

VLA-ED: 200 ppm - 266 mg/m3 dermal resorption

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter AX. Filter P3.

8.4 Hand protection:

Use suitable gloves neopren nitrile PVC

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: green with red shades

Granulometry: N/A

Odour: Methanolic.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point: 17 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 0,817

Solubility: Miscible with alcohol and water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Acid halides. Alkaline metals. Alkali-earth metals. Oxidant agents (amongst others: perchloric acid, perchlorates, halogenates, CrO3, halogen oxides, nitric acid, nitrogen oxides, non-metal oxides, chromo-sulphuric acid). Hydrides. Zinc diethyl. Halogens.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

Hygroscopic. The gases/fumes can form explosive mixtures with the air.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

Taking the preparation' components into account, the likely dangerous characteristics are as follows: If fumes inhaled: Irritations to the respiratory tracts. Upon contact with the skin: Risk of cutaneous absorption. Through contact with the eyes: irritations Due to absorption: nausea vomiting headaches vertigo intoxication sight disorders blindness (irreversible injury of the optic nerve) Systemic effects: acidosis hypotension anxiety spasms narcosis coma

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 284400 mg/l

Classification:

Toxic

Fish (Leuciscus Idus) >10000 mg/l

Classification:

Toxic

Fish (Salmo gairdneri) 8000 mg/l

Classification:

Very toxic

12.1.2. - Receptor medium:

12.1.3. - Observations:

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

DATA BASED on the components of the preparation.

(Major component:methanol).

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: FLAMMABLE LIQUID, TOXIC, N.O.S.

UN 1992 Class: 3 6.1 Packaging group: II (D/E)

By sea (IMDG):

Technical name: FLAMMABLE LIQUID, TOXIC, N.O.S.

UN 1992 Class: 3 6.1 Packaging group: II

By air (ICAI-IATA):

Technical name: Flammable liquid, toxic, n.o.s.

UN 1992 Class: 3 6.1 Packaging group: II

Packaging instructions: CAO 364 PAX 352

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R11 Highly flammable.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S36/37 Wear suitable protective clothing and gloves.

S16 Keep away from sources of ignition - No smoking.

S7 Keep container tightly closed.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3594 Papanicolaou's Раствор EA 50

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Papanicolaou's Раствор EA 50

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H370 Causes damage до organs <или state all organs affected, if known> <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

Xn Вредный

F Легко воспламеняем

R39/23/24/25

R23/24/25

R11

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Dyestuff раствор

Название: Papanicolaou's Раствор EA 50

Состав:

0001: Уксусная кислота ледян.

Формула: CH3COOH M.= 60,05 CAS [64-19-7]

Номер ЕС (EINECS): 200-580-7

ЕС индекс: 607-002-00-6

REACH Registration Number: 01-2119475328-30-XXXX

Content: <= 0,5 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 3, Skin Corr. 1A

Hazard Pictograms

Signal word

Danger

Hazard statements

H226 Воспламеняем жидкость и vapour.

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R10 Воспламеняем.

R35 Causes severe ожоги.

0002: Метанол

Формула: CH3OH M.= 32,04 CAS [67-56-1]

Номер ЕС (EINECS): 200-659-6

ЕС индекс: 603-001-00-X

REACH Registration Number: 01-2119433307-44-XXXX

Content: >= 80 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H370 Causes damage до organs <или state all organs affected, if known> <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

F Легко воспламеняем

T Токсично

R11 Легко воспламеняем.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

R39/23/24/25 Токсично: danger very serious irreversible effects through inhalation, в contact с skin и При попадании внутрь.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Переместить пострадавшего на свежий воздух. Вызвать рвоту. Drink ethyl спирт (25 ml при 50%). Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом. Существует риск воспламенения из-за образования электростатических разрядов. В случае возгорания могут образовываться токсичные пары.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.Ограничить право доступа к веществу, предоставив его только специалистам.Do not store в light-металл containers.Не хранить в пластиковых контейнерах.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC(метанол): 333 мг/м3

VLA-ECdermal resorption: 250 ppm

VLA-ED: 200 ppm - 266 мг/м3 dermal resorption

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр AX. Фильтр P3.

8.4 Защита рук:

Использовать защитные перчатки neopren nitrile PVC

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: зелен. с red shades

Granulometry: N/A

Запах: Methanolic.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения: 17 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность: (20/4) 0,817

Растворимость: Смешивается с спирт и вода

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Кислота галиды. Щелочных металлы. Щелочн.-earth металлы. Окислители (: перхлорная кислота, перхлораты, галогены, CrO3, оксиды галогенов, Азотная кислота, оксиды азота, оксиды не металлов, раствор хромового ангидрида в серной кислоте). Hydrides. Цинк diethyl. Галогены.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

Гигроскопичный. The gases/fumes can form explosive mixtures с the air.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

Taking the preparation' components into account, the likely dangerous characteristics are как follows: If fumes inhaled: Irritations до the respiratory tracts. Upon Контакт с кожей: Cуществует риск попадания в кровоток через кожные покровы. Контакт с глазами: irritations Due до absorption: тошнота рвота headaches vertigo intoxication sight disorders blindness (irreversible injury the optic nerve) Systemic effects: acidosis hypotension anxiety spasms narcosis coma

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 284400 mg/l

Классификация:

Токсично

Рыбы (Leuciscus Idus) >10000 mg/l

Классификация:

Токсично

Рыбы (Salmo gairdneri) 8000 mg/l

Классификация:

Очень токсично

12.1.2. - Воздействие на окружающую среду:

12.1.3. - Наблюдения:

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

DATA BASED on the components the preparation.

(Major component:метанол).

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: FLAMMABLE LIQUID, TOXIC, N.O.S.

UN 1992 Класс: 3 6.1 Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: FLAMMABLE LIQUID, TOXIC, N.O.S.

UN 1992 Класс: 3 6.1 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Воспламеняем жидкость, токсично, n.o.s.

UN 1992 Класс: 3 6.1 Группа: II

Инструкция по упаковке: CAO 364 PAX 352

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P307+P311 IF exposed: Call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R39/23/24/25 Токсично: danger very serious irreversible effects through inhalation, в contact с skin и При попадании внутрь.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

R11 Легко воспламеняем.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S36/37 Использовать специальную защитную одежду и перчатки.

S16 Держать на расстоянии от источников возгорания - Не курить.

S7 Keep container tightly closed.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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