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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1429 Butanone *(Methylethylketone)

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Butanone *(Methylethylketone)

Synonym:

Ethyl Methyl Ketone, MEK, Methyl Ethyl Ketone

REACH Registration Number: 01-2119457290-43-XXXX

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

EUH066 Repeated exposure may cause skin dryness or cracking.

H336 May cause drowsiness or dizziness.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

Xi Irritant

F Highly flammable

R67

R66

R36

R11

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Butanone *(Methylethylketone)

Formula: CH3COCH2CH3 M.= 72,11 CAS [78-93-3]

EC number (EINECS): 201-159-0

EC index number: 606-002-00-3

REACH Registration Number: 01-2119457290-43-XXXX

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Do not drink milk. Do not administer digestive oils. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. Risk of inflammation due to accumulation of electrostatic charges. In the event of fire, toxic fumes may form.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

VLA-EC: 300 ppm - 900 mg/m3

VLA-ED: 200 ppm - 600 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter A.

8.4 Hand protection:

Use suitable gloves latex

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Characteristic.

pH: 5,5 ((300g/l))

Melting point/freezing point: -86 °C

Initial boiling point and boiling range: 79,6 °C

Flash point: - 6 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits: 11,5 %(V) / 1,8 %(V)

Vapour pressure: 105 hPa (20 °C)

Vapour density: N/A

Relative density: (20/4) 0,805

Solubility: 290 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature: 505 °C

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Oxidant agents (amongst others: perchloric acid, perchlorates, halogenates, CrO3, halogen oxides, nitric acid, nitrogen oxides, non-metal oxides, chromo-sulphuric acid). Hydrogen peroxide. Chloroform Alkaline hydroxides.

10.3 Hazardous decomposition products:

Peroxides.

10.4 Complementary information:

The gases/fumes can form explosive mixtures with the air.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 2.737 mg/kg

LD50 skn rbt : 6.480 mg/kg

LC50 inh rat : 23500 mg/m3 8h

  • Dangerous effects for health:

Upon contact with the skin: irritations Through contact with the eyes: irritations Can have a demoisturizing effect on the skin, with the risk of secondary infection. If swallowed: Can cause nausea vomiting If it is absorbed in large quantities: effects on the central nervous system dizziness intoxication vertigo hypotension narcosis breathing difficulties cardiovascular disorders There are no definite objective conclusions regarding the carcinogenic effect of this substance.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 3426 mg/l

Classification:

Very toxic

Crustaceans (Daphnia magna) 7060 mg/l

Classification:

Very toxic

Bacteria (Ps. putida) EC0 1150 mg/l

Classification: Very toxic

Fish (Leuciscus Idus) 4600 mg/l

Classification:

Very toxic

12.1.2. - Receptor medium:

Risk for the water environment

Low

Risk for the land environment

Low

12.1.3. - Observations:

Low ecotoxicity due to its good degradability.

Acute ecotoxicity in line with the dumping concentration.

Acute ecotoxicity in the dumping area, depending on the dilution effect.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

High, over 1/3

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Easily biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Non-bioaccumulable product.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

If suitable handling conditions are maintained, no ecological problems are to be anticipated.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: ETHYL METHYL KETONE (METHYL ETHYL KETONE)

UN 1193 Class: 3 Packaging group: II (D/E)

By sea (IMDG):

Technical name: ETHYL METHYL KETONE (METHYL ETHYL KETONE)

UN 1193 Class: 3 Packaging group: II EMS 2170

By air (ICAI-IATA):

Technical name: Methyl ethyl ketone

UN 1193 Class: 3 Packaging group: II

Packaging instructions: CAO 364 PAX 353

Regulatory information

The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.

Other information

Other precautionary statements

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P337+P313 If eye irritation persists: Get medical advice/attention.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R67 Vapours may cause drowsiness and dizziness.

R66 Repeated exposure may cause skin dryness or cracking.

R36 Irritating to eyes.

R11 Highly flammable.

S-phrase(s):

S16 Keep away from sources of ignition - No smoking.

S9 Keep container in a well-ventilated place.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1429 Butanone *(Methylethylketone)

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Butanone *(Methylethylketone)

Synonym:

Ethyl Метил Ketone, MEK, Метил Ethyl Ketone

REACH Registration Number: 01-2119457290-43-XXXX

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H319 Causes serious eye irritation.

EUH066 Repeated exposure may cause skin dryness или cracking.

H336 May cause drowsiness или dizziness.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

Xi Irritant

F Легко воспламеняем

R67

R66

R36

R11

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Butanone *(Methylethylketone)

Формула: CH3COCH2CH3 M.= 72,11 CAS [78-93-3]

Номер ЕС (EINECS): 201-159-0

ЕС индекс: 606-002-00-3

REACH Registration Number: 01-2119457290-43-XXXX

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Do not drink milk. Do not administer digestive oils. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Существует риск воспламенения из-за образования электростатических разрядов. В случае возгорания могут образовываться токсичные пары.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC: 300 ppm - 900 мг/м3

VLA-ED: 200 ppm - 600 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A.

8.4 Защита рук:

Использовать защитные перчатки latex

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH: 5,5 ((300g/l))

точка плавления/Температура замерзания: -86 °C

Initial Точка кипения и Интервал температур кипения: 79,6 °C

Точка воспламенения: - 6 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 11,5 %(V) / 1,8 %(V)

Давление пара: 105 hPa (20 °C)

Vapour плотность: N/A

Relative плотность: (20/4) 0,805

Растворимость: 290 г/л в воде20 °C

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature: 505 °C

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Окислители (: перхлорная кислота, перхлораты, галогены, CrO3, оксиды галогенов, Азотная кислота, оксиды азота, оксиды не металлов, раствор хромового ангидрида в серной кислоте). Водорода пероксид. Хлороформ Щелочных hydroxides.

10.3 Опасные продукты разложения:

Пероксиды.

10.4 Общая информация:

The gases/fumes can form explosive mixtures с the air.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 2.737 мг/кг

LD50 skn rbt : 6.480 мг/кг

LC50 inh rat : 23500 мг/м3 8h

  • Опасное воздействие на здоровье:

Upon Контакт с кожей: irritations Контакт с глазами: irritations Can have a demoisturizing effect on the skin, с the риск secondary infection. При попадании внутрь: Can cause тошнота рвота При попадании в больших количествах: effects on the central nervous system dizziness intoxication vertigo hypotension narcosis затруднение дыхания cardiovascular disorders There are no definite objective conclusions regarding the carcinogenic effect this соединен..

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 3426 mg/l

Классификация:

Очень токсично

Crustaceans (Daphnia magna) 7060 mg/l

Классификация:

Очень токсично

Бактерии (Ps. putida) EC0 1150 mg/l

Классификация: Очень токсично

Рыбы (Leuciscus Idus) 4600 mg/l

Классификация:

Очень токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Low

Риск для земли

Low

12.1.3. - Наблюдения:

Low экотоксичность due до its good период распада.

Acute экотоксичность в line с the dumping концентрация.

Acute экотоксичность в the dumping area, зависит от the dilution effect.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

Высокий, над 1/3

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Легко biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Non-bioaccumulable product.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

При правильном обращении с продуктом не вызывает угрозу окружающей среде.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: ETHYL METHYL KETONE (METHYL ETHYL KETONE)

UN 1193 Класс: 3 Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: ETHYL METHYL KETONE (METHYL ETHYL KETONE)

UN 1193 Класс: 3 Группа: II EMS 2170

Авиа транспорт (ICAI-IATA):

Техническое название: Метил ethyl ketone

UN 1193 Класс: 3 Группа: II

Инструкция по упаковке: CAO 364 PAX 353

Regulatory information

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

Дополнительная информация

Др. precautionary statements

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P337+P313 If eye irritation persists: Get medical advice/attention.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R67 Vapours may cause drowsiness и dizziness.

R66 Repeated exposure may cause skin dryness или cracking.

R36 Вызывает раздражение глаз.

R11 Легко воспламеняем.

S-phrase(s):

S16 Держать на расстоянии от источников возгорания - Не курить.

S9 Keep container в a well-ventilated place.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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