S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
4850 Bromine Index AMCS solution
Identification of the substance/preparation and of the company or firm | ||||
1.1 Identification of the substance or preparation Name: Bromine Index AMCS solution
Synonym:
REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: | ||||
For laboratory utilisation, analysis, research and fine chemistry.
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008.
Flam. Liq. 2 Skin Corr. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Carc. 2 STOT RE 1 Ozone
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Hazard Pictograms
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Signal word Danger
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Hazard statements H225 Highly flammable liquid and vapour. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>. H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. EUH059 Hazardous to the ozone layer.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Classification (67/548/CEE or 1999/45/CE).
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For the full text of the R-phrases mentioned in this section, see section 16. | ||||
Component Composition/Information | ||||
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Name: Bromine Index AMCS solution | ||||
Composition:
0001: Methanol
Formula: CH3OH M.= 32,04 CAS [67-56-1] EC number (EINECS): 200-659-6 EC index number: 603-001-00-X REACH Registration Number: 01-2119433307-44-XXXX
Content: >= 10 % <= 20 %
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Classification Regulation (CE) nº 1272/2008.
Flam. Liq. 2 Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 STOT SE 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H225 Highly flammable liquid and vapour. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H370 Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P307+P311 IF exposed: Call a POISON CENTER or doctor/physician. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
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Classification (67/548/CEE or 1999/45/CE).
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0002: Carbon Tetrachloride
Formula: CCl4 M.= 153,82 CAS [56-23-5] EC number (EINECS): 200-262-8 EC index number: 602-008-00-5
Content: >= 10 % <= 20 %
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Classification Regulation (CE) nº 1272/2008.
Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Carc. 2 STOT RE 1 Ozone Aquatic Chronic 3
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Hazard Pictograms
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Signal word Danger
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Hazard statements H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>. H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. EUH059 Hazardous to the ozone layer. H412 Harmful to aquatic life with long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/attention. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Classification (67/548/CEE or 1999/45/CE).
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0003: Sulphuric Acid 25%
Formula: H2SO4 M.= 98,08 CAS [7664-93-9] EC number (EINECS): 231-639-5 EC index number: 016-020-00-8
Content: >= 1 % <= 3 %
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Classification Regulation (CE) nº 1272/2008.
Skin Corr. 1A
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Hazard Pictograms
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Signal word Danger
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Hazard statements H314 Causes severe skin burns and eye damage.
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Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P405 Store locked up.
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Classification (67/548/CEE or 1999/45/CE).
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0004: Acetic Acid glacial
Formula: CH3COOH M.= 60,05 CAS [64-19-7] EC number (EINECS): 200-580-7 EC index number: 607-002-00-6 REACH Registration Number: 01-2119475328-30-XXXX
Content: >= 65 % <= 75 %
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Classification Regulation (CE) nº 1272/2008.
Flam. Liq. 3, Skin Corr. 1A
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Hazard Pictograms
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Signal word Danger
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Hazard statements H226 Flammable liquid and vapour. H314 Causes severe skin burns and eye damage.
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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
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Classification (67/548/CEE or 1999/45/CE).
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First aid
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4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air. In the event sickness persists, seek medical assistance.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.
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4.5 Swallowing: Drink large amounts of water. Avoid vomiting (there is a risk of perforation). Seek immediate medical assistance. Do not neutralize.
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Fire-fighting means
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5.1 Suitable fire-extinguishing means: Water. Carbon dioxide (CO2). Foam. Dry powder.
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5.2 Fire-fighting means which must NOT be used: No specific data.
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5.3 Special risks: Combustible. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air. In the event of fire, fumes may form: acetic acid.
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5.4 Protective equipment: Suitable clothing and footwear. Self-contained breathing equipment.
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: Do not inhale the fumes. Avoid contact with the skin, eyes or clothing.
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6.2 Precautions for care of the environment: Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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Handling and storage
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7.1 Handling: No special indications.
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7.2 Storage: Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Room temperature.Restricted access, only authorized to technicians.
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Staff exposure/protection controls
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8.1 Technical protective measures: No special indications.
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8.2 Exposure limit control: VLA-EC(referring to acetic acid).: 15 ppm - 37 mg/m3 VLA-ED(referring to acetic acid).: 10 ppm - 25 mg/m3
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8.3 Respiratory protection: In the event of fumes forming/aerosols, use suitable respiratory protection. Filter B. Filter P.
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8.4 Hand protection: Use suitable gloves neopren nitrile
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | ||||
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Physical and chemical properties
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Appearance: liquid | ||||
Colour: Colourless | ||||
Granulometry: N/A | ||||
Odour: Piquant. | ||||
pH: N/A | ||||
Melting point/freezing point: N/A | ||||
Initial boiling point and boiling range: N/A | ||||
Flash point: N/A | ||||
Flammability (solid, gas): N/A | ||||
Upper/lower flammability or explosive limits: N/A | ||||
Vapour pressure: N/A | ||||
Vapour density: N/A | ||||
Relative density: (20/4) 1,1 | ||||
Solubility: N/A | ||||
Partition coefficient: n-octanol/water: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Viscosity: N/A | ||||
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Stability and reactivity
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10.1 Conditions which should be avoided: High temperatures.
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10.2 Matter which should be avoided: Anhydrides. Water. Aldehydes. Alcohols. Halogen halides. Oxidant agents (amongst others: perchloric acid, perchlorates, halogenates, CrO3, halogen oxides, nitric acid, nitrogen oxides, non-metal oxides, chromo-sulphuric acid). Metals. Alkaline hydroxides. Non-metal halides. Ethanolamine.
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10.3 Hazardous decomposition products: No specific data.
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10.4 Complementary information: No specific data.
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Toxicological information
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LD50 oral rat : 3.310 mg/kg (refers to the component with the highest toxicity) LD50 skn rbt : 1.060 mg/kg
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If fumes inhaled: Irritations to the respiratory tracts. Very corrosive substance. Can cause bronchopneumonia oedemas in the respiratory tract Upon contact with the skin: burns Through contact with the eyes: burns sight disorders blindness (irreversible injury of the optic nerve) Burns in the mucosae. If swallowed: Burns in the oesophagus and stomach. spasms vomiting breathing difficulties Risk of perforation in the oesophagus and stomach. Risk of aspiration upon vomiting. The following cannot be ruled out: shock cardiovascular failure acidosis kidney problems Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
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12.1 Toxicity: 12.1.1 - EC50 test (mg/l): Fish (Leuciscus Idus) 410 mg/l Classification: Highly toxic Fish (L. Macrochirus) 75 mg/l Classification: Extr. toxic Crustaceans (Daphnia magna) 47 mg/l Classification: Extr. toxic Bacteria (Photobacterium phosphoreum) 11 mg/l Classification: Extr. toxic 12.1.2. - Receptor medium: Risk for the water environment High Risk for the land environment Medium 12.1.3. - Observations: Highly toxic in water environments. Affects fish, micro-crustaceans and bacteria due to pH deviation. Acute ecotoxicity in line with the dumping concentration.
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12.2 Persistence and Degradability : 12.2.1 - Test: 12.2.2. - Biotic degradation classification: BOD5 0,88 g/g BOD5/COD Biodegradability 12.2.3. - Abiotic degradation depending on pH: 12.2.4. - Observations: Biodegradable product.
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12.3 Bioaccumulative potential: 12.3.1. - Test: 12.3.2. - Bioaccumulation: Risk 12.3.3. - Observations: Non-bioaccumulable product.
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12.4 Mobility in soil : Repartition: log P(oct)= -0,31
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12.5 Assessment PBT and MPMB : Data not available.
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12.6 Other possible effects on the environment: Do not allow it to enter soils or water channels. DATA BASED on the components of the preparation. (Major component: acetic acid).
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Considerations regarding elimination
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13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
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Overland (ADR): Technical name: CORROSIVE LIQUID, TOXIC, N.O.S. UN 2922 Class: 8 6.1 CONTAM. MAR Packaging group: II (E) | ||||
By sea (IMDG): Technical name: CORROSIVE LIQUID, TOXIC, N.O.S. UN 2922 Class: 8 6.1 CONTAM. MAR Packaging group: II | ||||
By air (ICAI-IATA): Technical name: Corrosive liquid, toxic, n.o.s. UN 2922 Class: 8 6.1 CONTAM. MAR Packaging group: II | ||||
Packaging instructions: CAO 855 PAX 851 | ||||
Regulatory information
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The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.
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Other information
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Other precautionary statements P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P338 Remove contact lenses, if present and easy to do. Continue rinsing. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
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Labelling (65/548/CEE or 1999/45/CE) | ||||
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Review number and date: 3 3.11.10 Date published: 3.11.10 In respect of the previous review, changes have been made to the following sections: 2, 3, 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
4850 Бром Index AMCS раствор
Определение вещества/preparation и the company или firm | ||||
1.1 Определение вещества или preparation Название: Бром Index AMCS раствор
Synonym:
REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use вещества/preparation: | ||||
Для общелабораторного использования, анализов, исследований и тонкой химии.
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1.3 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
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Классификация вещества или the mixture.
| ||||
Классификация Regulation (CE) nº 1272/2008.
Flam. Liq. 2 Skin Corr. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Carc. 2 STOT RE 1 Ozone
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Hazard Pictograms
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Signal word Danger
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Hazard statements H225 Легко воспламеняем жидкость и vapour. H314 Causes severe skin ожоги и eye damage. H331 Токсично if inhaled. H311 Токсично в contact с skin. H301 Токсично При попадании внутрь. H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>. H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. EUH059 Hazardous до the ozone layer.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить. P233 Keep container tightly closed. P240 Ground/bond container и receiving equipment. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация (67/548/CEE или 1999/45/CE).
| ||||
For the full text the R-выражения mentioned в this section, see section 16. | ||||
Сведения о компонентах и состав | ||||
| ||||
Название: Бром Index AMCS раствор | ||||
Состав:
0001: Метанол
Формула: CH3OH M.= 32,04 CAS [67-56-1] Номер ЕС (EINECS): 200-659-6 ЕС индекс: 603-001-00-X REACH Registration Number: 01-2119433307-44-XXXX
Content: >= 10 % <= 20 %
| ||||
Классификация Regulation (CE) nº 1272/2008.
Flam. Liq. 2 Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 STOT SE 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H225 Легко воспламеняем жидкость и vapour. H331 Токсично if inhaled. H311 Токсично в contact с skin. H301 Токсично При попадании внутрь. H370 Causes damage до organs <или state all organs affected, if known> <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.
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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить. P233 Keep container tightly closed. P240 Ground/bond container и receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P243 Take precautionary measures against static discharge. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P307+P311 IF exposed: Call a POISON CENTER или doctor/physician. P311 Call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370+P378 В case fire: Use for extinction. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P403+P235 Store в a well-ventilated place. Keep cool. P405 Store locked up.
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Классификация (67/548/CEE или 1999/45/CE).
| ||||
0002: Тетрахлоруглерод
Формула: CCl4 M.= 153,82 CAS [56-23-5] Номер ЕС (EINECS): 200-262-8 ЕС индекс: 602-008-00-5
Content: >= 10 % <= 20 %
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Классификация Regulation (CE) nº 1272/2008.
Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Carc. 2 STOT RE 1 Ozone Aquatic Chronic 3
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Hazard Pictograms
| ||||
Signal word Danger
| ||||
Hazard statements H331 Токсично if inhaled. H311 Токсично в contact с skin. H301 Токсично При попадании внутрь. H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>. H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. EUH059 Hazardous до the ozone layer. H412 Вредный до aquatic life с long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal Средства индивидуальной защиты как required. P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P308+P313 IF exposed или concerned: Get medical advice/attention. P311 Call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Классификация (67/548/CEE или 1999/45/CE).
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0003: серная кислота 25%
Формула: H2SO4 M.= 98,08 CAS [7664-93-9] Номер ЕС (EINECS): 231-639-5 ЕС индекс: 016-020-00-8
Content: >= 1 % <= 3 %
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Классификация Regulation (CE) nº 1272/2008.
Skin Corr. 1A
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Hazard Pictograms
| ||||
Signal word Danger
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Hazard statements H314 Causes severe skin ожоги и eye damage.
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Precautionary statements P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P310 Immediately call a POISON CENTER или doctor/physician. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present и easy до do. Continue rinsing. P363 Wash contaminated clothing before reuse. P405 Store locked up.
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Классификация (67/548/CEE или 1999/45/CE).
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0004: Уксусная кислота ледян.
Формула: CH3COOH M.= 60,05 CAS [64-19-7] Номер ЕС (EINECS): 200-580-7 ЕС индекс: 607-002-00-6 REACH Registration Number: 01-2119475328-30-XXXX
Content: >= 65 % <= 75 %
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Классификация Regulation (CE) nº 1272/2008.
Flam. Liq. 3, Skin Corr. 1A
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Hazard Pictograms
| ||||
Signal word Danger
| ||||
Hazard statements H226 Воспламеняем жидкость и vapour. H314 Causes severe skin ожоги и eye damage.
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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить. P233 Keep container tightly closed. P240 Ground/bond container и receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P243 Take precautionary measures against static discharge. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P310 Immediately call a POISON CENTER или doctor/physician. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present и easy до do. Continue rinsing. P363 Wash contaminated clothing before reuse. P370+P378 В case fire: Use for extinction. P403+P235 Store в a well-ventilated place. Keep cool. P405 Store locked up.
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Классификация (67/548/CEE или 1999/45/CE).
| ||||
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Первая помощь
| ||||
4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.
| ||||
4.5 Попадание Внутрь: Выпить большое количество воды. Avoid рвота (there is a риск perforation). Обратиться немедленно за медицинской помощью. Do not neutralize.
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Меры и средства обеспечения пожаро- и взрывобезопасности
| ||||
5.1 Пригодные средства пожаротушения: Вода. Углекислый газ (CO2). Пена. Песок.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used: No specific data.
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5.3 Особая опасность: Горючее Вещество. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом. В the event fire, fumes may form: Уксусная кислота.
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5.4 Средства индивидуальной защиты: Специальная одежда и обувь. Средства индивидуальной защиты дыхательных путей.
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
| ||||
6.1 Индивидуальные меры предосторожности: Не вдыхать пары. Avoid Контакт с кожей, глаза или clothing.
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6.2 Меры по защите окружающей среды: Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.
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Правила обращения и хранения
| ||||
7.1 Обращение: Специальные указания отсутствуют.
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7.2 Хранение: В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Room temperature.Ограничить право доступа к веществу, предоставив его только специалистам.
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Требования по охране труда и меры по обеспечению безопасности персонала
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8.1 Технические меры защиты: Специальные указания отсутствуют.
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8.2 Контроль предельно допустимого уровня воздействия: VLA-EC(referring до Уксусная кислота).: 15 ppm - 37 мг/м3 VLA-ED(referring до Уксусная кислота).: 10 ppm - 25 мг/м3
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр B. Фильтр P.
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8.4 Защита рук: Использовать защитные перчатки neopren nitrile
| ||||
8.5 Защита глаз: Использовать защитные очки.
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.
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8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | ||||
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Физико-химические свойства
| ||||
Внешний Вид: жидкость | ||||
Цвета: Бесцветная | ||||
Granulometry: N/A | ||||
Запах: Piquant. | ||||
pH: N/A | ||||
точка плавления/Температура замерзания: N/A | ||||
Initial Точка кипения и Интервал температур кипения: N/A | ||||
Точка воспламенения: N/A | ||||
Flammability (solid, gas): N/A | ||||
Верхний/нижний flammability или explosive показатели: N/A | ||||
Давление пара: N/A | ||||
Vapour плотность: N/A | ||||
Relative плотность: (20/4) 1,1 | ||||
Растворимость: N/A | ||||
Partition coefficient: n-октанол/вода: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Вязк.: N/A | ||||
| ||||
Стабильность и реакционноспособность
| ||||
10.1 Условия, которых следует избегать: Высокий temperatures.
| ||||
10.2 Вещества, которых следует избегать: Anhydrides. Вода. Альдегид.. Спирт.. Halogen галиды. Окислители (: перхлорная кислота, перхлораты, галогены, CrO3, оксиды галогенов, Азотная кислота, оксиды азота, оксиды не металлов, раствор хромового ангидрида в серной кислоте). Металлы. Щелочных hydroxides. Non-металл галиды. Ethanolamine.
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10.3 Опасные продукты разложения: No specific data.
| ||||
10.4 Общая информация: No specific data.
| ||||
Токсикологическая информация
| ||||
LD50 oral rat : 3.310 мг/кг (refers до the component с the highest toxicity) LD50 skn rbt : 1.060 мг/кг
| ||||
If fumes inhaled: Irritations до the respiratory tracts. Very коррозионное вещество соединен.. Can cause bronchopneumonia oedemas в the respiratory tract Upon Контакт с кожей: ожоги Контакт с глазами: ожоги sight disorders blindness (irreversible injury the optic nerve) Ожоги в the mucosae. При попадании внутрь: Ожоги в the oesophagus и stomach. spasms рвота затруднение дыхания Риск perforation в the oesophagus и stomach. Риск aspiration upon рвота. The following cannot be ruled out: shock cardiovascular failure acidosis kidney problems Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
| ||||
Информация по окружающей среде
| ||||
12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): Рыбы (Leuciscus Idus) 410 mg/l Классификация: Highly токсично Рыбы (L. Macrochirus) 75 mg/l Классификация: Extr. токсично Crustaceans (Daphnia magna) 47 mg/l Классификация: Extr. токсично Бактерии (Photobacterium phosphoreum) 11 mg/l Классификация: Extr. токсично 12.1.2. - Воздействие на окружающую среду: Риск для водной среды Высокий Риск для земли Средний 12.1.3. - Наблюдения: Highly токсично в воде environments. Affects рыбы, micro-crustaceans и бактерии due до pH deviation. Acute экотоксичность в line с the dumping концентрация.
| ||||
12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Классификация биотического периода распада: BOD5 0,88 g/g BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от рН: 12.2.4. - Наблюдения: Biodegradable product.
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения: Non-bioaccumulable product.
| ||||
12.4 Мобильность в soil : Repartition: log P(oct)= -0,31
| ||||
12.5 Assessment PBT и MPMB : Нет данных.
| ||||
12.6 Другие возможные воздействия на окружающую среду: Избегать попаданию вещества в почву и воду. DATA BASED on the components the preparation. (Major component: Уксусная кислота).
| ||||
| ||||
Правила утилизации
| ||||
13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
.
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13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
| ||||
Информация относительно транспорта
| ||||
Автотранспорт (ADR): Техническое название: CORROSIVE LIQUID, TOXIC, N.O.S. UN 2922 Класс: 8 6.1 CONTAM. MAR Группа: II (E) | ||||
Морской транспорт (IMDG): Техническое название: CORROSIVE LIQUID, TOXIC, N.O.S. UN 2922 Класс: 8 6.1 CONTAM. MAR Группа: II | ||||
Авиа транспорт (ICAI-IATA): Техническое название: Коррозионное Вещество жидкость, токсично, n.o.s. UN 2922 Класс: 8 6.1 CONTAM. MAR Группа: II | ||||
Инструкция по упаковке: CAO 855 PAX 851 | ||||
Regulatory information
| ||||
The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.
| ||||
| ||||
Дополнительная информация
| ||||
Др. precautionary statements P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal Средства индивидуальной защиты как required. P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P308+P313 IF exposed или concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER или doctor/physician. P311 Call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P338 Remove contact lenses, if present и easy до do. Continue rinsing. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370+P378 В case fire: Use for extinction. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P403+P235 Store в a well-ventilated place. Keep cool. P405 Store locked up.
| ||||
Labelling (65/548/CEE или 1999/45/CE) | ||||
| ||||
| ||||
Номер рецензии и дата: 3 3.11.10 Date published: 3.11.10 Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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