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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

A868 Sodium Methylate solution ~30% *in methanol

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Sodium Methylate solution ~30% *in methanol

Synonym:

Sodium Methoxide

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Skin Corr. 1B

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H370 Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

T Toxic

F Highly flammable

R34

R39/23/24/25

R23/24/25

R11

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Sodium Methylate solution ~30% *in methanol

Formula: CH3ONa M.= 54,02 CAS [124-41-4]

EC number (EINECS): 204-699-5

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed to provide artificial respiration. In case of loss of consciousness, position the person lying on his/her side. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing. Take the product out with cotton wool soaked in polyethylene-glycol 400.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.

4.5 Swallowing:

Drink lemon juice, vinegar or milk mixed with raw eggs. Subsequently, drink large amounts of water. Drink lemon juice, vinegar or milk mixed with raw eggs. Subsequently, drink large amounts of water. Avoid vomiting (there is a risk of perforation). Avoid vomiting (there is a risk of perforation).

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Carbon dioxide (CO2). Dry powder. Smother with dry earth or sand.

5.2 Fire-fighting means which must NOT be used:

Water. Foam.

5.3 Special risks:

Combustible. Keep away from sources of ignition. Keep the workplace dry. The substance must not come into contact with water.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

Avoid the formation of electrostatic charges. Limited shelf-life.

7.2 Storage:

Well sealed containers.Dry atmosphere.Away from sources of ignition and heat.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Characteristic.

pH: 7

Melting point/freezing point: -20 °C

Initial boiling point and boiling range: 81 °C

Flash point: 12 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits: 26,5 %(V) / 5,5 %(V)

Vapour pressure: 150 hPa (50 °C)

Vapour density: N/A

Relative density: (20/4) 0,97

Solubility: in Reacts violently with water and ethanol. Miscible with ether, chloroform or benzene

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature: 240 °C

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

Moisture-sensitive. Light-sensitive.

10.2 Matter which should be avoided:

Water. Acids.

10.3 Hazardous decomposition products:

Caustic bases. Methanol.

10.4 Complementary information:

Moisture sensitive. Exposure to air encourages decomposition.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

No specific data on this product known with regard to effects of overdose in humans. If fumes inhaled: Irritations to the mucosae coughing breathing difficulties Upon contact with the skin: burns Through contact with the eyes: burns If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

12.1.2. - Receptor medium:

Risk for the water environment

Risk for the land environment

12.1.3. - Observations:

Ecotoxic data not available.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Environmental risks cannot be excluded if used and/or disposed of inappropriately.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: SODIUM METHYLATE SOLUTION in alcohol

UN 1289 Class: 3 8 Packaging group: II (D/E)

By sea (IMDG):

Technical name: SODIUM METHYLATE SOLUTION in alcohol

UN 1289 Class: 3 8 Packaging group: II

By air (ICAI-IATA):

Technical name: Sodium methylate solution

UN 1289 Class: 3 8 Packaging group: II

Packaging instructions: CAO 363 PAX 352

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P243 Take precautionary measures against static discharge.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

P310 Immediately call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R34 Causes burns.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R11 Highly flammable.

S-phrase(s):

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37 Wear suitable protective clothing and gloves.

S16 Keep away from sources of ignition - No smoking.

S7 Keep container tightly closed.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

A868 Натрия Methylate раствор ~30% *в метанол

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Натрия Methylate раствор ~30% *в метанол

Synonym:

Натрия Methoxide

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

STOT SE 1

Skin Corr. 1B

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H370 Causes damage до organs <или state all organs affected, if known> <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H314 Causes severe skin ожоги и eye damage.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

T Токсично

F Легко воспламеняем

R34

R39/23/24/25

R23/24/25

R11

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Натрия Methylate раствор ~30% *в метанол

Формула: CH3ONa M.= 54,02 CAS [124-41-4]

Номер ЕС (EINECS): 204-699-5

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed до provide artificial respiration. В case loss consciousness, position the person lying on his/her side. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды. Соберите продукт ваткой, смоченной в полиэтилен-гликоле 400.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.

4.5 Попадание Внутрь:

Drink lemon juice, vinegar или milk mixed с raw eggs. Subsequently, Выпить большое количество воды. Drink lemon juice, vinegar или milk mixed с raw eggs. Subsequently, Выпить большое количество воды. Avoid рвота (there is a риск perforation). Avoid рвота (there is a риск perforation).

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Углекислый газ (CO2). Песок. Smother с безводн. earth или sand.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

Вода. Пена.

5.3 Особая опасность:

Горючее Вещество. Держать на расстоянии от источников возгорания. Keep the workplace безводн.. The соединен. must not come into contact с водой.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Избегать образования электростатических разрядов. Limited shelf-life.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Вдали от источников возгорания и тепла.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

: Нет данных.

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH: 7

точка плавления/Температура замерзания: -20 °C

Initial Точка кипения и Интервал температур кипения: 81 °C

Точка воспламенения: 12 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 26,5 %(V) / 5,5 %(V)

Давление пара: 150 hPa (50 °C)

Vapour плотность: N/A

Relative плотность: (20/4) 0,97

Растворимость: в Reacts violently с водой и этанол. Смешивается с эфир, хлороформ или бензол

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature: 240 °C

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Moisture-sensitive. Light-sensitive.

10.2 Вещества, которых следует избегать:

Вода. Кислоты.

10.3 Опасные продукты разложения:

Caustic основан.. Метанол.

10.4 Общая информация:

Moisture sensitive. Exposure до air encourages decomposition.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

Никаких конкретных данных об этом продукте не известно в связи с последствиями передозировки у людей. If fumes inhaled: Irritations до the mucosae coughing затруднение дыхания Upon Контакт с кожей: ожоги Контакт с глазами: ожоги При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Риск для земли

12.1.3. - Наблюдения:

Ecotoxic Нет данных.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Environmental risks cannot be excluded if used и/или disposed inappropriately.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: SODIUM METHYLATE SOLUTION в спирт

UN 1289 Класс: 3 8 Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: SODIUM METHYLATE SOLUTION в спирт

UN 1289 Класс: 3 8 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Натрия methylate раствор

UN 1289 Класс: 3 8 Группа: II

Инструкция по упаковке: CAO 363 PAX 352

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P243 Take precautionary measures against static discharge.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P307+P311 IF exposed: Call a POISON CENTER или doctor/physician.

P310 Immediately call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R34 Может вызвать ожоги.

R39/23/24/25 Токсично: danger very serious irreversible effects through inhalation, в contact с skin и При попадании внутрь.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

R11 Легко воспламеняем.

S-phrase(s):

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

S36/37 Использовать специальную защитную одежду и перчатки.

S16 Держать на расстоянии от источников возгорания - Не курить.

S7 Keep container tightly closed.

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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