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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1833 Phosphorus penta-Chloride

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Phosphorus penta-Chloride

Synonym:

Phosphorus(V) Chloride

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 4

Acute Tox. 2

Skin Corr. 1B

STOT RE 2

Hazard Pictograms

Signal word

Danger

Hazard statements

EUH014 Reacts violently with water.

H302 Harmful if swallowed.

H330 Fatal if inhaled.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

T+ Very toxic

R34

R26

R22

R14

R48/20

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Phosphorus penta-Chloride

Formula: PCl5 M.= 208,24 CAS [10026-13-8]

EC number (EINECS): 233-060-3

EC index number: 015-008-00-X

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.

4.5 Swallowing:

Drink large amounts of water. Avoid vomiting (there is a risk of perforation). Seek immediate medical assistance. Do not neutralize.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Dry powder. Carbon dioxide (CO2). Smother with dry earth or sand.

5.2 Fire-fighting means which must NOT be used:

Water.

5.3 Special risks:

Incombustible. Keep the workplace dry. The substance must not come into contact with water. In the event of fire, toxic fumes may form.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

No special indications.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Carry out the operation with maximum precaution.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.Restricted access, only authorized to technicians.In a cool place.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-ED: 0,1 ppm - 0,9 mg/m3

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: Yellow

Granulometry: N/A

Odour: Unpleasant, characteristic.

pH:

N/A

Melting point/freezing point: 162 °C

Initial boiling point and boiling range: 167 °C

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: in Breaks down violently in water.

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Water. Alcohols. Alkaline solutions. Acids. Amines. Alkaline metals. Strong oxidant agents.

10.3 Hazardous decomposition products:

Hydrogen chloride. Phosphorus oxides. Toxic gases.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 660 mg/kg

LC50 oral rat : 660 mg/kg

LC50 inh rat : 205 mg/m3 1h

  • Dangerous effects for health:

The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Very corrosive substance. Causes Burns in the mucosae, skin and eyes If fumes inhaled: breathing difficulties Can cause bronchitis pneumonia. Upon contact with the skin: burns Through contact with the eyes: burns sight disorders blindness (irreversible injury of the optic nerve) If swallowed: Burns in the oesophagus and stomach. Can cause perforation in the oesophagus and stomach. Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

12.1.2. - Receptor medium:

Risk for the water environment

Risk for the land environment

Ecotoxic data not available.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Encourages eotrophy in rivers and water channels.

Do not allow it to enter soils or water channels.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: PHOSPHORUS PENTACHLORIDE

UN 1806 Class: 8 Packaging group: II (E)

By sea (IMDG):

Technical name: PHOSPHORUS PENTACHLORIDE

UN 1806 Class: 8 Packaging group: II

By air (ICAI-IATA):

Technical name: Phosphorus Pentachloride

UN 1806 Class: 8 Packaging group: II

Packaging instructions: CAO 863 PAX F

Regulatory information

The substance is subject to Council Regulation (EC) No 1334/2000 of 22 June 2000 setting up a Community regime for the control of exports of dual-use items and technology.

Other information

Other precautionary statements

P284 Wear respiratory protection.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P314 Get medical advice/attention if you feel unwell.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R34 Causes burns.

R26 Very toxic by inhalation.

R22 Harmful if swallowed.

R14 Reacts violently with water.

R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S7/8 Keep container tightly closed and dry.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1833 Phosphorus penta-Хлорид

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Phosphorus penta-Хлорид

Synonym:

Phosphorus(V) Хлорид

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 4

Acute Tox. 2

Skin Corr. 1B

STOT RE 2

Hazard Pictograms

Signal word

Danger

Hazard statements

EUH014 Reacts violently с водой.

H302 Вредный При попадании внутрь.

H330 Fatal if inhaled.

H314 Causes severe skin ожоги и eye damage.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

T+ Очень токсично

R34

R26

R22

R14

R48/20

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Phosphorus penta-Хлорид

Формула: PCl5 M.= 208,24 CAS [10026-13-8]

Номер ЕС (EINECS): 233-060-3

ЕС индекс: 015-008-00-X

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Avoid рвота (there is a риск perforation). Обратиться немедленно за медицинской помощью. Do not neutralize.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Песок. Углекислый газ (CO2). Smother с безводн. earth или sand.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

Вода.

5.3 Особая опасность:

Incombustible. Keep the workplace безводн.. The соединен. must not come into contact с водой. В случае возгорания могут образовываться токсичные пары.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Специальные указания отсутствуют.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Carry out the operation с maximum precaution.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Ограничить право доступа к веществу, предоставив его только специалистам.В прохладном помещении.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-ED: 0,1 ppm - 0,9 мг/м3

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Желт.

Granulometry: N/A

Запах: Unpleasant, характерный.

pH:

N/A

точка плавления/Температура замерзания: 162 °C

Initial Точка кипения и Интервал температур кипения: 167 °C

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: в Breaks down violently в воде.

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Вода. Спирт.. Щелочных solutions. Кислоты. Амины. Щелочных металлы. Strong Окислители.

10.3 Опасные продукты разложения:

Водород хлорид. Phosphorus oxides. Токсично gases.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 660 мг/кг

LC50 oral rat : 660 мг/кг

LC50 inh rat : 205 мг/м3 1h

  • Опасное воздействие на здоровье:

The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Very коррозионное вещество соединен.. Может вызвать ожоги в the mucosae, skin и глаза If fumes inhaled: затруднение дыхания Can cause bronchitis pneumonia. Upon Контакт с кожей: ожоги Контакт с глазами: ожоги sight disorders blindness (irreversible injury the optic nerve) При попадании внутрь: Ожоги в the oesophagus и stomach. Can cause perforation в the oesophagus и stomach. Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Риск для земли

Ecotoxic Нет данных.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Encourages eotrophy в rivers и вода channels.

Избегать попаданию вещества в почву и воду.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: PHOSPHORUS PENTACHLORIDE

UN 1806 Класс: 8 Группа: II (E)

Морской транспорт (IMDG):

Техническое название: PHOSPHORUS PENTACHLORIDE

UN 1806 Класс: 8 Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Phosphorus Pentachloride

UN 1806 Класс: 8 Группа: II

Инструкция по упаковке: CAO 863 PAX F

Regulatory information

The соединен. is subject до Council Regulation (EC) No 1334/2000 22 June 2000 setting up a Community regime for the control exports dual-use items и technology.

Дополнительная информация

Др. precautionary statements

P284 Wear Защита органов дыхания.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P314 Get medical advice/attention if you feel unwell.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R34 Может вызвать ожоги.

R26 Очень токсично by inhalation.

R22 Вредный При попадании внутрь.

R14 Reacts violently с водой.

R48/20 Вредный: danger serious damage до health by prolonged exposure through inhalation.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S36/37/39 Wear suitable protective clothing, gloves и eye/face protection.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

S7/8 Keep container tightly closed и безводн..

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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