Viscosity:S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
1498 Potassium Chromate solution 5% w/v
Identification of the substance/preparation and of the company or firm | ||||
1.1 Identification of the substance or preparation Name: Potassium Chromate solution 5% w/v
Synonym:
REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: | ||||
For laboratory utilisation, analysis, research and fine chemistry.
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008.
Carc. 1B Muta. 1B Skin Sens. 1 Aquatic Chronic 2
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Hazard Pictograms
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Signal word Danger
| ||||
Hazard statements H350i May cause cancer by inhalation. H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.
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Classification (67/548/CEE or 1999/45/CE).
| ||||
For the full text of the R-phrases mentioned in this section, see section 16. | ||||
Component Composition/Information | ||||
| ||||
Name: Potassium Chromate solution 5% w/v Formula: K2CrO4 M.= 194,21 CAS [7789-00-6] EC number (EINECS): 232-140-5 EC index number: 024-006-00-8 | ||||
Composition:
0001: Potassium Chromate
Formula: K2CrO4 M.= 194,21 CAS [7789-00-6] EC number (EINECS): 232-140-5 EC index number: 024-006-00-8
Content: 5 %
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Classification Regulation (CE) nº 1272/2008.
Carc. 1B Muta. 1B Eye Irrit. 2 STOT SE 3 Skin Irrit. 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1
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Hazard Pictograms
| ||||
Signal word Danger
| ||||
Hazard statements H350i May cause cancer by inhalation. H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Classification (67/548/CEE or 1999/45/CE).
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First aid
| ||||
4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air. In the event sickness persists, seek medical assistance.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water (for at least 15 minutes), keeping eyelids open. In the event of irritation, seek medical assistance.
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4.5 Swallowing: Drink large amounts of water. Induce vomiting. Seek medical assistance.
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Fire-fighting means
| ||||
5.1 Suitable fire-extinguishing means: Water. Foam.
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5.2 Fire-fighting means which must NOT be used: No specific data.
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5.3 Special risks: Incombustible.
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5.4 Protective equipment: Suitable clothing and footwear.
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: No special indications.
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6.2 Precautions for care of the environment: Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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Handling and storage
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7.1 Handling: No special indications.
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7.2 Storage: Well sealed containers.Dry atmosphere.Room temperature.
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Staff exposure/protection controls
| ||||
8.1 Technical protective measures: No special indications.
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8.2 Exposure limit control: TLV-TWA(K2CrO4): 0,05 mg/m3 VLA-ED: 0,05 mg/m3 Risk of sensitization.
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8.3 Respiratory protection: In the event of fumes forming/aerosols, use suitable respiratory protection.
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8.4 Hand protection: Use suitable gloves
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | ||||
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Physical and chemical properties
| ||||
Appearance: liquid | ||||
Colour: Yellow | ||||
Granulometry: N/A | ||||
Odour: Odourless. | ||||
pH: N/A | ||||
Melting point/freezing point: N/A | ||||
Initial boiling point and boiling range: N/A | ||||
Flash point: N/A | ||||
Flammability (solid, gas): N/A | ||||
Upper/lower flammability or explosive limits: N/A | ||||
Vapour pressure: N/A | ||||
Vapour density: N/A | ||||
Relative density: (20/4) 1,041 | ||||
Solubility: Miscible with water | ||||
Partition coefficient: n-octanol/water: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Kinematic viscosity:N/A | ||||
Dynamic viscosity: N/A | ||||
Stability and reactivity
| ||||
10.1 Conditions which should be avoided: The product is chemically stable under standar ambient conditions (room temperature).
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10.2 Matter which should be avoided: Flammable substances. Organic compounds. Reducing agents. Chlorates. Phosphides. Sulphides. Hydrazine and derivatives. Metals (powder).
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10.3 Hazardous decomposition products: No specific data.
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10.4 Complementary information: No specific data.
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Toxicological information
| ||||
LD50 oral mus : 180 mg/kg (referring to the anhydrous substance) LD50 ipr mus : 32 mg/kg (referring to the anhydrous substance) K2CrO4
| ||||
Upon contact with the skin: irritations Risk of sensitization Through contact with the eyes: irritations If swallowed: gastro-intestinal disorders diarrhoea vomiting If inhaled: Carcinogenic in animal testing. Can cause allergic reaction May cause heritable genetic damage. Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
| ||||
12.1 Toxicity: 12.1.1 - EC50 test (mg/l): Algae (Cr) 5 mg/l Classification: Extr. toxic Crustaceans (Daphnia magna) (Cr) 0,3 mg/l Classification: Extr. toxic Fish (Cr) 29 mg/l Classification: Extr. toxic 12.1.2. - Receptor medium: Risk for the water environment High Risk for the land environment Medium 12.1.3. - Observations: The ecotoxicity is due to the chrome ion.
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12.2 Persistence and Degradability : 12.2.1 - Test: 12.2.2. - Biotic degradation classification: BOD5/COD Biodegradability 12.2.3. - Abiotic degradation depending on pH: 12.2.4. - Observations:
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12.3 Bioaccumulative potential: 12.3.1. - Test: 12.3.2. - Bioaccumulation: Risk 12.3.3. - Observations:
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12.4 Mobility in soil : Data not available.
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12.5 Assessment PBT and MPMB : Data not available.
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12.6 Other possible effects on the environment: Do not allow it to enter soils or water channels. High toxic product for water. Data refer to the pure substance.
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Considerations regarding elimination
| ||||
13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
| ||||
Overland (ADR): Technical name: TOXIC LIQUID, INORGANIC, N.O.S. UN 3287 Class: 6.1 CONTAM. MAR Packaging group: III (E) | ||||
By sea (IMDG): Technical name: TOXIC LIQUID, INORGANIC, N.O.S. UN 3287 Class: 6.1 CONTAM. MAR Packaging group: III | ||||
By air (ICAI-IATA): Technical name: Toxic liquid, inorganic, n.o.s. UN 3287 Class: 6.1 CONTAM. MAR Packaging group: III | ||||
Packaging instructions: CAO 663 PAX 655 | ||||
Regulatory information
| ||||
Contains a substance included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)
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Other information
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Other precautionary statements P281 Use personal protective equipment as required. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P308+P313 IF exposed or concerned: Get medical advice/attention. P321 Specific treatment (see on this label). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Labelling (65/548/CEE or 1999/45/CE) | ||||
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Review number and date: 4 15.09.2011 Date published: 15.09.2011 In respect of the previous review, changes have been made to the following sections: 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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Вязк.:S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
1498 Калий Хромат раствор 5% w/v
Определение вещества/preparation и the company или firm | ||||
1.1 Определение вещества или preparation Название: Калий Хромат раствор 5% w/v
Synonym:
REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use вещества/preparation: | ||||
Для общелабораторного использования, анализов, исследований и тонкой химии.
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1.3 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
| ||||
Классификация вещества или the mixture.
| ||||
Классификация Regulation (CE) nº 1272/2008.
Carc. 1B Muta. 1B Skin Sens. 1 Aquatic Chronic 2
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Hazard Pictograms
| ||||
Signal word Danger
| ||||
Hazard statements H350i May cause cancer by inhalation. H340 May cause genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H317 May cause an allergic skin reaction. H411 Токсично до aquatic life с long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out the workplace. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection.
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Классификация (67/548/CEE или 1999/45/CE).
| ||||
For the full text the R-выражения mentioned в this section, see section 16. | ||||
Сведения о компонентах и состав | ||||
| ||||
Название: Калий Хромат раствор 5% w/v Формула: K2CrO4 M.= 194,21 CAS [7789-00-6] Номер ЕС (EINECS): 232-140-5 ЕС индекс: 024-006-00-8 | ||||
Состав:
0001: Калий Хромат
Формула: K2CrO4 M.= 194,21 CAS [7789-00-6] Номер ЕС (EINECS): 232-140-5 ЕС индекс: 024-006-00-8
Content: 5 %
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Классификация Regulation (CE) nº 1272/2008.
Carc. 1B Muta. 1B Eye Irrit. 2 STOT SE 3 Skin Irrit. 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1
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Hazard Pictograms
| ||||
Signal word Danger
| ||||
Hazard statements H350i May cause cancer by inhalation. H340 May cause genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H410 Очень токсично до aquatic life с long lasting effects.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P271 Use only outdoors или в a well-ventilated area. P272 Contaminated work clothing should not be allowed out the workplace. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal Средства индивидуальной защиты как required. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P308+P313 IF exposed или concerned: Get medical advice/attention. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing и wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация (67/548/CEE или 1999/45/CE).
| ||||
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Первая помощь
| ||||
4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.
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Меры и средства обеспечения пожаро- и взрывобезопасности
| ||||
5.1 Пригодные средства пожаротушения: Вода. Пена.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used: No specific data.
| ||||
5.3 Особая опасность: Incombustible.
| ||||
5.4 Средства индивидуальной защиты: Специальная одежда и обувь.
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
| ||||
6.1 Индивидуальные меры предосторожности: Специальные указания отсутствуют.
| ||||
6.2 Меры по защите окружающей среды: Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.
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Правила обращения и хранения
| ||||
7.1 Обращение: Специальные указания отсутствуют.
| ||||
7.2 Хранение: В запечатанных контейнерах.Сухая атмосфера.Room temperature.
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Требования по охране труда и меры по обеспечению безопасности персонала
| ||||
8.1 Технические меры защиты: Специальные указания отсутствуют.
| ||||
8.2 Контроль предельно допустимого уровня воздействия: TLV-TWA(K2CrO4): 0,05 мг/м3 VLA-ED: 0,05 мг/м3 Риск sensitization.
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания.
| ||||
8.4 Защита рук: Использовать защитные перчатки
| ||||
8.5 Защита глаз: Использовать защитные очки.
| ||||
8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.
| ||||
8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | ||||
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Физико-химические свойства
| ||||
Внешний Вид: жидкость | ||||
Цвета: Желт. | ||||
Granulometry: N/A | ||||
Запах: Без Запаха. | ||||
pH: N/A | ||||
точка плавления/Температура замерзания: N/A | ||||
Initial Точка кипения и Интервал температур кипения: N/A | ||||
Точка воспламенения: N/A | ||||
Flammability (solid, gas): N/A | ||||
Верхний/нижний flammability или explosive показатели: N/A | ||||
Давление пара: N/A | ||||
Vapour плотность: N/A | ||||
Relative плотность: (20/4) 1,041 | ||||
Растворимость: Смешивается с водой | ||||
Partition coefficient: n-октанол/вода: N/A | ||||
Auto-ignition temperature: N/A | ||||
Decomposition temperature: N/A | ||||
Кинематич. вязк.:N/A | ||||
Динамич. вязк.: N/A | ||||
Стабильность и реакционноспособность
| ||||
10.1 Условия, которых следует избегать: The product is chemically stable under standar ambient conditions (room temperature).
| ||||
10.2 Вещества, которых следует избегать: Воспламеняем соединения. Органический соединен.. Восстановительs. Chlorates. Phosphides. Sulphides. Hydrazine и derivatives. Металлы (порошок).
| ||||
10.3 Опасные продукты разложения: No specific data.
| ||||
10.4 Общая информация: No specific data.
| ||||
Токсикологическая информация
| ||||
LD50 oral mus : 180 мг/кг (referring до the безводный соединен.) LD50 ipr mus : 32 мг/кг (referring до the безводный соединен.) K2CrO4
| ||||
Upon Контакт с кожей: irritations Риск sensitization Контакт с глазами: irritations При попадании внутрь: gastro-intestinal disorders diarrhoea рвота If inhaled: Carcinogenic в animal testing. Can cause allergic reaction May cause heritable genetic damage. Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
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Информация по окружающей среде
| ||||
12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): Algae (Cr) 5 mg/l Классификация: Extr. токсично Crustaceans (Daphnia magna) (Cr) 0,3 mg/l Классификация: Extr. токсично Рыбы (Cr) 29 mg/l Классификация: Extr. токсично 12.1.2. - Воздействие на окружающую среду: Риск для водной среды Высокий Риск для земли Средний 12.1.3. - Наблюдения: The экотоксичность is due до the chrome ion.
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12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Классификация биотического периода распада: BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от рН: 12.2.4. - Наблюдения:
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения:
| ||||
12.4 Мобильность в soil : Нет данных.
| ||||
12.5 Assessment PBT и MPMB : Нет данных.
| ||||
12.6 Другие возможные воздействия на окружающую среду: Избегать попаданию вещества в почву и воду. Высокий токсично product for вода. Data refer до the pure соединен..
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| ||||
Правила утилизации
| ||||
13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
.
| ||||
13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
| ||||
Информация относительно транспорта
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Автотранспорт (ADR): Техническое название: TOXIC LIQUID, INORGANIC, N.O.S. UN 3287 Класс: 6.1 CONTAM. MAR Группа: III (E) | ||||
Морской транспорт (IMDG): Техническое название: TOXIC LIQUID, INORGANIC, N.O.S. UN 3287 Класс: 6.1 CONTAM. MAR Группа: III | ||||
Авиа транспорт (ICAI-IATA): Техническое название: Токсично жидкость, неорганический, n.o.s. UN 3287 Класс: 6.1 CONTAM. MAR Группа: III | ||||
Инструкция по упаковке: CAO 663 PAX 655 | ||||
Regulatory information
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Contains a соединен. included в the Candidate List Соединения Very Высокий Concern (SVHC) в соответствии с Regulation (EC) No. 1907/2006 (REACH)
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Дополнительная информация
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Др. precautionary statements P281 Use personal Средства индивидуальной защиты как required. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P308+P313 IF exposed или concerned: Get medical advice/attention. P321 Specific treatment (see on this label). P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P405 Store locked up. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Labelling (65/548/CEE или 1999/45/CE) | ||||
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Номер рецензии и дата: 4 15.09.2011 Date published: 15.09.2011 Относительно предыдущего обзора изменения были произведены в следующих разделах: 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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