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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3111 Hydrochloric Acid 0,5 mol *(18,230gHCl) to prepare 1l of 0,5N solution

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Hydrochloric Acid 0,5 mol *(18,230gHCl) to prepare 1l of 0,5N solution

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

Xi Irritant

R36/37/38

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Hydrochloric solution

Name: Hydrochloric Acid 0,5 mol *(18,230gHCl) to prepare 1l of 0,5N solution

CAS [7647-01-0]

EC number (EINECS): 231-595-7

EC index number: 017-002-02-7

Composition:

0001: Hydrochloric Acid 37%

Formula: HCl M.= 36,46 CAS [7647-01-0]

EC number (EINECS): 231-595-7

EC index number: 017-002-01-X

REACH Registration Number: 01-2119484862-27-XXXX

Content: >= 10 % <= 25 %

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R34 Causes burns.

R37 Irritating to respiratory system.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible. Upon contact with metals, hydrogen gas may form (there is a risk of explosion). Precipitate fumes formed with water.

5.4 Protective equipment:

Suitable clothing and footwear. Self-contained breathing equipment.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes. Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Neutralize with diluted sodium hydroxide.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Room temperature.Do not store in metal containers.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-EC(HCl): 10 ppm - 15 mg/m3

VLA-ED(HCl): 7,6 mg/m3

VLA-ED(HCl): 5 ppm

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves neopren nitrile latex

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: N/A

Colour:

N/A

Granulometry: N/A

Odour: Piquant.

pH: 1

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Aluminium. Amines. Carbides. Hydrides. Fluorine. Alkaline metals. Metals. KMnO4. Strong bases. Salts of oxyhalogenic acids. Concentrated sulfuric acid. Semimetallic hydrogen compounds. Semimetallic oxides. Aldehydes. Sulphides. Lithium silicide. Vinyl methyl ether.

10.3 Hazardous decomposition products:

Hydrogen chloride. Chlorine.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LC50 inh rat : 3124 ppm (V) 1h

  • Dangerous effects for health:

If fumes inhaled: Irritations to the respiratory tracts. Upon contact with the skin: irritations Through contact with the eyes: irritations

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Fish test 25 mg/l

Classification:

Toxic

Leuciscus idus (48h)(1N) 862 mg/l

Classification:

Very toxic

12.1.2. - Receptor medium:

Risk for the water environment

Medium

Risk for the land environment

Medium

12.1.3. - Observations:

Has a major acute effect on the water and land environment depending on pH.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Does not consume oxygen biologically.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk = ----

12.3.3. - Observations:

It is not bio-accumulable, although it is accumulable in water courses and soils in saline form (Cl-).

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Generally, its effect is acutely considerable in the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

The treatment is neutralization.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: HYDROCHLORIC ACID

UN 1789 Class: 8 Packaging group: III (E)

By sea (IMDG):

Technical name: HYDROCHLORIC ACID

UN 1789 Class: 8 Packaging group: III

By air (ICAI-IATA):

Technical name: Hydrochloric acid

UN 1789 Class: 8 Packaging group: III

Packaging instructions: CAO 856 PAX 852

Regulatory information

The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.

Other information

Other precautionary statements

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R36/37/38 Irritating to eyes, respiratory system and skin.

S-phrase(s):

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3111 Соляная Кислота 0,5 mol *(18,230gHCl) до prepare 1l 0,5N раствор

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Соляная Кислота 0,5 mol *(18,230gHCl) до prepare 1l 0,5N раствор

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

Xi Irritant

R36/37/38

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Соляная раствор

Название: Соляная Кислота 0,5 mol *(18,230gHCl) до prepare 1l 0,5N раствор

CAS [7647-01-0]

Номер ЕС (EINECS): 231-595-7

ЕС индекс: 017-002-02-7

Состав:

0001: Соляная Кислота 37%

Формула: HCl M.= 36,46 CAS [7647-01-0]

Номер ЕС (EINECS): 231-595-7

ЕС индекс: 017-002-01-X

REACH Registration Number: 01-2119484862-27-XXXX

Content: >= 10 % <= 25 %

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R34 Может вызвать ожоги.

R37 Irritating до respiratory system.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible. Upon contact с металлы, водород gas may form (there is a риск explosion). Precipitate fumes formed с водой.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь. Средства индивидуальной защиты дыхательных путей.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары. Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Neutralize с diluted Натрия гидроксид.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Room temperature.Do not store в металл containers.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC(HCl): 10 ppm - 15 мг/м3

VLA-ED(HCl): 7,6 мг/м3

VLA-ED(HCl): 5 ppm

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки neopren nitrile latex

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: N/A

Цвета:

N/A

Granulometry: N/A

Запах: Piquant.

pH: 1

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Алюминий. Амины. Carbides. Hydrides. Fluorine. Щелочных металлы. Металлы. KMnO4. Сильные основания. Соли oxyhalogenic кислоты. Концентрированная серная кислота. Semimetallic водород соединен.. Semimetallic oxides. Альдегид.. Sulphides. Литий silicide. Vinyl метил эфир.

10.3 Опасные продукты разложения:

Водород хлорид. Хлор.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LC50 inh rat : 3124 ppm (V) 1h

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the respiratory tracts. Upon Контакт с кожей: irritations Контакт с глазами: irritations

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Рыбы тест 25 mg/l

Классификация:

Токсично

Leuciscus idus (48h)(1N) 862 mg/l

Классификация:

Очень токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Средний

Риск для земли

Средний

12.1.3. - Наблюдения:

Has a major acute effect on the вода и land environment зависит от pH.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Does not consume oxygen biologically.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск = ----

12.3.3. - Наблюдения:

It is not bio-accumulable, although it is accumulable в воде courses и soils в saline form (Cl-).

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Generally, its effect is acutely considerable в the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

The treatment is neutralization.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: HYDROCHLORIC ACID

UN 1789 Класс: 8 Группа: III (E)

Морской транспорт (IMDG):

Техническое название: HYDROCHLORIC ACID

UN 1789 Класс: 8 Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Соляная кислота

UN 1789 Класс: 8 Группа: III

Инструкция по упаковке: CAO 856 PAX 852

Regulatory information

The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.

Дополнительная информация

Др. precautionary statements

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R36/37/38 Вызывает раздражение глаз, respiratory system и skin.

S-phrase(s):

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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