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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1302 Turpentine Oil *stabilized with 100 ppm of DL-?-Tocopherol

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Turpentine Oil *stabilized with 100 ppm of DL-?-Tocopherol

Synonym:

Turpentine

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 3

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Chronic 2

Asp. Tox. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour.

H332 Harmful if inhaled.

H312 Harmful in contact with skin.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H304 May be fatal if swallowed and enters airways.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

Xn Harmful

R43

R36/38

R20/21/22

R10

R51/53

R65

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Turpentine Oil *stabilized with 100 ppm of DL-?-Tocopherol

CAS [8006-64-2]

EC number (EINECS): 232-350-7

EC index number: 650-002-00-6

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

Avoid the formation of electrostatic charges. No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

VLA-EC: 150 ppm - 850 mg/m3

VLA-ED: 100 ppm - 587 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: colourless to pale yellow

Granulometry: N/A

Odour: Characteristic.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range: 150 - 167 °C

Flash point: 36 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits: 6 %(V) / 0,8 %(V)

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 0,86

Solubility: Inmiscible with water.

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature: 255 °C

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

No specific data.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 5.760 mg/kg

LC50 inh rat : 12 g/m3 6h

  • Dangerous effects for health:

If inhaled: Causes breathing difficulties ataxia (motor coordination disorders) effects on the central nervous system If swallowed: nausea vomiting effects on the central nervous system Upon contact with the skin: irritations Through contact with the eyes: irritations Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

12.1.2. - Receptor medium:

Risk for the water environment

Risk for the land environment

12.1.3. - Observations:

Ecotoxic data not available.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Hardly pollutant product.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: TURPENTINE

UN 1299 Class: 3 PELIG.M.AMB Packaging group: III (D/E)

By sea (IMDG):

Technical name: TURPENTINE

UN 1299 Class: 3 PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Turpentine

UN 1299 Class: 3 PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 366 PAX 355

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P331 Do NOT induce vomiting.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use for extinction.

P391 Collect spillage.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R36/38 Irritating to eyes and skin.

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R10 Flammable.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 Harmful: may cause lung damage if swallowed.

S-phrase(s):

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S46 If swallowed, seek medical advice immediately and show this container or lable.

S36/37 Wear suitable protective clothing and gloves.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1302 Turpentine Oil *стабилизированный 100 ppm DL-?-Tocopherol

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Turpentine Oil *стабилизированный 100 ppm DL-?-Tocopherol

Synonym:

Turpentine

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 3

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Chronic 2

Asp. Tox. 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H226 Воспламеняем жидкость и vapour.

H332 Вредный if inhaled.

H312 Вредный в contact с skin.

H302 Вредный При попадании внутрь.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Токсично до aquatic life с long lasting effects.

H304 May be fatal При попадании внутрь и enters airways.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

Xn Вредный

R43

R36/38

R20/21/22

R10

R51/53

R65

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Turpentine Oil *стабилизированный 100 ppm DL-?-Tocopherol

CAS [8006-64-2]

Номер ЕС (EINECS): 232-350-7

ЕС индекс: 650-002-00-6

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Избегать образования электростатических разрядов. Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-EC: 150 ppm - 850 мг/м3

VLA-ED: 100 ppm - 587 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: бесцветная до pale желт.

Granulometry: N/A

Запах: Характерный.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения: 150 - 167 °C

Точка воспламенения: 36 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 6 %(V) / 0,8 %(V)

Давление пара: N/A

Vapour плотность: N/A

Relative плотность: (20/4) 0,86

Растворимость: Inmiscible с водой.

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature: 255 °C

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Высокий temperatures.

10.2 Вещества, которых следует избегать:

No specific data.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 5.760 мг/кг

LC50 inh rat : 12 g/m3 6h

  • Опасное воздействие на здоровье:

If inhaled: Causes затруднение дыхания ataxia (motor coordination disorders) effects on the central nervous system При попадании внутрь: тошнота рвота effects on the central nervous system Upon Контакт с кожей: irritations Контакт с глазами: irritations Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Риск для земли

12.1.3. - Наблюдения:

Ecotoxic Нет данных.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Hardly Продукт загрязнения.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: TURPENTINE

UN 1299 Класс: 3 PELIG.M.AMB Группа: III (D/E)

Морской транспорт (IMDG):

Техническое название: TURPENTINE

UN 1299 Класс: 3 PELIG.M.AMB Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Turpentine

UN 1299 Класс: 3 PELIG.M.AMB Группа: III

Инструкция по упаковке: CAO 366 PAX 355

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P272 Contaminated work clothing should not be allowed out the workplace.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P331 Do NOT Вызвать рвоту.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+P378 В case fire: Use for extinction.

P391 Collect spillage.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R36/38 Вызывает раздражение глаз и skin.

R20/21/22 Избегать контактов с кожей. Вреден при вдыхании и при употреблении во внутрь.

R10 Воспламеняем.

R51/53 Токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

R65 Вредный: may cause lung damage При попадании внутрь.

S-phrase(s):

S62 При попадании внутрь, do not Вызвать рвоту: seek medical advice immediately и show this container или label.

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S46 При попадании внутрь, seek medical advice immediately и show this container или lable.

S36/37 Использовать специальную защитную одежду и перчатки.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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