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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1925 Hydroxylammonium Sulphate

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Hydroxylammonium Sulphate

Synonym:

Hydroxylamine Sulphate

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Met. Corr. 1

Carc. 2

Acute Tox. 4

Acute Tox. 4

STOT RE 2

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H290 May be corrosive to metals.

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H312 Harmful in contact with skin.

H302 Harmful if swallowed.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H400 Very toxic to aquatic life.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P234 Keep only in original container.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

Xn Harmful

E Explosive

R40

R36/38

R21/22

R2

R43

R48/22

R50

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Hydroxylammonium Sulphate

Formula: (NH3OH)2SO4 M.= 164,15 CAS [10039-54-0]

EC number (EINECS): 233-118-8

EC index number: 612-123-00-2

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. Risk of explosion of dust. In the event of fire, toxic fumes may form: NOx,SOx.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the dust.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: White

Granulometry: N/A

Odour: Odourless.

pH: 3,5 (50 g/l)

Melting point/freezing point: 170 °C

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: 685 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: above170 °C

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Oxidant agents. Bases. Heat

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LD L0 skn rbt : 100 mg/kg

  • Dangerous effects for health:

If dust inhaled: Irritations to the respiratory tracts. Through contact with the eyes: irritations Upon contact with the skin: irritations sensitization allergic reaction dermatitis If swallowed: gastro-intestinal disorders Due to absorption: Risk of metahemoglobinemia with headaches Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

12.1.2. - Receptor medium:

Risk for the water environment

Risk for the land environment

12.1.3. - Observations:

Extremely toxic in water environments.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

High toxic product for water.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: HYDROXYLAMINE SULPHATE

UN 2865 Class: 8 PELIG.M.AMB Packaging group: III (E)

By sea (IMDG):

Technical name: HYDROXYLAMINE SULPHATE

UN 2865 Class: 8 PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Hydroxylamine sulphate

UN 2865 Class: 8 PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 864 PAX 860

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P270 Do no eat, drink or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage to prevent material damage.

P391 Collect spillage.

P405 Store locked up.

P406 Store in corrosive resistant/ container with a resistant inner liner.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R40 Limited evidence of a carcinogenic effect.

R36/38 Irritating to eyes and skin.

R21/22 Harmful in contact with skin and if swallowed.

R2 Risk of explosion by shock, friction, fire or other sources of ignition.

R43 May cause sensitisation by skin contact.

R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.

R50 Very toxic to aquatic organisms.

S-phrase(s):

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S36/37 Wear suitable protective clothing and gloves.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1925 HydroxylАммония сульфат

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

HydroxylАммония сульфат

Synonym:

Hydroxylamine Сульфат

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Met. Corr. 1

Carc. 2

Acute Tox. 4

Acute Tox. 4

STOT RE 2

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H290 May be коррозионное вещество до металлы.

H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>.

H312 Вредный в contact с skin.

H302 Вредный При попадании внутрь.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H400 Очень токсично до aquatic life.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P234 Keep only в original container.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

Xn Вредный

E Explosive

R40

R36/38

R21/22

R2

R43

R48/22

R50

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: HydroxylАммония сульфат

Формула: (NH3OH)2SO4 M.= 164,15 CAS [10039-54-0]

Номер ЕС (EINECS): 233-118-8

ЕС индекс: 612-123-00-2

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. Риск explosion dust. В случае возгорания могут образовываться токсичные пары: NOx,SOx.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пыль.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

: Нет данных.

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Белый

Granulometry: N/A

Запах: Без Запаха.

pH: 3,5 (50 г/л)

точка плавления/Температура замерзания: 170 °C

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: 685 г/л в воде20 °C

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: above170 °C

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Окислители. Основан.. Heat

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD L0 skn rbt : 100 мг/кг

  • Опасное воздействие на здоровье:

If dust inhaled: Irritations до the respiratory tracts. Контакт с глазами: irritations Upon Контакт с кожей: irritations sensitization allergic reaction dermatitis При попадании внутрь: gastro-intestinal disorders Due до absorption: Риск metahemoglobinemia с headaches Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Риск для земли

12.1.3. - Наблюдения:

Extremely токсично в воде environments.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Высокий токсично product for вода.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: HYDROXYLAMINE SULPHATE

UN 2865 Класс: 8 PELIG.M.AMB Группа: III (E)

Морской транспорт (IMDG):

Техническое название: HYDROXYLAMINE SULPHATE

UN 2865 Класс: 8 PELIG.M.AMB Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Hydroxylamine сульфат

UN 2865 Класс: 8 PELIG.M.AMB Группа: III

Инструкция по упаковке: CAO 864 PAX 860

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P270 Do no eat, drink или smoke when using this product.

P272 Contaminated work clothing should not be allowed out the workplace.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing и wash before reuse.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage до prevent material damage.

P391 Collect spillage.

P405 Store locked up.

P406 Store в коррозионное вещество resistant/ container с a resistant inner liner.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R40 Limited evidence a carcinogenic effect.

R36/38 Вызывает раздражение глаз и skin.

R21/22 Вредный в contact с skin и При попадании внутрь.

R2 Риск explosion by shock, friction, fire или др. sources ignition.

R43 May cause sensitisation by skin contact.

R48/22 Вредный: danger serious damage до health by prolonged exposure При попадании внутрь.

R50 Очень токсично до aquatic organisms.

S-phrase(s):

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S36/37 Использовать специальную защитную одежду и перчатки.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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