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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3886 2-[(Ethylmercury)Thio] Benzoic Acid Sodium Salt

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

2-[(Ethylmercury)Thio] Benzoic Acid Sodium Salt

Synonym:

Mercurothiolate, Merthiolate, Sodium Ethylmercurithiosalicylate, Thimerosal

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal in contact with skin.

H300 Fatal if swallowed.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T+ Very toxic

R50/53

R33

R26/27/28

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: 2-[(Ethylmercury)Thio] Benzoic Acid Sodium Salt

Formula: C9H9HgNaO2S M.= 404,81 CAS [54-64-8]

EC number (EINECS): 200-210-4

EC index number: 080-004-00-7

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing. Take the product out with cotton wool soaked in polyethylene-glycol 400.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek immediate medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek immediate medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

In the event of fire, toxic fumes may form: Hg. Incombustible.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing. Do not inhale the dust.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

Handle under an extractor fan.

7.2 Storage:

Well sealed containers.Dry atmosphere.Away from light.Restricted access, only authorized to technicians.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

TLV-TWA(Hg): 0,01 mg/m3 dermal resorption

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Avoid the formation of dust. Remove contaminated clothing. Do not inhale the substance. Use suitable work clothing. Wash hands and face before breaks and when the job is done. Do not eat, drink or smoke in the workplace.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: Cream

Granulometry: N/A

Odour: Characteristic.

pH: 6,5 ((1% sol.))

Melting point/freezing point: 233 °C

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: 625 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

Risk of explosion in the event of decomposition.

10.2 Matter which should be avoided:

Reducing agents. Aluminium.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

LD50 oral mus : 91 mg/kg

LD50 oral rat : 75 mg/kg

LD50 ipr mus : 54 mg/kg

  • Dangerous effects for health:

Mercury compounds have toxic effects on cells and protoplasms. Symptoms due to acute intoxication of (Hg): Through contact with the eyes: Serious injuries If swallowed and inhaled: Tissue injuries (mouth, oesophagus, stomach and intestinal tract). Metallic taste nausea vomiting stomach pains intestinal disorders Burns in the digestive apparatus oedemas in the respiratory tract pneumonia. Can cause blood alterations arrhythmia collapse kidney problems Chronic effects Buccal infections, mercury halo, risk of loss of teeth. Risk of effects on the central nervous system sensitization sight disorders hallucinations dizziness Pregnant women must not be allowed to come into contact with the product. Possible risk of adverse effects to the foetus during pregnacy. Other dangerous characteristics are not discarded.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 0,046 mg/l

Classification:

Extr. toxic

Algae (Sc. cuadricauda) 0,07 mg/l

Classification:

Extr. toxic

Algae (M. aeruginosa) 0,005 mg/l

Classification:

Extr. toxic

Fish (Salmonidae) 0,05 mg/l

Classification:

Extr. toxic

Fish (P. promelas) 0,19 mg/l

Classification:

Extr. toxic

Fish (Leuciscus Idus) 0,013 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

High

12.1.3. - Observations:

The ecotoxicity is due to the mercury ion.

Toxic product in any environment. Ecotoxicity acute and chronic.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk = High

12.3.3. - Observations:

The mercury ion is bioaccumulable in the food chain.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

High pollutant product.

Do not allow it to enter soils or water channels.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: MERCURY COMPOUND, SOLID, N.O.S.

UN 2025 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III (E)

By sea (IMDG):

Technical name: MERCURY COMPOUND, SOLID, N.O.S.

UN 2025 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Mercury compound, solid, n.o.s.

UN 2025 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 677 PAX 670

Regulatory information

The substance is subject to Regulation (EC) No 689/2008 of the European Parliament and of the Council of 17 June 2008 concerning the export and import of dangerous chemicals.

Other information

Other precautionary statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 Wear respiratory protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P314 Get medical advice/attention if you feel unwell.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R33 Danger of cumulative effects.

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S36 Wear suitable protective clothing.

S28a After contact with skin, wash immediately with plenty of water.

S13 Keep away from food, drink and animal feedingstuffs.

S60 This material and its container must be disposed of as hazardous waste.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3886 2-[(Ethylmercury)Thio] Бензойн. Кислота Натриевая соль

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

2-[(Ethylmercury)Thio] Бензойн. Кислота Натриевая соль

Synonym:

Mercurothiolate, Merthiolate, Натрия Ethylmercurithiosalicylate, Thimerosal

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal в contact с skin.

H300 Fatal При попадании внутрь.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H410 Очень токсично до aquatic life с long lasting effects.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P262 Do not get в глаза, on skin, или on clothing.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T+ Очень токсично

R50/53

R33

R26/27/28

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: 2-[(Ethylmercury)Thio] Бензойн. Кислота Натриевая соль

Формула: C9H9HgNaO2S M.= 404,81 CAS [54-64-8]

Номер ЕС (EINECS): 200-210-4

ЕС индекс: 080-004-00-7

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды. Соберите продукт ваткой, смоченной в полиэтилен-гликоле 400.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться немедленно за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться немедленно за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

В случае возгорания могут образовываться токсичные пары: Hg. Incombustible.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Avoid Контакт с кожей, глаза или clothing. Не вдыхать пыль.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Handle under an extractor fan.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Away from light.Ограничить право доступа к веществу, предоставив его только специалистам.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

TLV-TWA(Hg): 0,01 мг/м3 dermal resorption

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Avoid the formation dust. Избавиться от загрязненной одежды. Do not inhale the соединен.. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы. Do not eat, drink или smoke в the workplace.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Кремов.

Granulometry: N/A

Запах: Характерный.

pH: 6,5 ((1% sol.))

точка плавления/Температура замерзания: 233 °C

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: 625 г/л в воде20 °C

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Риск explosion в the event decomposition.

10.2 Вещества, которых следует избегать:

Восстановительs. Алюминий.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral mus : 91 мг/кг

LD50 oral rat : 75 мг/кг

LD50 ipr mus : 54 мг/кг

  • Опасное воздействие на здоровье:

Mercury соединен. have токсично effects on cells и protoplasms. Symptoms due до acute intoxication (Hg): Контакт с глазами: Serious injuries При попадании внутрь и inhaled: Tissue injuries (mouth, oesophagus, stomach и intestinal tract). Metallic taste тошнота рвота stomach pains intestinal disorders Ожоги в the digestive apparatus oedemas в the respiratory tract pneumonia. Can cause blood alterations arrhythmia collapse kidney problems Chronic effects Buccal infections, mercury halo, риск loss teeth. Риск effects on the central nervous system sensitization sight disorders hallucinations dizziness Pregnant women must not be allowed до come into contact с the product. Possible риск adverse effects до the foetus during pregnacy. Другие опасные характеристики данного вещества не обнаружены.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 0,046 mg/l

Классификация:

Extr. токсично

Algae (Sc. cuadricauda) 0,07 mg/l

Классификация:

Extr. токсично

Algae (M. aeruginosa) 0,005 mg/l

Классификация:

Extr. токсично

Рыбы (Salmonidae) 0,05 mg/l

Классификация:

Extr. токсично

Рыбы (P. promelas) 0,19 mg/l

Классификация:

Extr. токсично

Рыбы (Leuciscus Idus) 0,013 mg/l

Классификация:

Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Высокий

12.1.3. - Наблюдения:

The экотоксичность is due до the mercury ion.

Токсично product в any environment. Экотоксичность acute и chronic.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск = Высокий

12.3.3. - Наблюдения:

The mercury ion is bioaccumulable в the food chain.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Высокий Продукт загрязнения.

Избегать попаданию вещества в почву и воду.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: MERCURY COMPOUND, SOLID, N.O.S.

UN 2025 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III (E)

Морской транспорт (IMDG):

Техническое название: MERCURY COMPOUND, SOLID, N.O.S.

UN 2025 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Mercury compound, solid, n.o.s.

UN 2025 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Инструкция по упаковке: CAO 677 PAX 670

Regulatory information

The соединен. is subject до Regulation (EC) No 689/2008 the Европейск. Parliament и the Council 17 June 2008 concerning the export и import dangerous chemicals.

Дополнительная информация

Др. precautionary statements

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P284 Wear Защита органов дыхания.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P350 IF ON SKIN: Gently wash с plenty soap и вода.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P310 Immediately call a POISON CENTER или doctor/physician.

P314 Get medical advice/attention if you feel unwell.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R50/53 Очень токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

R33 Danger cumulative effects.

R26/27/28 Очень токсично by inhalation, в contact с skin и При попадании внутрь.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S36 Wear suitable protective clothing.

S28a После contact с skin, wash immediately с plenty вода.

S13 Keep away from food, drink и animal feedingstuffs.

S60 This material и its container must be disposed как опасная доза waste.

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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