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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

5396 Phenol-1,1,2,2-Tetrachloroethane 60:40 w/w

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Phenol-1,1,2,2-Tetrachloroethane 60:40 w/w

Synonym:

1,1,2,2-Tetrachloroethane-Phenol

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1B

Aquatic Chronic 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal in contact with skin.

H300 Fatal if swallowed.

H314 Causes severe skin burns and eye damage.

H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T+ Very toxic

R53

R51

R34

R26/27/28

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Phenol-1,1,2,2-Tetrachloroethane 60:40 w/w

Composition:

0001: 1,1,2,2-Tetrachloroethane

Formula: CHCl2HCCl2 M.= 167,84 CAS [79-34-5]

EC number (EINECS): 201-197-8

EC index number: 602-015-00-3

Content: >= 25 % <= 40 %

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Aquatic Chronic 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal in contact with skin.

H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash...thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 Wear respiratory protection.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P320 Specific treatment is urgent (see on this label).

P322 Specific measures (see on this label).

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T+ Very toxic

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R26/27 Very toxic by inhalation and in contact with skin.

0002: Phenol crystallized *(detached crystals)

Formula: C6H6O M.= 94,11 CAS [108-95-2]

EC number (EINECS): 203-632-7

EC index number: 604-001-00-2

REACH Registration Number: 01-2119471329-32-XXXX

Content: >= 60 % <= 75 %

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Skin Corr. 1B

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

T Toxic

R68 Possible risk of irreversible effects.

R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.

R34 Causes burns.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of soap and water. Remove contaminated clothing. Take the product out with cotton wool soaked in polyethylene-glycol 400.

4.4 Eyes:

Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Avoid vomiting (there is a risk of perforation). Seek immediate medical assistance. Do not neutralize.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Foam.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Combustible. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air. In the event of fire, toxic fumes may form.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes. Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.Away from light.In well ventilated premises.Keep away from flammable substances, sources of ignition and heat.Room temperature.Restricted access, only authorized to technicians.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-ED (1,1,2,2-tetrac.): 1 ppm - 7 mg/m3 dermal resorption

VLA-ED(phenol): 5 ppm - 20 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter A. Filter P3.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use complete protective equipment. Wash hands and face before breaks and when the job is done. Do not eat, drink or smoke in the workplace.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: N/A

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 1,234

Solubility: Miscible with ehtanol

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

Aluminium. Aldehydes. Halogens. Nitrites. Nitrates. Hydrogen peroxide. Ferric compounds. Salts of oxyhalogenic acids. Peroxides. Rubber. Alkaline metals. Strong bases. Strong oxidant agents.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

No specific data.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

If fumes inhaled: Irritations to the mucosae coughing breathing difficulties Due to absorption: headaches nausea vomiting narcosis If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Upon contact with the skin: burns Risk of cutaneous absorption. Through contact with the eyes: burns Risk of blindness (irreversible injury of the optic nerve) Systemic effects: effects on the central nervous system cardiovascular disorders blood alterations sensitization allergic reaction narcosis hepatic problems kidney problems Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 25 mg/l

Classification:

Extr. toxic

Crustaceans (Daphnia magna) 100 mg/l

Classification:

Extr. toxic

Fish (C. auratus) 44,5 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

High

12.1.3. - Observations:

High toxicity.

12.2 Persistence and Degradability :

12.2.1 - Test:

COD 2,3 g/g

BOD5 = 1,88 g/g

ThOD 2,26 mg/g

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

High, over 1/3

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Non-bioaccumulable product.

12.4 Mobility in soil :

Repartition: log P(oct)= -1,46

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Water-pollutant product.

Bactericide effect.

Do not allow it to enter soils or water channels.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Class: 6.1 CONTAM. MAR Packaging group: II (D/E)

By sea (IMDG):

Technical name: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Class: 6.1 CONTAM. MAR Packaging group: II

By air (ICAI-IATA):

Technical name: Toxic liquid, organic, n.o.s.

UN 2810 Class: 6.1 CONTAM. MAR Packaging group: II

Packaging instructions: CAO 662 PAX 654

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P284 Wear respiratory protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R53 May cause long-term adverse effects in the aquatic environment.

R51 Toxic to aquatic organisms.

R34 Causes burns.

R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.

S-phrase(s):

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S38 In case of insufficient ventilation, wear suitable respiratory equipment.

S28f After contact with skin, wash immediately and plentifully with polyethylene glycol 400 and with plenty of water.

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

5396 Фенол-1,1,2,2-Тетрахлорэтан 60:40 (масс.)

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Фенол-1,1,2,2-Тетрахлорэтан 60:40 (масс.)

Synonym:

1,1,2,2-Тетрахлорэтан-Фенол

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Acute Tox. 2

Skin Corr. 1B

Aquatic Chronic 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal в contact с skin.

H300 Fatal При попадании внутрь.

H314 Causes severe skin ожоги и eye damage.

H411 Токсично до aquatic life с long lasting effects.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P262 Do not get в глаза, on skin, или on clothing.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T+ Очень токсично

R53

R51

R34

R26/27/28

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Фенол-1,1,2,2-Тетрахлорэтан 60:40 (масс.)

Состав:

0001: 1,1,2,2-Тетрахлорэтан

Формула: CHCl2HCCl2 M.= 167,84 CAS [79-34-5]

Номер ЕС (EINECS): 201-197-8

ЕС индекс: 602-015-00-3

Content: >= 25 % <= 40 %

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 2

Acute Tox. 1

Aquatic Chronic 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H330 Fatal if inhaled.

H310 Fatal в contact с skin.

H411 Токсично до aquatic life с long lasting effects.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P262 Do not get в глаза, on skin, или on clothing.

P264 Wash...thoroughly после обращение.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P284 Wear Защита органов дыхания.

P302+P350 IF ON SKIN: Gently wash с plenty soap и вода.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P310 Immediately call a POISON CENTER или doctor/physician.

P320 Specific treatment is urgent (see on this label).

P322 Specific measures (see on this label).

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T+ Очень токсично

R51/53 Токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

R26/27 Очень токсично by inhalation и в contact с skin.

0002: Фенол кристалл. *(отдельн. кристаллы)

Формула: C6H6O M.= 94,11 CAS [108-95-2]

Номер ЕС (EINECS): 203-632-7

ЕС индекс: 604-001-00-2

REACH Registration Number: 01-2119471329-32-XXXX

Content: >= 60 % <= 75 %

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Skin Corr. 1B

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H314 Causes severe skin ожоги и eye damage.

H373 May cause damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

T Токсично

R68 Possible риск irreversible effects.

R48/20/21/22 Вредный: danger serious damage до health by prolonged exposure through inhalation, в contact с skin и При попадании внутрь.

R34 Может вызвать ожоги.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.

4.3 Контакт с кожей:

Wash с plenty soap и вода. Избавиться от загрязненной одежды. Соберите продукт ваткой, смоченной в полиэтилен-гликоле 400.

4.4 Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Avoid рвота (there is a риск perforation). Обратиться немедленно за медицинской помощью. Do not neutralize.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Пена.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Горючее Вещество. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом. В случае возгорания могут образовываться токсичные пары.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары. Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Away from light.В хорошо проветриваемом помещении.Keep away from воспламеняем соединения, sources ignition и heat.Room temperature.Ограничить право доступа к веществу, предоставив его только специалистам.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-ED (1,1,2,2-tetrac.): 1 ppm - 7 мг/м3 dermal resorption

VLA-ED(фенол): 5 ppm - 20 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A. Фильтр P3.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use complete Средства индивидуальной защиты. Мыть руки и лицо перед перерывами и после окончания работы. Do not eat, drink или smoke в the workplace.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: N/A

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность: (20/4) 1,234

Растворимость: Смешивается с ehtanol

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

Алюминий. Альдегид.. Галогены. Nitrites. Nitrates. Водорода пероксид. Ferric соединен.. Соли oxyhalogenic кислоты. Пероксиды. Резина. Щелочных металлы. Сильные основания. Strong Окислители.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

No specific data.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the mucosae coughing затруднение дыхания Due до absorption: headaches тошнота рвота narcosis При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Upon Контакт с кожей: ожоги Cуществует риск попадания в кровоток через кожные покровы. Контакт с глазами: ожоги Риск blindness (irreversible injury the optic nerve) Systemic effects: effects on the central nervous system cardiovascular disorders blood alterations sensitization allergic reaction narcosis hepatic problems kidney problems Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 25 mg/l

Классификация:

Extr. токсично

Crustaceans (Daphnia magna) 100 mg/l

Классификация:

Extr. токсично

Рыбы (C. auratus) 44,5 mg/l

Классификация:

Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Высокий

12.1.3. - Наблюдения:

Высокий toxicity.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

COD 2,3 g/g

BOD5 = 1,88 g/g

ThOD 2,26 mg/g

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

Высокий, над 1/3

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Biodegradable product.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Non-bioaccumulable product.

12.4 Мобильность в soil :

Repartition: log P(oct)= -1,46

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Вода-Продукт загрязнения.

Bactericide effect.

Избегать попаданию вещества в почву и воду.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Класс: 6.1 CONTAM. MAR Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: TOXIC LIQUID, ORGANIC, N.O.S.

UN 2810 Класс: 6.1 CONTAM. MAR Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Токсично жидкость, органический, n.o.s.

UN 2810 Класс: 6.1 CONTAM. MAR Группа: II

Инструкция по упаковке: CAO 662 PAX 654

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P284 Wear Защита органов дыхания.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P302+P350 IF ON SKIN: Gently wash с plenty soap и вода.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P320 Specific treatment is urgent (see on this label).

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R53 May cause long-term adverse effects в the aquatic environment.

R51 Токсично до aquatic organisms.

R34 Может вызвать ожоги.

R26/27/28 Очень токсично by inhalation, в contact с skin и При попадании внутрь.

S-phrase(s):

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S38 В case insufficient ventilation, wear suitable respiratory equipment.

S28f После contact с skin, wash immediately и plentifully с Полиэтиленгликоль 400 и с plenty вода.

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Date published: 3.11.10

Номер рецензии и дата: 3 3.11.10




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