S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
1588 Schiff's Reagent
Identification of the substance/preparation and of the company or firm | |||
1.1 Identification of the substance or preparation Name: Schiff's Reagent
Synonym: Reagent for aldehydes
REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: | |||
For laboratory utilisation, analysis, research and fine chemistry.
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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No hazardous mixture as specified in Regulation (CE) 1272/2008.
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No hazardous mixture as specified in Classification (67/548/CEE or 1999/45/CE).
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Component Composition/Information | |||
Aqueous solution
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Name: Schiff's Reagent | |||
Composition:
0001: Hydrochloric Acid 37%
Formula: HCl M.= 36,46 CAS [7647-01-0] EC number (EINECS): 231-595-7 EC index number: 017-002-01-X REACH Registration Number: 01-2119484862-27-XXXX
Content: >= 1 % <= 5 %
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Classification Regulation (CE) nº 1272/2008.
Skin Corr. 1B STOT SE 3
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Hazard Pictograms
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Signal word Danger
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Hazard statements H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation.
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Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Classification (67/548/CEE or 1999/45/CE).
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First aid
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4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.
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4.5 Swallowing: Drink large amounts of water. Induce vomiting. In the event of sickness, seek medical assistance.
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Fire-fighting means
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5.1 Suitable fire-extinguishing means: As appropriate to the environment.
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5.2 Fire-fighting means which must NOT be used: No specific data.
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5.3 Special risks: Incombustible.
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5.4 Protective equipment: Suitable clothing and footwear.
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: Do not inhale the fumes.
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6.2 Precautions for care of the environment: Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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Handling and storage
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7.1 Handling: No special indications.
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7.2 Storage: Well sealed containers.In well ventilated premises.Away from light.Room temperature.
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Staff exposure/protection controls
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8.1 Technical protective measures: No special indications.
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8.2 Exposure limit control: : Data not available.
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8.3 Respiratory protection: In the event of fumes forming/aerosols, use suitable respiratory protection.
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8.4 Hand protection: Use suitable gloves
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Wash hands and face before breaks and when the job is done.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | |||
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Physical and chemical properties
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Appearance: liquid | |||
Colour: Colourless | |||
Granulometry: N/A | |||
Odour: Slightly piquant. | |||
pH: 2,2 | |||
Melting point/freezing point: N/A | |||
Initial boiling point and boiling range: N/A | |||
Flash point: N/A | |||
Flammability (solid, gas): N/A | |||
Upper/lower flammability or explosive limits: N/A | |||
Vapour pressure: N/A | |||
Vapour density: N/A | |||
Relative density: N/A | |||
Solubility: in Miscible with water | |||
Partition coefficient: n-octanol/water: N/A | |||
Auto-ignition temperature: N/A | |||
Decomposition temperature: N/A | |||
Viscosity: N/A | |||
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Stability and reactivity
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10.1 Conditions which should be avoided: High temperatures.
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10.2 Matter which should be avoided: Acids. (Formation of Sulphoxides.
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10.3 Hazardous decomposition products: No specific data.
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10.4 Complementary information: No specific data.
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Toxicological information
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: Data not available.
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The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Upon contact with the skin: irritations slight Through contact with the eyes: irritations slight Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
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12.1 Toxicity: 12.1.1 - EC50 test (mg/l): Risk for the water environment Risk for the land environment 12.1.3. - Observations: Ecotoxic data not available.
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12.2 Persistence and Degradability : 12.2.1 - Test: 12.2.2. - Biotic degradation classification: BOD5/COD Biodegradability 12.2.3. - Abiotic degradation depending on pH: 12.2.4. - Observations:
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12.3 Bioaccumulative potential: 12.3.1. - Test: 12.3.2. - Bioaccumulation: Risk 12.3.3. - Observations:
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12.4 Mobility in soil : Data not available.
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12.5 Assessment PBT and MPMB : Data not available.
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12.6 Other possible effects on the environment: If suitable handling conditions are maintained, no ecological problems are to be anticipated.
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Considerations regarding elimination
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13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
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Not classified as dangerous in the meaning of transport regulations.
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Regulatory information
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The substance is subject to Regulation (EC) No 273/2004 of the European Parliament and of the Council, of 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors, Commission Regulation (EC) No 1277/2005 of 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and for Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors.
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Other information
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Review number and date: 4 15.09.2011 Date published: 15.09.2011 In respect of the previous review, changes have been made to the following sections: 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
1588 Schiff's Реагент
Определение вещества/preparation и the company или firm | |||
1.1 Определение вещества или preparation Название: Schiff's Реагент
Synonym: Реагент for альдегид.
REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use вещества/preparation: | |||
Для общелабораторного использования, анализов, исследований и тонкой химии.
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1.3 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
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Классификация вещества или the mixture.
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No опасная доза mixture как specified в Regulation (CE) 1272/2008.
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No опасная доза mixture как specified в Классификация (67/548/CEE или 1999/45/CE).
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Сведения о компонентах и состав | |||
Водный раствор
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Название: Schiff's Реагент | |||
Состав:
0001: Соляная Кислота 37%
Формула: HCl M.= 36,46 CAS [7647-01-0] Номер ЕС (EINECS): 231-595-7 ЕС индекс: 017-002-01-X REACH Registration Number: 01-2119484862-27-XXXX
Content: >= 1 % <= 5 %
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Классификация Regulation (CE) nº 1272/2008.
Skin Corr. 1B STOT SE 3
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Hazard Pictograms
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Signal word Danger
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Hazard statements H314 Causes severe skin ожоги и eye damage. H335 May cause respiratory irritation.
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Precautionary statements P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P271 Use only outdoors или в a well-ventilated area. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P310 Immediately call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present и easy до do. Continue rinsing. P363 Wash contaminated clothing before reuse. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация (67/548/CEE или 1999/45/CE).
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Первая помощь
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4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды, Веки постоянно держать открытыми. При раздражении кожи, Обратиться за медицинской помощью.
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. В the event sickness, Обратиться за медицинской помощью.
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Меры и средства обеспечения пожаро- и взрывобезопасности
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5.1 Пригодные средства пожаротушения: Не опасные для окружающей среды.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used: No specific data.
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5.3 Особая опасность: Incombustible.
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5.4 Средства индивидуальной защиты: Специальная одежда и обувь.
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
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6.1 Индивидуальные меры предосторожности: Не вдыхать пары.
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6.2 Меры по защите окружающей среды: Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.
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Правила обращения и хранения
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7.1 Обращение: Специальные указания отсутствуют.
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7.2 Хранение: В запечатанных контейнерах.В хорошо проветриваемом помещении.Away from light.Room temperature.
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Требования по охране труда и меры по обеспечению безопасности персонала
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8.1 Технические меры защиты: Специальные указания отсутствуют.
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8.2 Контроль предельно допустимого уровня воздействия: : Нет данных.
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания.
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8.4 Защита рук: Использовать защитные перчатки
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8.5 Защита глаз: Использовать защитные очки.
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Мыть руки и лицо перед перерывами и после окончания работы.
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8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | |||
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Физико-химические свойства
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Внешний Вид: жидкость | |||
Цвета: Бесцветная | |||
Granulometry: N/A | |||
Запах: Слабо piquant. | |||
pH: 2,2 | |||
точка плавления/Температура замерзания: N/A | |||
Initial Точка кипения и Интервал температур кипения: N/A | |||
Точка воспламенения: N/A | |||
Flammability (solid, gas): N/A | |||
Верхний/нижний flammability или explosive показатели: N/A | |||
Давление пара: N/A | |||
Vapour плотность: N/A | |||
Relative плотность: N/A | |||
Растворимость: в Смешивается с водой | |||
Partition coefficient: n-октанол/вода: N/A | |||
Auto-ignition temperature: N/A | |||
Decomposition temperature: N/A | |||
Вязк.: N/A | |||
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Стабильность и реакционноспособность
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10.1 Условия, которых следует избегать: Высокий temperatures.
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10.2 Вещества, которых следует избегать: Кислоты. (Formation Sulphoxides.
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10.3 Опасные продукты разложения: No specific data.
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10.4 Общая информация: No specific data.
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Токсикологическая информация
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: Нет данных.
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The data we have are insufficient for correct toxicological assessment. Based on the physico-chemical properties, the likely dangerous characteristics are: Upon Контакт с кожей: irritations slight Контакт с глазами: irritations slight Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
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Информация по окружающей среде
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12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): Риск для водной среды Риск для земли 12.1.3. - Наблюдения: Ecotoxic Нет данных.
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12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Классификация биотического периода распада: BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от рН: 12.2.4. - Наблюдения:
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения:
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12.4 Мобильность в soil : Нет данных.
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12.5 Assessment PBT и MPMB : Нет данных.
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12.6 Другие возможные воздействия на окружающую среду: При правильном обращении с продуктом не вызывает угрозу окружающей среде.
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Правила утилизации
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13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
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13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
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Информация относительно транспорта
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Not classified как dangerous в the meaning ТРАНСПОРТНЫЕ ПОЛОЖЕНИЯ.
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Regulatory information
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The соединен. is subject до Regulation (EC) No 273/2004 the Европейск. Parliament и the Council, 11 February 2004 on drug precursors, Council Regulation (EC) No 111/2005 22 December 2004 laying down rules for the monitoring trade between the Community и third countries в drug precursors, Commission Regulation (EC) No 1277/2005 27 July 2005 laying down implementing rules for Regulation (EC) No 273/2004 the Европейск. Parliament и the Council on drug precursors и for Council Regulation (EC) No 111/2005 laying down rules for the monitoring trade between the Community и third countries в drug precursors.
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Дополнительная информация
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Номер рецензии и дата: 4 15.09.2011 Date published: 15.09.2011 Относительно предыдущего обзора изменения были произведены в следующих разделах: 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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