S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Calcium *standard solution Ca=1,000+-0,002 g/l

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

H315 Causes skin irritation.

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Calcium *standard solution Ca=1,000+-0,002 g/l

Composition:

Formula: HNO3 M.= 63,01 CAS [7697-37-2]

EC number (EINECS): 231-714-2

Content: >= 1 % <= 5 %

Classification Regulation (CE) nº 1272/2008.

Eye Irrit. 2

Skin Irrit. 2

Hazard Pictograms

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation.

H315 Causes skin irritation.

Precautionary statements

P264 Wash...thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P321 Specific treatment (see on this label).

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

Classification (67/548/CEE or 1999/45/CE).

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. In the event of irritation, seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible. In the event of fire, toxic fumes may form:

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Atmospheric temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-EC(HNO3): 4 ppm - 10 mg/m3

VLA-ED(HNO3): 5,2 mg/m3

VLA-ED(HNO3): 2 ppm

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter B. Filter P. Filter NOX.

8.4 Hand protection:

Use suitable gloves neopren latex

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour:

N/A

Granulometry: N/A

Odour: Odourless.

pH: 0,5

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density: (20/4) 1,01

Solubility: Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

Metals. Organic compounds.

10.3 Hazardous decomposition products:

Nitrous fumes.

10.4 Complementary information:

No specific data.

Toxicological information

• Acute toxicity:

: Data not available.

• Dangerous effects for health:

If fumes inhaled: Irritations to the respiratory tracts. coughing breathing difficulties Upon contact with the skin: irritations burns Through contact with the eyes: irritations burns If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Fish

(Nitrates) > 500 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

Medium

Risk for the land environment

Low

12.1.3. - Observations:

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Encourages eotrophy in rivers and water channels.

DATA BASED on the components of the preparation.

(Soluble compounds of calcium).

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III (E)

By sea (IMDG):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III

By air (ICAI-IATA):

Technical name: Corrosive liquid, n.o.s

UN 1760 Class: 8 Packaging group: III

Packaging instructions: CAO 856 PAX 852

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.