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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1255 Cobalt(II) Acetate 4-hydrate

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Cobalt(II) Acetate 4-hydrate

Synonym:

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 1B

Resp. Sens 1

Skin Sens. 1

Muta. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H360F May damage fertility.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T Toxic

R68

R42/43

R60

R49

R50/53

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Cobalt(II) Acetate 4-hydrate

Formula: Co(CH3COO)2.4H2O M.= 249,08 CAS [6147-53-1]

EC number (EINECS): 200-755-8

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event sickness persists, seek medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Incombustible.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the dust.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.Restricted access, only authorized to technicians.In well ventilated premises.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

VLA-ED(Co): 0,02 mg/m3

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection. Filter P3.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done. Avoid the formation of dust. Do not inhale the substance.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: Red-violet

Granulometry: N/A

Odour: Odourless.

pH: 7,2 (50 g/l)

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: 380 g/l in water20 °C

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

No specific data.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

Moisture sensitive. Through heating, the product loses the crystallization water.

Toxicological information

  • Acute toxicity:

LD50 oral rat : 708 mg/kg

  • Dangerous effects for health:

If inhaled: Carcinogenic in animal testing. Symptoms due to acute intoxication of (Co): diarrhoea loss of appetite anxiety spasms hypotension kidney problems cardiovascular disorders pancreas disorders Risk of sensitization allergic reaction Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

Bacteria (Photobacterium phosphoreum) 16 mg/l

Classification:

Extr. toxic

Fish 4,0 mg/l

Classification:

Extr. toxic

Bacteria 6,2 mg/l

Classification:

Extr. toxic

Mammals 5,0 mg/l

Classification:

Extr. toxic

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

Extremely toxic in water supplies and soils. Ecotoxicity acute and chronic.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk = ----

12.3.3. - Observations:

Bioaccumulable product.

(Co)

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Not classified as dangerous in the meaning of transport regulations.

Regulatory information

The substance is included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)

Other information

Other precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P285 In case of inadequate ventilation wear respiratory protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R68 Possible risk of irreversible effects.

R42/43 May cause sensitisation by inhalation and skin contact.

R60 May impair fertility.

R49 May cause cancer by inhalation.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s):

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S60 This material and its container must be disposed of as hazardous waste.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1255 Кобальт(II) Ацетат 4-водный

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Кобальт(II) Ацетат 4-водный

Synonym:

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 1B

Resp. Sens 1

Skin Sens. 1

Muta. 2

Aquatic Acute 1

Aquatic Chronic 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H350i May cause cancer by inhalation.

H360F May damage fertility.

H334 May cause allergy или asthma symptoms или затруднение дыхания if inhaled.

H317 May cause an allergic skin reaction.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H410 Очень токсично до aquatic life с long lasting effects.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out the workplace.

P273 Avoid release до the environment.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T Токсично

R68

R42/43

R60

R49

R50/53

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Кобальт(II) Ацетат 4-водный

Формула: Co(CH3COO)2.4H2O M.= 249,08 CAS [6147-53-1]

Номер ЕС (EINECS): 200-755-8

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Incombustible.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пыль.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.Ограничить право доступа к веществу, предоставив его только специалистам.В хорошо проветриваемом помещении.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-ED(Co): 0,02 мг/м3

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания. Фильтр P3.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы. Avoid the formation dust. Do not inhale the соединен..

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Красно-Фиолетов.

Granulometry: N/A

Запах: Без Запаха.

pH: 7,2 (50 г/л)

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: 380 г/л в воде20 °C

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

No specific data.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

Moisture sensitive. Through heating, the product loses the crystallization вода.

Токсикологическая информация

  • Высокая токсичность:

LD50 oral rat : 708 мг/кг

  • Опасное воздействие на здоровье:

If inhaled: Carcinogenic в animal testing. Symptoms due до acute intoxication (Co): diarrhoea loss appetite anxiety spasms hypotension kidney problems cardiovascular disorders pancreas disorders Риск sensitization allergic reaction Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

Бактерии (Photobacterium phosphoreum) 16 mg/l

Классификация:

Extr. токсично

Рыбы 4,0 mg/l

Классификация:

Extr. токсично

Бактерии 6,2 mg/l

Классификация:

Extr. токсично

Mammals 5,0 mg/l

Классификация:

Extr. токсично

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

Extremely токсично в воде supplies и soils. Экотоксичность acute и chronic.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск = ----

12.3.3. - Наблюдения:

Bioaccumulable product.

(Co)

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Not classified как dangerous в the meaning ТРАНСПОРТНЫЕ ПОЛОЖЕНИЯ.

Regulatory information

The соединен. is included в the Candidate List Соединения Very Высокий Concern (SVHC) в соответствии с Regulation (EC) No. 1907/2006 (REACH)

Дополнительная информация

Др. precautionary statements

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P285 В case inadequate ventilation wear Защита органов дыхания.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P304+P341 IF INHALED: If breathing is difficult, remove victim до fresh air и keep при rest в a position comfortable for breathing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P321 Specific treatment (see on this label).

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER или doctor/physician.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R68 Possible риск irreversible effects.

R42/43 May cause sensitisation by inhalation и skin contact.

R60 May impair fertility.

R49 May cause cancer by inhalation.

R50/53 Очень токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

S-phrase(s):

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S60 This material и its container must be disposed как опасная доза waste.

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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