Показать русскую версию

S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

A715 Anilinium Sulphate

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Anilinium Sulphate

Synonym:

Aniline Sulphate

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Carc. 2

Eye Dam. 1

Skin Sens. 1

STOT RE 1

Muta. 2

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H331 Toxic if inhaled.

H311 Toxic in contact with skin.

H301 Toxic if swallowed.

H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs of exposure cause the hazard>.

H318 Causes serious eye damage.

H317 May cause an allergic skin reaction.

H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H400 Very toxic to aquatic life.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T Toxic

R43

R41

R40

R23/24/25

R48/23/24/25

R68

R50

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Anilinium Sulphate

Formula: C12H14N2.H2SO4 M.= 284,33 CAS [542-16-5]

EC number (EINECS): 208-805-0

EC index number: 612-009-00-2

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed immediately to provide artificial respiration. Seek immediate medical assistance.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open.

4.5 Swallowing:

Drink large amounts of water. Drink large amounts of water. Induce vomiting. Induce vomiting. Seek immediate medical assistance. Seek immediate medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Combustible. Keep away from sources of ignition. In the event of fire, toxic fumes may form. Precipitate fumes formed with water.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the dust.

6.2 Precautions for care of the environment:

Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Dry atmosphere.In well ventilated premises.Away from sources of ignition and heat.Away from light.Restricted access, only authorized to technicians.Room temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

No special indications.

8.2 Exposure limit control:

: Data not available.

8.3 Respiratory protection:

If dust forms, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use complete protective equipment. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: solid

Colour: White or slightly yellow

Granulometry: N/A

Odour: Odourless.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point:

N/A

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: in Soluble in water.

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

Direct sunlight. High temperatures.

10.2 Matter which should be avoided:

Acids. Oxidant agents (amongst others: perchloric acid, perchlorates, halogenates, CrO3, halogen oxides, nitric acid, nitrogen oxides, non-metal oxides, chromo-sulphuric acid). Alkaline metals. Air

10.3 Hazardous decomposition products:

Phosgene. Carbon monoxide. Chlorine. Hydrogen chloride. Nitrogen oxides.

10.4 Complementary information:

Hygroscopic. Light-sensitive.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

If fumes inhaled: Irritations to the mucosae breathing difficulties coughing Upon contact with the skin: Irritations to the skin and mucosae. Risk of cutaneous absorption. Through contact with the eyes: irritations If swallowed: nausea vomiting Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. Can cause kidney problems If it is absorbed in large quantities: metahemoglobinemia with headaches hypotension spasms cyanosis arrhythmia breathing difficulties Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Toxicity:

12.1.1 - EC50 test (mg/l):

12.1.2. - Receptor medium:

Risk for the water environment

High

Risk for the land environment

Medium

12.1.3. - Observations:

High toxicity in water environment.

12.2 Persistence and Degradability :

12.2.1 - Test:

12.2.2. - Biotic degradation classification:

BOD5/COD

Biodegradability

12.2.3. - Abiotic degradation depending on pH:

12.2.4. - Observations:

Data not available.

12.3 Bioaccumulative potential:

12.3.1. - Test:

12.3.2. - Bioaccumulation:

Risk

12.3.3. - Observations:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

Do not allow it to enter soils or water channels.

Water-pollutant product.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: TOXIC SOLID, ORGANIC, N.O.S.

UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III (E)

By sea (IMDG):

Technical name: TOXIC SOLID, ORGANIC, N.O.S.

UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

By air (ICAI-IATA):

Technical name: Toxic solid, organic, n.o.s.

UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: III

Packaging instructions: CAO 677 PAX 670

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

P311 Call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R41 Risk of serious damage to eyes.

R40 Limited evidence of a carcinogenic effect.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.

R68 Possible risk of irreversible effects.

R50 Very toxic to aquatic organisms.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S27 Take off immediately all contaminated clothing.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest.

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

A715 Anilinium Сульфат

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Anilinium Сульфат

Synonym:

Анилин Сульфат

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Acute Tox. 3

Acute Tox. 3

Acute Tox. 3

Carc. 2

Eye Dam. 1

Skin Sens. 1

STOT RE 1

Muta. 2

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H331 Токсично if inhaled.

H311 Токсично в contact с skin.

H301 Токсично При попадании внутрь.

H351 Suspected causing cancer <state route exposure if it is conclusively proven that no др. routs exposure cause the hazard>.

H318 Causes serious eye damage.

H317 May cause an allergic skin reaction.

H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H400 Очень токсично до aquatic life.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T Токсично

R43

R41

R40

R23/24/25

R48/23/24/25

R68

R50

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Anilinium Сульфат

Формула: C12H14N2.H2SO4 M.= 284,33 CAS [542-16-5]

Номер ЕС (EINECS): 208-805-0

ЕС индекс: 612-009-00-2

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В случае удушья немедленно сделать искусственное дыхание. Обратиться немедленно за медицинской помощью.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми.

4.5 Попадание Внутрь:

Выпить большое количество воды. Выпить большое количество воды. Вызвать рвоту. Вызвать рвоту. Обратиться немедленно за медицинской помощью. Обратиться немедленно за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Горючее Вещество. Держать на расстоянии от источников возгорания. В случае возгорания могут образовываться токсичные пары. Precipitate fumes formed с водой.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пыль.

6.2 Меры по защите окружающей среды:

Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.Сухая атмосфера.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.Away from light.Ограничить право доступа к веществу, предоставив его только специалистам.Room temperature.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Специальные указания отсутствуют.

8.2 Контроль предельно допустимого уровня воздействия:

: Нет данных.

8.3 Защита органов дыхания:

If dust forms, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use complete Средства индивидуальной защиты. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: solid

Цвета: Белый или слабо желт.

Granulometry: N/A

Запах: Без Запаха.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения:

N/A

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: в Растворяется в воде.

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:

N/A

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Direct sunlight. Высокий temperatures.

10.2 Вещества, которых следует избегать:

Кислоты. Окислители (: перхлорная кислота, перхлораты, галогены, CrO3, оксиды галогенов, Азотная кислота, оксиды азота, оксиды не металлов, раствор хромового ангидрида в серной кислоте). Щелочных металлы. Air

10.3 Опасные продукты разложения:

Phosgene. Моноксид углерода. Хлор. Водород хлорид. оксиды азота.

10.4 Общая информация:

Гигроскопичный. Light-sensitive.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the mucosae затруднение дыхания coughing Upon Контакт с кожей: Irritations до the skin и mucosae. Cуществует риск попадания в кровоток через кожные покровы. Контакт с глазами: irritations При попадании внутрь: тошнота рвота Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. Can cause kidney problems При попадании в больших количествах: metahemoglobinemia с headaches hypotension spasms cyanosis arrhythmia затруднение дыхания Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Toxicity:

12.1.1 - EC50 тест (mg/l):

12.1.2. - Воздействие на окружающую среду:

Риск для водной среды

Высокий

Риск для земли

Средний

12.1.3. - Наблюдения:

Высокий toxicity в воде environment.

12.2 Persistence и Период Распада :

12.2.1 - Тест:

12.2.2. - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.2.3. - Абиотический период распада зависит от рН:

12.2.4. - Наблюдения:

Нет данных.

12.3 Bioaccumulative potential:

12.3.1. - Тест:

12.3.2. - Биоаккумуляция:

Риск

12.3.3. - Наблюдения:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

Избегать попаданию вещества в почву и воду.

Вода-Продукт загрязнения.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: TOXIC SOLID, ORGANIC, N.O.S.

UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III (E)

Морской транспорт (IMDG):

Техническое название: TOXIC SOLID, ORGANIC, N.O.S.

UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Токсично solid, органический, n.o.s.

UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: III

Инструкция по упаковке: CAO 677 PAX 670

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P270 Do no eat, drink или smoke when using this product.

P271 Use only outdoors или в a well-ventilated area.

P272 Contaminated work clothing should not be allowed out the workplace.

P273 Avoid release до the environment.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P302+P352 IF ON SKIN: Wash с plenty soap и вода.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER или doctor/physician.

P311 Call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P314 Get medical advice/attention if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation или rash occurs: Get medical advice/attention.

P361 Remove/Take off immediately all contaminated clothing.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R43 May cause sensitisation by skin contact.

R41 Риск serious damage до глаза.

R40 Limited evidence a carcinogenic effect.

R23/24/25 Токсично by inhalation, в contact с skin и При попадании внутрь.

R48/23/24/25 Токсично: danger serious damage до health by prolonged exposure through inhalation, в contact с skin и При попадании внутрь.

R68 Possible риск irreversible effects.

R50 Очень токсично до aquatic organisms.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S36/37/39 Wear suitable protective clothing, gloves и eye/face protection.

S27 Take off immediately all contaminated clothing.

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

S63 В case accident by inhalation: remove casualty до fresh air и keep при rest.

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Date published: 3.11.10

Номер рецензии и дата: 3 3.11.10




chevron-up