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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

1327 Phenolphthalein solution 1%

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Phenolphthalein solution 1%

Synonym:

3,3-bis-(4-Hydroxyphenyl)-1-(3H)-iso-Benzofuranone, 3,3-bis-(4-Hydroxyphenyl)Phtalide

REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.

1.2 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.3 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Carc. 1B

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

T Toxic

F Highly flammable

R68

R45

R10

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Hydroalcoholic solution

Name: Phenolphthalein solution 1%

Formula: C20H14O4 M.= 318,33

Composition:

0001: Ethanol absolute

Formula: CH3CH2OH M.= 46,07 CAS [64-17-5]

EC number (EINECS): 200-578-6

EC index number: 603-002-00-5

REACH Registration Number: 01-2119457610-43-XXXX

Content: >= 50 %

Classification Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

P243 Take precautionary measures against static discharge.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P370+P378 In case of fire: Use for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

Classification (67/548/CEE or 1999/45/CE).

F Highly flammable

R11 Highly flammable.

0002: Phenolphthalein

Formula: C20H14O4 M.= 318,33 CAS [77-09-8]

EC number (EINECS): 201-004-7

Content: 1 %

Classification Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 2

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H361f Suspected of damaging fertility.

H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P281 Use personal protective equipment as required.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

T Toxic

R68 Possible risk of irreversible effects.

R62 Possible risk of impaired fertility.

R45 May cause cancer.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air. In the event of suffocation, proceed to provide artificial respiration.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Induce vomiting. Do not administer emetics. Do not administer animal carbon. Do not drink milk. In the event of sickness, seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

Water. Carbon dioxide (CO2). Foam. Dry powder.

5.2 Fire-fighting means which must NOT be used:

No specific data.

5.3 Special risks:

Flammable. Keep away from sources of ignition. The fumes are heavier than air, so they may spread at floor level. May form explosive mixtures with the air.

5.4 Protective equipment:

Suitable clothing and footwear.

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Do not inhale the fumes.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.In well ventilated premises.Away from sources of ignition and heat.Atmospheric temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

Ensure good ventilation and renewal of the air in the premises.

8.2 Exposure limit control:

VLA-ED(ethanol): 1.000 ppm - 1.910 mg/m3

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection. Filter A. Filter P.

8.4 Hand protection:

Use suitable gloves neopren nitrile PVC

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Colourless

Granulometry: N/A

Odour: Characteristic.

pH:

N/A

Melting point/freezing point: N/A

Initial boiling point and boiling range:

N/A

Flash point: 23 °C

Flammability (solid, gas):

N/A

Upper/lower flammability or explosive limits:

N/A

Vapour pressure: N/A

Vapour density: N/A

Relative density:

N/A

Solubility: in Miscible with water

Partition coefficient: n-octanol/water:

N/A

Auto-ignition temperature: ~425 °C

Decomposition temperature: N/A

Viscosity: N/A

Stability and reactivity

10.1 Conditions which should be avoided:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Matter which should be avoided:

No specific data.

10.3 Hazardous decomposition products:

No specific data.

10.4 Complementary information:

The gases/fumes can form explosive mixtures with the air.

Toxicological information

  • Acute toxicity:

: Data not available.

  • Dangerous effects for health:

Taking the preparation' components into account, the likely dangerous characteristics are as follows: Irritations to the mucosae slight If swallowed: Absorption effects on the central nervous system intoxication anxiety ataxia (motor coordination disorders) respiratory paralysis narcosis

Environmental information

12.1 Toxicity:

Daphnia EC0 7800 mg/l

Fish LC50 > 10000 mg/l

12.2 Persistence and Degradability :

Biodegradable product.

12.3 Bioaccumulative potential:

Data not available.

12.4 Mobility in soil :

Data not available.

12.5 Assessment PBT and MPMB :

Data not available.

12.6 Other possible effects on the environment:

No interferences are to be anticipated in treatment plants if use correctly.

If suitable handling conditions are maintained, no ecological problems are to be anticipated.

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: FLAMMABLE LIQUID, N.O.S.

UN 1993 Class: 3 Packaging group: III (D/E)

By sea (IMDG):

Technical name: FLAMMABLE LIQUID, N.O.S.

UN 1993 Class: 3 Packaging group: III

By air (ICAI-IATA):

Technical name: Flammable liquid, n.o.s.

UN 1993 Class: 3 Packaging group: III

Packaging instructions: CAO 366 PAX 355

Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Other information

Other precautionary statements

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P370+P378 In case of fire: Use for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R68 Possible risk of irreversible effects.

R45 May cause cancer.

R10 Flammable.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

S16 Keep away from sources of ignition - No smoking.

Review number and date: 4 15.09.2011

Date published: 15.09.2011

In respect of the previous review, changes have been made to the following sections: 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

1327 фенолфталеин раствор 1%

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

фенолфталеин раствор 1%

Synonym:

3,3-bis-(4-Hydroxyphenyl)-1-(3H)-iso-Benzofuranone, 3,3-bis-(4-Hydroxyphenyl)Phtalide

REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.

1.2 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.3 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4 Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Carc. 1B

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

H350 May cause cancer <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

T Токсично

F Легко воспламеняем

R68

R45

R10

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Hydroalcoholic раствор

Название: фенолфталеин раствор 1%

Формула: C20H14O4 M.= 318,33

Состав:

0001: Этанол absolute

Формула: CH3CH2OH M.= 46,07 CAS [64-17-5]

Номер ЕС (EINECS): 200-578-6

ЕС индекс: 603-002-00-5

REACH Registration Number: 01-2119457610-43-XXXX

Content: >= 50 %

Классификация Regulation (CE) nº 1272/2008.

Flam. Liq. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H225 Легко воспламеняем жидкость и vapour.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P233 Keep container tightly closed.

P240 Ground/bond container и receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

P243 Take precautionary measures against static discharge.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P370+P378 В case fire: Use for extinction.

P403+P235 Store в a well-ventilated place. Keep cool.

Классификация (67/548/CEE или 1999/45/CE).

F Легко воспламеняем

R11 Легко воспламеняем.

0002: фенолфталеин

Формула: C20H14O4 M.= 318,33 CAS [77-09-8]

Номер ЕС (EINECS): 201-004-7

Content: 1 %

Классификация Regulation (CE) nº 1272/2008.

Carc. 1B

Repr. 2

Muta. 2

Hazard Pictograms

Signal word

Danger

Hazard statements

H350 May cause cancer <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

H361f Suspected damaging fertility.

H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>.

Precautionary statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been чтение и understood.

P281 Use personal Средства индивидуальной защиты как required.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

T Токсично

R68 Possible риск irreversible effects.

R62 Possible риск impaired fertility.

R45 May cause cancer.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed до provide artificial respiration.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Вызвать рвоту. Do not administer emetics. Do not administer animal carbon. Do not drink milk. В the event sickness, Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Вода. Углекислый газ (CO2). Пена. Песок.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

No specific data.

5.3 Особая опасность:

Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air, so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом.

5.4 Средства индивидуальной защиты:

Специальная одежда и обувь.

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Не вдыхать пары.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.В хорошо проветриваемом помещении.Вдали от источников возгорания и тепла.При температуре воздуха.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

Обеспечивать хорошую вентиляцию и приток воздуха в помещение.

8.2 Контроль предельно допустимого уровня воздействия:

VLA-ED(этанол): 1.000 ppm - 1.910 мг/м3

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A. Фильтр P.

8.4 Защита рук:

Использовать защитные перчатки neopren nitrile PVC

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH:

N/A

точка плавления/Температура замерзания: N/A

Initial Точка кипения и Интервал температур кипения:

N/A

Точка воспламенения: 23 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

N/A

Растворимость: в Смешивается с водой

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature: ~425 °C

Decomposition temperature: N/A

Вязк.: N/A

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

The product is chemically stable under standar ambient conditions (room temperature).

10.2 Вещества, которых следует избегать:

No specific data.

10.3 Опасные продукты разложения:

No specific data.

10.4 Общая информация:

The gases/fumes can form explosive mixtures с the air.

Токсикологическая информация

  • Высокая токсичность:

: Нет данных.

  • Опасное воздействие на здоровье:

Taking the preparation' components into account, the likely dangerous characteristics are как follows: Irritations до the mucosae slight При попадании внутрь: Absorption effects on the central nervous system intoxication anxiety ataxia (motor coordination disorders) respiratory paralysis narcosis

Информация по окружающей среде

12.1 Toxicity:

Daphnia EC0 7800 mg/l

Рыбы LC50 > 10000 mg/l

12.2 Persistence и Период Распада :

Biodegradable product.

12.3 Bioaccumulative potential:

Нет данных.

12.4 Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

Нет данных.

12.6 Другие возможные воздействия на окружающую среду:

No interferences are до be anticipated в treatment plants if use correctly.

При правильном обращении с продуктом не вызывает угрозу окружающей среде.

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: FLAMMABLE LIQUID, N.O.S.

UN 1993 Класс: 3 Группа: III (D/E)

Морской транспорт (IMDG):

Техническое название: FLAMMABLE LIQUID, N.O.S.

UN 1993 Класс: 3 Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Воспламеняем жидкость, n.o.s.

UN 1993 Класс: 3 Группа: III

Инструкция по упаковке: CAO 366 PAX 355

Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

Дополнительная информация

Др. precautionary statements

P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P281 Use personal Средства индивидуальной защиты как required.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P308+P313 IF exposed или concerned: Get medical advice/attention.

P370+P378 В case fire: Use for extinction.

P403+P235 Store в a well-ventilated place. Keep cool.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R68 Possible риск irreversible effects.

R45 May cause cancer.

R10 Воспламеняем.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S53 Avoid exposure - obtain special instructions before use.

S16 Держать на расстоянии от источников возгорания - Не курить.

Номер рецензии и дата: 4 15.09.2011

Date published: 15.09.2011

Относительно предыдущего обзора изменения были произведены в следующих разделах: 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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