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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

2482

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

1.2 Synonym:

1.3 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.4 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Flam. Gas 1

Press. Gas

Acute Tox. 2

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H220 Extremely flammable gas.

H330 Fatal if inhaled.

H400 Very toxic to aquatic life.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P284 Wear respiratory protection.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

N Dangerous for the environment

T+ Very toxic

F+ Extremely flammable

R50

R26

R12

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Formula: H2S M.= 34,08 CAS [7783-06-4]

EC number (EINECS): 231-977-3

EC index number: 016-001-00-4

First aid

4.1 General indications:

4.2 Inhaling:

4.3 Contact with the skin:

4.4 Eyes:

4.5 Swallowing:

Fire-fighting means

5.1 Suitable fire-extinguishing means:

5.2 Fire-fighting means which must NOT be used:

5.3 Special risks:

5.4 Protective equipment:

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

6.2 Precautions for care of the environment:

6.3 Methods for collection/cleaning:

Handling and storage

7.1 Handling:

7.2 Storage:

Staff exposure/protection controls

8.1 Technical protective measures:

8.2 Exposure limit control:

8.3 Respiratory protection:

8.4 Hand protection:

8.5 Eye protection:

8.6 Individual hygiene measures:

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance:

Colour:

Granulometry:

Odour:

pH:

Melting point/freezing point: -85 °C

Initial boiling point and boiling range: -60 °C

Flash point:

Flammability (solid, gas):

Upper/lower flammability or explosive limits: 45,5 %(V) / 4,3 %(V)

Vapour pressure: 18.000 hPa (20 °C)

Vapour density:

Relative density:

Solubility: 4 g/l in water at 20°C

Partition coefficient: n-octanol/water:

Auto-ignition temperature: 270 °C

Decomposition temperature:

Viscosity:

Stability and reactivity

10.1 Conditions which should be avoided:

10.2 Matter which should be avoided:

10.3 Hazardous decomposition products:

10.4 Complementary information:

Toxicological information

Acute toxicity:

Dangerous effects for health:

Environmental information

12.1 Mobility:

12.2 Ecotoxicity:

12.3 Degradability:

12.4 Accumulation:

12.5 Other possible effects on the environment:

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

Information concerning transport

Overland (ADR):

Technical name: HYDROGEN SULPHIDE

UN 1053 Class: 2.3 Packaging group: - (B/D)

By sea (IMDG):

Technical name: HYDROGEN SULPHIDE

UN 1053 Class: 2.3 Packaging group: -

By air (ICAI-IATA):

Technical name: Hydrogen sulphide

UN 1053 Class: 2.3 Packaging group: -

Packaging instructions: CAO P PAX P

Regulatory information

Other information

Other precautionary statements

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P320 Specific treatment is urgent (see on this label).

P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

P381 Eliminate all ignition sources if safe to do so.

P391 Collect spillage.

P403 Store in a well-ventilated place.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R50 Very toxic to aquatic organisms.

R26 Very toxic by inhalation.

R12 Extremely flammable.

S-phrase(s):

S38 In case of insufficient ventilation, wear suitable respiratory equipment.

S36 Wear suitable protective clothing.

S16 Keep away from sources of ignition - No smoking.

S9 Keep container in a well-ventilated place.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

Date published: 3.11.10

Review number and date: 3 3.11.10

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

2482

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

1.2 Synonym:

1.3 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.4 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Flam. Gas 1

Press. Gas

Acute Tox. 2

Aquatic Acute 1

Hazard Pictograms

Signal word

Danger

Hazard statements

H220 Extremely воспламеняем gas.

H330 Fatal if inhaled.

H400 Очень токсично до aquatic life.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P271 Use only outdoors или в a well-ventilated area.

P273 Avoid release до the environment.

P284 Wear Защита органов дыхания.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

N Dangerous for the environment

T+ Очень токсично

F+ Extremely воспламеняем

R50

R26

R12

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Формула: H2S M.= 34,08 CAS [7783-06-4]

Номер ЕС (EINECS): 231-977-3

ЕС индекс: 016-001-00-4

Первая помощь

4.1 Общие указания:

4.2 Вдыхание:

4.3 Контакт с кожей:

4.4 Глаза:

4.5 Попадание Внутрь:

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

5.3 Особая опасность:

5.4 Средства индивидуальной защиты:

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

6.2 Меры по защите окружающей среды:

6.3 Методы нейтрализации и очистки:

Правила обращения и хранения

7.1 Обращение:

7.2 Хранение:

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

8.2 Контроль предельно допустимого уровня воздействия:

8.3 Защита органов дыхания:

8.4 Защита рук:

8.5 Защита глаз:

8.6 Индивидуальные средства гигиены:

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид:

Цвета:

Granulometry:

Запах:

pH:

точка плавления/Температура замерзания: -85 °C

Initial Точка кипения и Интервал температур кипения: -60 °C

Точка воспламенения:

Flammability (solid, gas):

Верхний/нижний flammability или explosive показатели: 45,5 %(V) / 4,3 %(V)

Давление пара: 18.000 hPa (20 °C)

Vapour плотность:

Relative плотность:

Растворимость: 4 г/л в воде при 20°C

Partition coefficient: n-октанол/вода:

Auto-ignition temperature: 270 °C

Decomposition temperature:

Вязк.:

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

10.2 Вещества, которых следует избегать:

10.3 Опасные продукты разложения:

10.4 Общая информация:

Токсикологическая информация

Высокая токсичность:

Опасное воздействие на здоровье:

Информация по окружающей среде

12.1 Мобильность:

12.2 Экотоксичность:

12.3 Период Распада:

12.4 Аккумуляция:

12.5 Другие возможные воздействия на окружающую среду:

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: HYDROGEN SULPHIDE

UN 1053 Класс: 2.3 Группа: - (B/D)

Морской транспорт (IMDG):

Техническое название: HYDROGEN SULPHIDE

UN 1053 Класс: 2.3 Группа: -

Авиа транспорт (ICAI-IATA):

Техническое название: Водород сульфид

UN 1053 Класс: 2.3 Группа: -

Инструкция по упаковке: CAO P PAX P

Regulatory information

Дополнительная информация

Др. precautionary statements

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P310 Immediately call a POISON CENTER или doctor/physician.

P320 Specific treatment is urgent (see on this label).

P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

P381 Eliminate all ignition sources if safe до do so.

P391 Collect spillage.

P403 Store в a well-ventilated place.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R50 Очень токсично до aquatic organisms.

R26 Очень токсично by inhalation.

R12 Extremely воспламеняем.

S-phrase(s):

S38 В case insufficient ventilation, wear suitable respiratory equipment.

S36 Wear suitable protective clothing.

S16 Держать на расстоянии от источников возгорания - Не курить.

S9 Keep container в a well-ventilated place.

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S61 Avoid release до the environment. Refer до special instructions/safety data sheets.

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Date published: 3.11.10

Номер рецензии и дата: 3 3.11.10