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S a f e t y D a t a S h e e t

According to Regulation (EC) 1907/2006

3424 Titanium(III) Chloride solution 2% w/w

Identification of the substance/preparation and of the company or firm

1.1 Identification of the substance or preparation

Name:

Titanium(III) Chloride solution 2% w/w

1.2 Synonym:

1.3 Use of the substance/preparation:

For laboratory utilisation, analysis, research and fine chemistry.

1.4 Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Identification of dangers

Classification of the substance or the mixture.

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R37

R34

For the full text of the R-phrases mentioned in this section, see section 16.

Component Composition/Information

Name: Titanium(III) Chloride solution 2% w/w

Composition:

0001: Hydrochloric Acid 37%

Formula: HCl M.= 36,46 CAS [7647-01-0]

EC number (EINECS): 231-595-7

EC index number: 017-002-01-X

Content: >= 5 % <= 10 %

Classification Regulation (CE) nº 1272/2008.

Skin Corr. 1B, STOT SE 3

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Classification (67/548/CEE or 1999/45/CE).

C Corrosive

R37 Irritating to respiratory system.

R34 Causes burns.

First aid

4.1 General indications:

Never provide drink or induce vomiting in the event of loss of consciousness.

4.2 Inhaling:

Take the person out into the fresh air.

4.3 Contact with the skin:

Wash with plenty of water. Remove contaminated clothing. In the event of irritation, seek medical assistance.

4.4 Eyes:

Wash with plenty of water, keeping eyelids open. Seek medical assistance.

4.5 Swallowing:

Drink large amounts of water. Induce vomiting. Seek medical assistance.

Fire-fighting means

5.1 Suitable fire-extinguishing means:

As appropriate to the environment.

5.2 Fire-fighting means which must NOT be used:

5.3 Special risks:

Incombustible. In the event of fire, toxic fumes may form.

5.4 Protective equipment:

Measures to be taken in the event of accidental spillage

6.1 Individual precautions:

Avoid contact with the skin, eyes or clothing.

6.2 Precautions for care of the environment:

Avoid pollution of the soil, water supplies and drains.

6.3 Methods for collection/cleaning:

Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.

Handling and storage

7.1 Handling:

No special indications.

7.2 Storage:

Well sealed containers.Atmospheric temperature.

Staff exposure/protection controls

8.1 Technical protective measures:

8.2 Exposure limit control:

VLA-ED(HCl): 7 mg/m3

VLA-ED(HCl): 5 ppm

8.3 Respiratory protection:

In the event of fumes forming/aerosols, use suitable respiratory protection.

8.4 Hand protection:

Use suitable gloves

8.5 Eye protection:

Use suitable goggles.

8.6 Individual hygiene measures:

Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done.

8.7 Environmental exposure controls:

Fulfill the commitments under local environmental protection legislation.

Physical and chemical properties

Appearance: liquid

Colour: Violet

Granulometry:

Odour: Piquant.

pH:

Melting point/freezing point:

Initial boiling point and boiling range:

Flash point:

Flammability (solid, gas):

Upper/lower flammability or explosive limits:

Vapour pressure: 587 hPa (20 °C)

Vapour density:

Relative density: (20/4) 1,067

Solubility: Miscible with water

Partition coefficient: n-octanol/water:

Auto-ignition temperature:

Decomposition temperature:

Viscosity:

Stability and reactivity

10.1 Conditions which should be avoided:

High temperatures.

10.2 Matter which should be avoided:

Metals. Alkaline solutions.

10.3 Hazardous decomposition products:

Hydrogen chloride. Chlorine.

10.4 Complementary information:

Toxicological information

  • Acute toxicity:

  • Dangerous effects for health:

If fumes inhaled: Irritations to the respiratory tracts. Causes coughing breathing difficulties Upon contact with the skin: irritations burns Through contact with the eyes: irritations burns If swallowed: Irritations of the mucosae in the mouth, throat, oesophagus and intestinal tract. No damage is anticipated to the foetus, provided the VLA values are respected (maximum admissible concentration in the workplace). Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.

Environmental information

12.1 Mobility:

12.2 Ecotoxicity:

12.1.1 - EC50 test (mg/l):

Fish test (HCl) 25 mg/l

Classification: Toxic

Fish (Leuciscus Idus) (HCl) 862 mg/l (48h)(1N)

Classification: Very toxic

12.2.2 - Receptor medium:

Risk for the water environment

Medium

Risk for the land environment

Medium

12.2.3 - Observations:

Has a major acute effect on the water and land environment depending on pH.

12.3 Degradability:

12.3.1 - Test:

12.3.2 - Biotic degradation classification:

BOD5/COD

Biodegradability

12.3.3 - Abiotic degradation depending on pH:

12.3.4 - Observations:

Data not available.

12.4 Accumulation:

12.4.1 - Test:

12.4.2 - Bioaccumulation:

Risk = ----

12.4.3 - Observations:

It is not bio-accumulable, although it is accumulable in water courses and soils in saline form (Cl-).

12.5 Other possible effects on the environment:

Generally, its effect is acutely considerable in the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

Do not allow it to enter soils or water channels.

DATA BASED on the components of the preparation.

(Hydrochloric acid)

Considerations regarding elimination

13.1 Substance or preparation:

In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country.

In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste.

2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2 Contaminated containers:

Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them.

European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.

.

Information concerning transport

Overland (ADR):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III (E)

By sea (IMDG):

Technical name: CORROSIVE LIQUID, N.O.S.

UN 1760 Class: 8 Packaging group: III

By air (ICAI-IATA):

Technical name: Corrosive liquid, n.o.s

UN 1760 Class: 8 Packaging group: III

Packaging instructions: CAO 820 PAX 818

Regulatory information

Other information

Other precautionary statements

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present and easy to do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.

Labelling (65/548/CEE or 1999/45/CE)

R-phrase(s):

R37 Irritating to respiratory system.

R34 Causes burns.

S-phrase(s):

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Review number and date: 3 3.11.10

Date published: 3.11.10

In respect of the previous review, changes have been made to the following sections: 2, 3, 15

The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.

S a f e t y D a t a S h e e t

в соответствии с Regulation (EC) 1907/2006

3424 Титан(III) Хлорид раствор 2% (масс.)

Определение вещества/preparation и the company или firm

1.1 Определение вещества или preparation

Название:

Титан(III) Хлорид раствор 2% (масс.)

1.2 Synonym:

1.3 Use вещества/preparation:

Для общелабораторного использования, анализов, исследований и тонкой химии.

1.4 Сведения о компании или фирме:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona) Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

Emergencies:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

Виды опасного воздействия

Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R37

R34

For the full text the R-выражения mentioned в this section, see section 16.

Сведения о компонентах и состав

Название: Титан(III) Хлорид раствор 2% (масс.)

Состав:

0001: Соляная Кислота 37%

Формула: HCl M.= 36,46 CAS [7647-01-0]

Номер ЕС (EINECS): 231-595-7

ЕС индекс: 017-002-01-X

Content: >= 5 % <= 10 %

Классификация Regulation (CE) nº 1272/2008.

Skin Corr. 1B, STOT SE 3

Skin Corr. 1B

STOT SE 3

Hazard Pictograms

Signal word

Danger

Hazard statements

H314 Causes severe skin ожоги и eye damage.

H335 May cause respiratory irritation.

Precautionary statements

P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash...thoroughly после обращение.

P271 Use only outdoors или в a well-ventilated area.

P280 Wear protective gloves/protective clothing/Защита глаз/face protection.

P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Классификация (67/548/CEE или 1999/45/CE).

C Коррозионное Вещество

R37 Irritating до respiratory system.

R34 Может вызвать ожоги.

Первая помощь

4.1 Общие указания:

Не давать пить и не вызывать рвоту при потере сознания.

4.2 Вдыхание:

Переместить пострадавшего на свежий воздух.

4.3 Контакт с кожей:

Промыть большим количеством воды. Избавиться от загрязненной одежды. При раздражении кожи, Обратиться за медицинской помощью.

4.4 Глаза:

Промыть большим количеством воды, Веки постоянно держать открытыми. Обратиться за медицинской помощью.

4.5 Попадание Внутрь:

Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.

Меры и средства обеспечения пожаро- и взрывобезопасности

5.1 Пригодные средства пожаротушения:

Не опасные для окружающей среды.

5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:

5.3 Особая опасность:

Incombustible. В случае возгорания могут образовываться токсичные пары.

5.4 Средства индивидуальной защиты:

Меры по предотвращению и ликвидации чрезвычайных ситуаций

6.1 Индивидуальные меры предосторожности:

Avoid Контакт с кожей, глаза или clothing.

6.2 Меры по защите окружающей среды:

Избегайте загрязнения почвы, систем водоснабжения и дренажа.

6.3 Методы нейтрализации и очистки:

Собирать с помощью абсорбирующего материала ( Panreac абсорбент общего назначения, Kieselguhr, etc), если абсорбент не доступен использовать сухой песок или землю и поместить в контейнеры для последующей утилизации в соответствии с законодательством.. Смыть остатки большим количеством воды.

Правила обращения и хранения

7.1 Обращение:

Специальные указания отсутствуют.

7.2 Хранение:

В запечатанных контейнерах.При температуре воздуха.

Требования по охране труда и меры по обеспечению безопасности персонала

8.1 Технические меры защиты:

8.2 Контроль предельно допустимого уровня воздействия:

VLA-ED(HCl): 7 мг/м3

VLA-ED(HCl): 5 ppm

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания.

8.4 Защита рук:

Использовать защитные перчатки

8.5 Защита глаз:

Использовать защитные очки.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки и лицо перед перерывами и после окончания работы.

8.7 Контроль воздействия на окружающую среду:

Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.

Физико-химические свойства

Внешний Вид: жидкость

Цвета: Violet

Granulometry:

Запах: Piquant.

pH:

точка плавления/Температура замерзания:

Initial Точка кипения и Интервал температур кипения:

Точка воспламенения:

Flammability (solid, gas):

Верхний/нижний flammability или explosive показатели:

Давление пара: 587 hPa (20 °C)

Vapour плотность:

Relative плотность: (20/4) 1,067

Растворимость: Смешивается с водой

Partition coefficient: n-октанол/вода:

Auto-ignition temperature:

Decomposition temperature:

Вязк.:

Стабильность и реакционноспособность

10.1 Условия, которых следует избегать:

Высокий temperatures.

10.2 Вещества, которых следует избегать:

Металлы. Щелочных solutions.

10.3 Опасные продукты разложения:

Водород хлорид. Хлор.

10.4 Общая информация:

Токсикологическая информация

  • Высокая токсичность:

  • Опасное воздействие на здоровье:

If fumes inhaled: Irritations до the respiratory tracts. Causes coughing затруднение дыхания Upon Контакт с кожей: irritations ожоги Контакт с глазами: irritations ожоги При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. No damage is anticipated до the foetus, provided the VLA values are respected (maximum admissible концентрация в the workplace). Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.

Информация по окружающей среде

12.1 Мобильность:

12.2 Экотоксичность:

12.1.1 - EC50 тест (mg/l):

Рыбы тест (HCl) 25 mg/l

Классификация: Токсично

Рыбы (Leuciscus Idus) (HCl) 862 mg/l (48h)(1N)

Классификация: Очень токсично

12.2.2 - Воздействие на окружающую среду:

Риск для водной среды

Средний

Риск для земли

Средний

12.2.3 - Наблюдения:

Has a major acute effect on the вода и land environment зависит от pH.

12.3 Период Распада:

12.3.1 - Тест:

12.3.2 - Классификация биотического периода распада:

BOD5/COD

Биоразложение

12.3.3 - Абиотический период распада зависит от рН:

12.3.4 - Наблюдения:

Нет данных.

12.4 Аккумуляция:

12.4.1 - Тест:

12.4.2 - Биоаккумуляция:

Риск = ----

12.4.3 - Наблюдения:

It is not bio-accumulable, although it is accumulable в воде courses и soils в saline form (Cl-).

12.5 Другие возможные воздействия на окружающую среду:

Generally, its effect is acutely considerable в the dumping area. Its long-term effect is not so considerable if the dumping is not frequent.

Избегать попаданию вещества в почву и воду.

DATA BASED on the components the preparation.

(Соляная кислота)

Правила утилизации

13.1 Вещество или препарат:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

.

13.2 Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

.

Информация относительно транспорта

Автотранспорт (ADR):

Техническое название: CORROSIVE LIQUID, N.O.S.

UN 1760 Класс: 8 Группа: III (E)

Морской транспорт (IMDG):

Техническое название: CORROSIVE LIQUID, N.O.S.

UN 1760 Класс: 8 Группа: III

Авиа транспорт (ICAI-IATA):

Техническое название: Коррозионное Вещество жидкость, n.o.s

UN 1760 Класс: 8 Группа: III

Инструкция по упаковке: CAO 820 PAX 818

Regulatory information

Дополнительная информация

Др. precautionary statements

P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с водой/shower.

P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P310 Immediately call a POISON CENTER или doctor/physician.

P312 Call a POISON CENTER или doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P338 Remove contact lenses, if present и easy до do. Continue rinsing.

P363 Wash contaminated clothing before reuse.

P403+P233 Store в a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

Labelling (65/548/CEE или 1999/45/CE)

R-phrase(s):

R37 Irritating до respiratory system.

R34 Может вызвать ожоги.

S-phrase(s):

S45 При ухудшении самочувствия обратиться за медицинской помощью (show the lable where possible).

S26 При контакте с глазами, немедленно промыть большим количеством воды и обратиться за медицинской помощью.

Номер рецензии и дата: 3 3.11.10

Date published: 3.11.10

Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15

Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.




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