S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
2328 Phenylhydrazinium Chloride
Identification of the substance/preparation and of the company or firm | ||||
1.1 Identification of the substance or preparation Name: Phenylhydrazinium Chloride | ||||
1.2 Synonym: Phenylhydrazinium Chlorhydrate | ||||
1.3 Use of the substance/preparation: | ||||
For laboratory utilisation, analysis, research and fine chemistry. | ||||
1.4 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com Emergencies: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Identification of dangers
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008.
Carc. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 STOT RE 1 Muta. 2 Aquatic Acute 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H372 Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H400 Very toxic to aquatic life.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE.
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Classification (67/548/CEE or 1999/45/CE).
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For the full text of the R-phrases mentioned in this section, see section 16. | ||||
Component Composition/Information | ||||
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Name: Phenylhydrazinium Chloride Formula: C6H5NHNH2.HCl M.= 144,61 CAS [59-88-1] EC number (EINECS): 200-444-7 | ||||
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First aid
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4.1 General indications: Never provide drink or induce vomiting in the event of loss of consciousness.
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4.2 Inhaling: Take the person out into the fresh air. In the event sickness persists, seek medical assistance.
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4.3 Contact with the skin: Wash with plenty of water. Remove contaminated clothing.
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4.4 Eyes: Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek medical assistance.
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4.5 Swallowing: Drink large amounts of water. Induce vomiting. Seek medical assistance.
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Fire-fighting means
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5.1 Suitable fire-extinguishing means: Dry powder. Water. Foam.
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5.2 Fire-fighting means which must NOT be used:
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5.3 Special risks: Flammable. Keep away from sources of ignition. In the event of fire, toxic fumes may form: NOx,HCl,Cl2.
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5.4 Protective equipment:
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Measures to be taken in the event of accidental spillage
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6.1 Individual precautions: Avoid contact with the skin, eyes or clothing.
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6.2 Precautions for care of the environment: Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.
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6.3 Methods for collection/cleaning: Collect up dry and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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Handling and storage
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7.1 Handling:
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7.2 Storage: Well sealed containers.Dry atmosphere.Atmospheric temperature.Away from light.
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Staff exposure/protection controls
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8.1 Technical protective measures:
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8.2 Exposure limit control:
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8.3 Respiratory protection: In the event of fumes forming/aerosols, use suitable respiratory protection.
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8.4 Hand protection: Use suitable gloves
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8.5 Eye protection: Use suitable goggles.
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8.6 Individual hygiene measures: Remove contaminated clothing. Use suitable work clothing. Wash hands before breaks and when the job is done. Avoid the formation of dust.
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8.7 Environmental exposure controls: Fulfill the commitments under local environmental protection legislation. | ||||
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Physical and chemical properties
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Appearance: solid | ||||
Colour: | ||||
Granulometry: | ||||
Odour: Characteristic. | ||||
pH: 2,6 - 2,9 (5% solution) | ||||
Melting point/freezing point: 243 - 246 °C | ||||
Initial boiling point and boiling range: | ||||
Flash point: | ||||
Flammability (solid, gas): | ||||
Upper/lower flammability or explosive limits: | ||||
Vapour pressure: | ||||
Vapour density: | ||||
Relative density: | ||||
Solubility: 50 g/l water 20 °C | ||||
Partition coefficient: n-octanol/water: | ||||
Auto-ignition temperature: | ||||
Decomposition temperature: above245 °C | ||||
Viscosity: | ||||
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Stability and reactivity
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10.1 Conditions which should be avoided:
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10.2 Matter which should be avoided: Strong oxidant agents. Metal oxides. Air Halogenated hydrocarbons. Alkaline hydroxides. Surfactants.
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10.3 Hazardous decomposition products: Hydrogen.
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10.4 Complementary information: Light-sensitive.
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Toxicological information
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LD L0 oral rbt : 25 mg/kg LD50 oral mus : 2.100 mg/kg LD L0 skn rbt : 500 mg/kg LD50 ipr rat : 161 mg/kg
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Through contact with the eyes: irritations Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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Environmental information
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12.1 Mobility:
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12.2 Ecotoxicity: 12.1.1 - EC50 test (mg/l): 12.2.2 - Receptor medium: Risk for the water environment Risk for the land environment 12.2.3 - Observations: Ecotoxic data not available.
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12.3 Degradability: 12.3.1 - Test: 12.3.2 - Biotic degradation classification: BOD5/COD Biodegradability 12.3.3 - Abiotic degradation depending on pH: 12.3.4 - Observations: Data not available.
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12.4 Accumulation: 12.4.1 - Test: 12.4.2 - Bioaccumulation: Risk 12.4.3 - Observations: Data not available.
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12.5 Other possible effects on the environment: Do not allow it to enter soils or water channels. High toxic product for water.
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Considerations regarding elimination
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13.1 Substance or preparation: In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste. .
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13.2 Contaminated containers: Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. .
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Information concerning transport
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Overland (ADR): Technical name: TOXIC SOLID, ORGANIC, N.O.S. UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: II (D/E) | ||||
By sea (IMDG): Technical name: TOXIC SOLID, ORGANIC, N.O.S. UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: II | ||||
By air (ICAI-IATA): Technical name: Toxic solid, organic, n.o.s. UN 2811 Class: 6.1 CONTAM. MAR PELIG.M.AMB Packaging group: II | ||||
Packaging instructions: CAO 615 PAX 613
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Regulatory information
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Other information
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Other precautionary statements P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P311 Call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Labelling (65/548/CEE or 1999/45/CE) | ||||
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Review number and date: 3 3.11.10 Date published: 3.11.10 In respect of the previous review, changes have been made to the following sections: 2, 3, 15 The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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S a f e t y D a t a S h e e t |
в соответствии с Regulation (EC) 1907/2006 |
2328 Фенилгидразина хлористый
Определение вещества/preparation и the company или firm | ||||
1.1 Определение вещества или preparation Название: Фенилгидразина хлористый | ||||
1.2 Synonym: Phenylhydrazinium Chlorhydrate | ||||
1.3 Use вещества/preparation: | ||||
Для общелабораторного использования, анализов, исследований и тонкой химии. | ||||
1.4 Сведения о компании или фирме: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com Emergencies: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499
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Виды опасного воздействия
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Классификация вещества или the mixture.
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Классификация Regulation (CE) nº 1272/2008.
Carc. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 STOT RE 1 Muta. 2 Aquatic Acute 1
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Hazard Pictograms
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Signal word Danger
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Hazard statements H350 May cause cancer <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H331 Токсично if inhaled. H311 Токсично в contact с skin. H301 Токсично При попадании внутрь. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H400 Очень токсично до aquatic life.
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P260 Не вдыхать пыль/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация (67/548/CEE или 1999/45/CE).
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For the full text the R-выражения mentioned в this section, see section 16. | ||||
Сведения о компонентах и состав | ||||
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Название: Фенилгидразина хлористый Формула: C6H5NHNH2.HCl M.= 144,61 CAS [59-88-1] Номер ЕС (EINECS): 200-444-7 | ||||
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Первая помощь
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4.1 Общие указания: Не давать пить и не вызывать рвоту при потере сознания.
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух. При ухудшении самочувствия, Обратиться за медицинской помощью.
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4.3 Контакт с кожей: Промыть большим количеством воды. Избавиться от загрязненной одежды.
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4.4 Глаза: Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью.
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Меры и средства обеспечения пожаро- и взрывобезопасности
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5.1 Пригодные средства пожаротушения: Песок. Вода. Пена.
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5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:
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5.3 Особая опасность: Воспламеняем. Держать на расстоянии от источников возгорания. В случае возгорания могут образовываться токсичные пары: NOx,HCl,Cl2.
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5.4 Средства индивидуальной защиты:
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Меры по предотвращению и ликвидации чрезвычайных ситуаций
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6.1 Индивидуальные меры предосторожности: Avoid Контакт с кожей, глаза или clothing.
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6.2 Меры по защите окружающей среды: Не допускайте попадания в канализацию.. Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Методы нейтрализации и очистки: Собирать в сухом виде, поместить в контейнеры для последующей утилизации в соответствии с законодательством. Смыть остатки большим количеством воды.
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Правила обращения и хранения
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7.1 Обращение:
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7.2 Хранение: В запечатанных контейнерах.Сухая атмосфера.При температуре воздуха.Away from light.
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Требования по охране труда и меры по обеспечению безопасности персонала
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8.1 Технические меры защиты:
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8.2 Контроль предельно допустимого уровня воздействия:
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания.
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8.4 Защита рук: Использовать защитные перчатки
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8.5 Защита глаз: Использовать защитные очки.
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Использовать специальную одежду. Мыть руки перед перерывами в работе и после окончания работы. Avoid the formation dust.
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8.7 Контроль воздействия на окружающую среду: Выполнять предписания по охране окружающей среды в соответствии с местным законодательством. | ||||
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Физико-химические свойства
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Внешний Вид: solid | ||||
Цвета: | ||||
Granulometry: | ||||
Запах: Характерный. | ||||
pH: 2,6 - 2,9 (5% раствор) | ||||
точка плавления/Температура замерзания: 243 - 246 °C | ||||
Initial Точка кипения и Интервал температур кипения: | ||||
Точка воспламенения: | ||||
Flammability (solid, gas): | ||||
Верхний/нижний flammability или explosive показатели: | ||||
Давление пара: | ||||
Vapour плотность: | ||||
Relative плотность: | ||||
Растворимость: 50 г/л вода 20 °C | ||||
Partition coefficient: n-октанол/вода: | ||||
Auto-ignition temperature: | ||||
Decomposition temperature: above245 °C | ||||
Вязк.: | ||||
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Стабильность и реакционноспособность
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10.1 Условия, которых следует избегать:
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10.2 Вещества, которых следует избегать: Strong Окислители. Металл oxides. Air Halogenated углеводороды. Щелочных hydroxides. Surfactants.
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10.3 Опасные продукты разложения: Водород.
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10.4 Общая информация: Light-sensitive.
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Токсикологическая информация
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LD L0 oral rbt : 25 мг/кг LD50 oral mus : 2.100 мг/кг LD L0 skn rbt : 500 мг/кг LD50 ipr rat : 161 мг/кг
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Контакт с глазами: irritations Другие опасные характеристики данного вещества не обнаружены. Применять обычные меры предосторожности при работе с химическими веществами.
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Информация по окружающей среде
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12.1 Мобильность:
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12.2 Экотоксичность: 12.1.1 - EC50 тест (mg/l): 12.2.2 - Воздействие на окружающую среду: Риск для водной среды Риск для земли 12.2.3 - Наблюдения: Ecotoxic Нет данных.
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12.3 Период Распада: 12.3.1 - Тест: 12.3.2 - Классификация биотического периода распада: BOD5/COD Биоразложение 12.3.3 - Абиотический период распада зависит от рН: 12.3.4 - Наблюдения: Нет данных.
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12.4 Аккумуляция: 12.4.1 - Тест: 12.4.2 - Биоаккумуляция: Риск 12.4.3 - Наблюдения: Нет данных.
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12.5 Другие возможные воздействия на окружающую среду: Избегать попаданию вещества в почву и воду. Высокий токсично product for вода.
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Правила утилизации
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13.1 Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.
.
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13.2 Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. .
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Информация относительно транспорта
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Автотранспорт (ADR): Техническое название: TOXIC SOLID, ORGANIC, N.O.S. UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: II (D/E) | ||||
Морской транспорт (IMDG): Техническое название: TOXIC SOLID, ORGANIC, N.O.S. UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: II | ||||
Авиа транспорт (ICAI-IATA): Техническое название: Токсично solid, органический, n.o.s. UN 2811 Класс: 6.1 CONTAM. MAR PELIG.M.AMB Группа: II | ||||
Инструкция по упаковке: CAO 615 PAX 613
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Regulatory information
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Дополнительная информация
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Др. precautionary statements P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P272 Contaminated work clothing should not be allowed out the workplace. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal Средства индивидуальной защиты как required. P301+P310 При попадании внутрь: Immediately call a POISON CENTER или doctor/physician. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P308+P313 IF exposed или concerned: Get medical advice/attention. P311 Call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P362 Take off contaminated clothing и wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up.
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Labelling (65/548/CEE или 1999/45/CE) | ||||
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Номер рецензии и дата: 3 3.11.10 Date published: 3.11.10 Относительно предыдущего обзора изменения были произведены в следующих разделах: 2, 3, 15 Информация, включенная в этот сертификат безопасности, базируется на современных данных и соответствует аспектам безопасности.
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