1. Identification of the substance/preparation and of the company or firm1.1 | Identification of the substance or preparation | | Name: Allyl Alcohol
| 1.2 | Use of the substance/preparation: | | For laboratory utilisation, analysis, research and fine chemistry.
| 1.3 | Identification of the company or firm: | | PANREAC QUIMICA, S.L.U. C/Garraf, 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com Emergencies: Single telephone number for emergency calls: 112 (EU) Tel.:(+34) Tel.:(+34) 937 489 499
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2. Identification of dangers | | | Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms.
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3. Component Composition/Information | | | Name: Allyl Alcohol Formula: C3H6O M.=58,08 CAS [107-18-6] EC number (EINECS): 203-470-7 EC index number: 603-015-00-6
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4. First aid4.1 | General indications: | | Never provide drink or induce vomiting in the event of loss of consciousness.
| 4.2 | Inhaling: | | Take the person out into the fresh air. In the event of suffocation, proceed to provide artificial respiration.
| 4.3 | Contact with the skin: | | Wash with plenty of water. Remove contaminated clothing.
| 4.4 | Eyes: | | Wash with plenty of water (for at least 15 minutes), keeping eyelids open.
| 4.5 | Swallowing: | | Administer Vaseline oil as a laxative (3 ml/kg). Avoid vomiting. Risk of aspiration. Seek immediate medical assistance.
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5. Fire-fighting means5.1 | Suitable fire-extinguishing means: | | Water. Carbon dioxide (CO2). Dry powder. Foam.
| 5.2 | Fire-fighting means which must NOT be used: | | -----
| 5.3 | Special risks: | | Combustible. May form explosive mixtures with the air. The fumes are heavier than air, so they may spread at floor level.
| 5.4 | Protective equipment: | | -----
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6. Measures to be taken in the event of accidental spillage6.1 | Individual precautions: | | Do not inhale the fumes. Ensure adequate ventilation.
| 6.2 | Precautions for care of the environment: | | Do not allow it to enter the drainage system. Avoid pollution of the soil, water supplies and drains.
| 6.3 | Methods for collection/cleaning: | | Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.) or, if none available, dry sand or earth, and deposit in waste containers for subsequent elimination in accordance with current legislation. Clean any remains with plenty of water.
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7. Handling and storage7.1 | Handling: | | No special indications.
| 7.2 | Storage: | | Well sealed containers. In well ventilated premises. In a cool place.
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8. Staff exposure/protection controls8.1 | Technical protective measures: | | Ensure good ventilation and renewal of the air in the premises.
| 8.2 | Exposure limit control: | | PEL-TWA: 5 mg/m3 (OSHA) STEL: 2 ppm or 4,8 mg/m3 (ACGIH) VLA-ED: 2 ppm or 5 mg/m3 VLA-EC: 5 ppm or 12 mg/m3
| 8.3 | Respiratory protection: | | In the event of fumes forming/aerosols, use suitable respiratory protection.
| 8.4 | Hand protection: | | Use suitable gloves
| 8.5 | Eye protection: | | Use suitable goggles.
| 8.6 | Individual hygiene measures: | | Remove contaminated clothing. Use suitable work clothing. Wash hands and face before breaks and when the job is done. Do not eat, drink or smoke in the workplace.
| 8.7 | Environmental exposure controls: | | Fulfill the commitments under local environmental protection legislation.
| | | | The supplier of the protection equipment must specify the type of protection to be worn when handling the substance or preparation, including the type of material and the breakthrough time of the material, with regard to the amount and duration of exposure.
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9. Physical and chemical properties | Appearance: | | Transparent, colourless liquid.
| | Odour: | | Characteristic.
| | | | Boiling point:97°C Melting point: -50°C Flash point: 21°C Self-ignition temperature: 375°C Explosion limits (lower/upper): 2,5 / 18 Vol. % Vapour pressure: 24 hPa (20°C) Density (20/4): 0,852 Solubility: Miscible with water
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10. Stability and reactivity10.1 | Conditions which should be avoided: | | High temperatures.
| 10.2 | Matter which should be avoided: | | Oxidant agents.
| 10.3 | Hazardous decomposition products: | | -----
| 10.4 | Complementary information: | | -----
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11. Toxicological information11.1 | Acute toxicity: | | LD50 oral rat: 64 mg/kg LD50 dermal rabbit: 45 mg/kg LD50 oral rabbit: 71 mg/kg LC50 inh rat: 76 ppm/8H
| 11.2 | Dangerous effects for health: | | If fumes inhaled: Irritations to the respiratory tracts. Can cause coughing, breathing difficulties. Upon contact with the skin: irritations. Risk of cutaneous absorption. Through contact with the eyes: Irritations to the mucosae, sight disorders. Can cause burns. Risk of blindness (irreversible injury of the optic nerve). Can cause narcosis, hepatic problems, kidney problems. Other dangerous characteristics are not discarded. Take the usual precautions for handling chemical products.
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12. Environmental information12.1 | Mobility: | | -----
| 12.2 | Ecotoxicity: | | 12.1.1 - EC50 test (mg/l): ----- 12.2.2 - Receptor medium: Risk for the water environment = ---- Risk for the land environment = ---- 12.2.3 - Observations: Ecotoxic data not available.
| 12.3 | Degradability: | | 12.3.1 - Test:------- 12.3.2 - Biotic degradation classification: BOD5/COD Biodegradability = ----- 12.3.3 - Abiotic degradation depending on pH: ------- 12.3.4 - Observations: -----
| 12.4 | Accumulation: | | 12.4.1 - Test: ------- 12.4.2 - Bioaccumulation: Risk = ----- 12.4.3 - Observations: -----
| 12.5 | Other possible effects on the environment: | | Do not allow it to enter soils or water channels.
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13. Considerations regarding elimination13.1 | Substance or preparation: | | In the European Union, there are no homogeneous standards established for elimination of chemical waste, which is waste of a special nature, and treatment and elimination of same is subject to the domestic legislation in each country. In view of this, in each case, you should contact the competent authority or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision 2000/532/EC as regards the list of wastes. Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.
| 13.2 | Contaminated containers: | | Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste.
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14. Information concerning transport | | | Overland (ADR): Technical name: ALCOHOL ALÍLICO ONU 1098 Class: 6.1 (C/D) By sea (IMDG): Technical name: ALCOHOL ALÍLICO ONU 1098 Class: 6.1 Packaging group: I By air (ICAI-IATA): Technical name: Alcohol alílico ONU 1098 Class: 6.1 Packaging instructions: CAO P PAX P
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15. Mandatory information15.1 | Labelling as per REACH | | Symbols: Danger indications: Toxic Dangerous for the environment Phrases R: 10-23/24/25-36/37/38-50 Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms. Phrases S: 36/37/39-38-45-61 Wear suitable protective clothing, gloves and eye-face protection. In case of insuficient ventilation, wear suitable, respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions-safety data sheet. EC index number: 603-015-00-6
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16. Other information | | | Review number and date:2 07.06.09 In respect of the previous review, changes have been made to the following sections: 8. The information included in this Safety Data Sheet is based on our most up-to-date knowledge, and is solely intended to inform regarding aspects of safety; the properties and characteristics indicated herein are not guaranteed.
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