S a f e t y D a t a S h e e t
According to Regulation (EC) 1907/2006
3314
Sodium Borohydride
1.
Identification of the substance/preparation and of the
company or firm
1.1 Identification of the substance or preparation
Name:
Sodium Borohydride
Synonym:
Sodium Tetrahydroborane
REACH Registration Number: A registration number is not available for this
substance as the substance or its use are exempted from registration according to
Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not
requiere a registration, the registration is envisaged for a later registration
deadline or it is a mixture.
1.2 Use of the substance/preparation:
For laboratory utilisation, analysis, research and fine chemistry.
1.3 Identification of the company or firm:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail:
1.4 Emergency telephone:
Single telephone number for emergency calls: 112 (EU)
Tel.: (+34) 937 489 499
2.
Identification of dangers
Classification of the substance or the mixture.
Classification Regulation (CE) nº 1272/2008.
Water-react. 2
Acute Tox. 3
Skin Corr. 1B
Hazard Pictograms
Signal word
Danger
Hazard statements
H261 In contact with water releases flammable gases.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statements
P223 Keep away from any possible contact with water, because of violent reaction
and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly after handling.
P270 Do no eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Classification (67/548/CEE or 1999/45/CE).
T Toxic
F Highly flammable
R34
R25
R15
For the full text of the R-phrases mentioned in this section, see section 16.
3.
Component Composition/Information
Name: Sodium Borohydride
Formula: NaH4B M.= 37,83 CAS [16940-66-2]
EC number (EINECS): 241-004-4
4.
First aid
4.1 General indications:
Never provide drink or induce vomiting in the event of loss of consciousness.
4.2 Inhaling:
Take the person out into the fresh air. In the event of suffocation, proceed
immediately to provide artificial respiration. Seek immediate medical assistance.
4.3 Contact with the skin:
Take the product out with cotton wool soaked in polyethylene-glycol 400. Wash
with plenty of water. Remove contaminated clothing.
4.4 Eyes:
Seek immediate medical assistance. Wash with plenty of water, keeping eyelids
open.
4.5 Swallowing:
Drink large amounts of water. Avoid vomiting (there is a risk of perforation). Seek
immediate medical assistance. Do not neutralize.
5.
Fire-fighting means
5.1 Suitable fire-extinguishing means:
Smother with dry earth or sand.
5.2 Fire-fighting means which must NOT be used:
Water. Carbon dioxide (CO2). Foam.
5.3 Special risks:
Combustible. Keep away from sources of ignition. In the event of fire, toxic fumes
may form. Risk of explosion of dust.
5.4 Protective equipment:
Suitable clothing and footwear.
6.
Measures to be taken in the event of accidental spillage
6.1 Individual precautions:
Do not inhale the dust.
6.2 Precautions for care of the environment:
Do not allow it to enter the drainage system. Avoid pollution of the soil, water
supplies and drains.
6.3 Methods for collection/cleaning:
Carry out the operation with maximum precaution. Collect up dry and deposit in
waste containers for subsequent elimination in accordance with current legislation.
Clean any remains with plenty of water.
7.
Handling and storage
7.1 Handling:
No special indications.
7.2 Storage:
Well sealed containers.Dry atmosphere.In well ventilated premises.Room
temperature.Restricted access, only authorized to technicians.Away from sources
of ignition and heat.
8.
Staff exposure/protection controls
8.1 Technical protective measures:
No special indications.
8.2 Exposure limit control:
: Data not available.
8.3 Respiratory protection:
If dust forms, use suitable respiratory protection.
8.4 Hand protection:
Use suitable gloves
8.5 Eye protection:
Use suitable goggles.
8.6 Individual hygiene measures:
Remove contaminated clothing. Use suitable work clothing. Avoid the formation of
dust. Wash hands and face before breaks and when the job is done.
8.7 Environmental exposure controls:
Fulfill the commitments under local environmental protection legislation.
9.
Physical and chemical properties
Appearance: solid
Colour: White
Granulometry: N/A
Odour: Odourless.
pH:
N/A
Melting point/freezing point: 36 °C
Initial boiling point and boiling range: ~500 °C
Flash point:
N/A
Flammability (solid, gas):
N/A
Upper/lower flammability or explosive limits:
N/A
Vapour pressure: N/A
Vapour density: N/A
Relative density:
N/A
Solubility: 550 g/l in water25 °C
Partition coefficient: n-octanol/water:
N/A
Auto-ignition temperature:
N/A
Decomposition temperature: above300 °C
Viscosity: N/A
10.
Stability and reactivity
10.1 Conditions which should be avoided:
High temperatures.
10.2 Matter which should be avoided:
Water. Acids. Alkaline hydroxides. Oxidant agents.
10.3 Hazardous decomposition products:
Hydrogen.
10.4 Complementary information:
Hygroscopic.
11.
Toxicological information
11.1 Acute toxicity:
LD L0 oral rat : 160 mg/kg
LD50
ipr rat : 18 mg/kg
11.2 Dangerous effects for health:
The product breaks down with the moisture of the tissues. Upon contact with the
skin: burns Through contact with the eyes: burns Risk of blindness (irreversible
injury of the optic nerve) Risk of sight disorders If swallowed: burns Other
dangerous characteristics are not discarded. Take the usual precautions for
handling chemical products.
12.
Environmental information
12.1
Toxicity:
12.1.1 - EC50 test (mg/l):
Fish (G.Affinis)(B) 5600 mg/l
Classification: Very toxic
Plants (B) 1 mg/l
Classification: Extr. toxic
12.1.2. - Receptor medium:
Risk for the water environment
Medium
Risk for the land environment
Medium
12.1.3. - Observations:
Acute ecotoxicity in the dumping area.
12.2
Persistence and Degradability :
12.2.1 - Test:
12.2.2. - Biotic degradation classification:
BOD5/COD
Biodegradability
12.2.3. - Abiotic degradation depending on pH:
12.2.4. - Observations:
12.3
Bioaccumulative potential:
12.3.1. - Test:
12.3.2. - Bioaccumulation:
Risk
12.3.3. - Observations:
12.4
Mobility in soil :
Data not available.
12.5 Assessment PBT and MPMB :
Data not available.
12.6
Other possible effects on the environment:
Water-pollutant product.
Reacts with water.
13.
Considerations regarding elimination
13.1
Substance or preparation:
In the European Union, there are no homogeneous standards established for
elimination of chemical waste, which is waste of a special nature, and treatment
and elimination of same is subject to the domestic legislation in each country.
In view of this, in each case, you should contact the competent authority or those
companies legally authorized for elimination of waste.
2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision
2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18
March 1991 amending Directive 75/442/EEC on waste.
.
13.2
Contaminated containers:
Contaminated containers and packaging of dangerous substances or preparations
must be treated in the same manner as the actual products contained in them.
European Parliament and Council Directive 94/62/EC of 20 December 1994 on
packaging and packaging waste.
.
14.
Information concerning transport
Overland (ADR):
Technical name: SODIUM BOROHYDRIDE
UN 1426 Class: 4.3 Packaging group: I (E)
By sea (IMDG):
Technical name: SODIUM BOROHYDRIDE
UN 1426 Class: 4.3 Packaging group: I
By air (ICAI-IATA):
Technical name: Sodium borohydride
UN 1426 Class: 4.3 Packaging group: I
Packaging instructions: CAO 487 PAX F
15.
Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
16.
Other information
Other precautionary statements
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see on this label).
P330 Rinse mouth.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P405 Store locked up.
P501 Dispose of contents/container according to Directive 94/62/CE or
2008/98/CE.
Labelling (65/548/CEE or 1999/45/CE)
R-phrase(s):
R34 Causes burns.
R25 Toxic if swallowed.
R15 Contact with water liberates extremely
flammable gases.
S-phrase(s):
S43f In case of fire, use sand. Never use water.
S36/37/39 Wear suitable protective clothing,
gloves and eye/face protection.
S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S14b Keep away from oxidizing substances and
acids, compounds of heavy metals.
S45 In case of accident or if you feel unwell,
seek medical advice immediately (show the lable
where possible).
The information included in this Safety Data Sheet is based on our most up-to-date
knowledge, and is solely intended to inform regarding aspects of safety; the
properties and characteristics indicated herein are not guaranteed.
In respect of the previous review, changes have been made to the following
sections: 2, 3, 15
Date published: 3.11.10
Review number and date: 3 3.11.10
S a f e t y D a t a S h e e t
в соответствии с Regulation (EC) 1907/2006
3314
Натрия борогидрид
1.
Identification вещества/preparation и the
company или firm
1.1 Определение вещества или preparation
Название:
Натрия борогидрид
Synonym:
Натрия Тетрагидроборан
REACH Registration Number: A registration number is not available for this
соединен. как the соединен. или its use are exempted from registration в соответствии с
Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not
requiere a registration, the registration is envisaged for a later registration
deadline или it is a mixture.
1.2 Use вещества/preparation:
Для общелабораторного использования, анализов, исследований и тонкой химии.
1.3 Сведения о компании или фирме:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail:
1.4 Emergency telephone:
Single telephone number for emergency calls: 112 (EU)
Tel.: (+34) 937 489 499
2.
Identification dangers
Классификация вещества или the mixture.
Классификация Regulation (CE) nº 1272/2008.
Вода-react. 2
Acute Tox. 3
Skin Corr. 1B
Hazard Pictograms
Signal word
Danger
Hazard statements
H261 В contact с водой releases воспламеняем gases.
H301 Токсично При попадании внутрь.
H314 Causes severe skin ожоги и eye damage.
Precautionary statements
P223 Keep away from any possible contact с водой, because violent reaction
и possible flash fire.
P231+P232 Handle under inert gas. Защищать от влаги
P260 Не вдыхать пыль/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly после обращение.
P270 Do no eat, drink или smoke when using this product.
P280 Wear protective gloves/protective clothing/Защита глаз/face protection.
Классификация (67/548/CEE или 1999/45/CE).
T Токсично
F Легко воспламеняем
R34
R25
R15
For the full text the R-выражения mentioned в this section, see section 16.
3.
Сведения о компонентах и состав
Название: Натрия борогидрид
Формула: NaH4B M.= 37,83 CAS [16940-66-2]
Номер ЕС (EINECS): 241-004-4
4.
Первая помощь
4.1 Общие указания:
Не давать пить и не вызывать рвоту при потере сознания.
4.2 Вдыхание:
Переместить пострадавшего на свежий воздух. В the event suffocation, proceed
immediately до provide artificial respiration. Обратиться немедленно за медицинской помощью.
4.3 Контакт с кожей:
Соберите продукт ваткой, смоченной в полиэтилен-гликоле 400. Wash
с plenty вода. Избавиться от загрязненной одежды.
4.4 Глаза:
Обратиться немедленно за медицинской помощью. Промыть большим количеством воды, keeping eyelids
open.
4.5 Попадание Внутрь:
Выпить большое количество воды. Avoid рвота (there is a риск perforation). Seek
immediate medical assistance. Do not neutralize.
5.
Fire-fighting means
5.1 Пригодные средства пожаротушения:
Smother с безводн. earth или sand.
5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:
Вода. Углекислый газ (CO2). Пена.
5.3 Особая опасность:
Горючее Вещество. Держать на расстоянии от источников возгорания. В the event fire, токсично fumes
may form. Риск explosion dust.
5.4 Средства индивидуальной защиты:
Специальная одежда и обувь.
6.
Меры по предотвращению и ликвидации чрезвычайных ситуаций
6.1 Индивидуальные меры предосторожности:
Не вдыхать пыль.
6.2 Меры по защите окружающей среды:
Не допускайте попадания в канализацию.. Avoid pollution the soil, вода
supplies и drains.
6.3 Методы нейтрализации и очистки:
Carry out the operation с maximum precaution. Collect up безводн. и deposit в
waste containers for subsequent elimination в соответствии с законодательством.
Смыть остатки большим количеством воды.
7.
Правила обращения и хранения
7.1 Обращение:
Специальные указания отсутствуют.
7.2 Хранение:
В запечатанных контейнерах.Сухая атмосфера.В хорошо проветриваемом помещении.Room
temperature.Ограничить право доступа к веществу, предоставив его только специалистам.Away from sources
ignition и heat.
8.
Staff exposure/protection controls
8.1 Технические меры защиты:
Специальные указания отсутствуют.
8.2 Контроль предельно допустимого уровня воздействия:
: Нет данных.
8.3 Защита органов дыхания:
If dust forms, use suitable Защита органов дыхания.
8.4 Защита рук:
Использовать защитные перчатки
8.5 Защита глаз:
Использовать защитные очки.
8.6 Индивидуальные средства гигиены:
Избавиться от загрязненной одежды. Использовать специальную одежду. Avoid the formation
dust. Мыть руки и лицо перед перерывами и после окончания работы.
8.7 Контроль воздействия на окружающую среду:
Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.
9.
Физико-химические свойства
Внешний Вид: solid
Цвета: Белый
Granulometry: N/A
Запах: Без Запаха.
pH:
N/A
точка плавления/Температура замерзания: 36 °C
Initial Точка кипения и Интервал температур кипения: ~500 °C
Точка воспламенения:
N/A
Flammability (solid, gas):
N/A
Верхний/нижний flammability или explosive показатели:
N/A
Давление пара: N/A
Vapour плотность: N/A
Relative плотность:
N/A
Растворимость: 550 г/л в water25 °C
Partition coefficient: н-октанол/вода:
N/A
Auto-ignition temperature:
N/A
Decomposition temperature: above300 °C
Вязк.: N/A
10.
Стабильность и реакционноспособность
10.1 Условия, которых следует избегать:
Высокий temperatures.
10.2 Вещества, которых следует избегать:
Вода. Кислоты. Щелочных hydroxides. Окислители.
10.3 Опасные продукты разложения:
Водород.
10.4 Общая информация:
Гигроскопичный.
11.
Токсикологическая информация
11.1 Высокая токсичность:
LD L0 oral rat : 160 мг/кг
LD50
ipr rat : 18 мг/кг
11.2 Опасное воздействие на здоровье:
The product breaks down с the moisture the tissues. Upon contact с the
skin: ожоги Контакт с глазами: ожоги Риск blindness (irreversible
injury the optic nerve) Риск sight disorders При попадании внутрь: ожоги Др.
dangerous characteristics are not discarded. Take the usual precautions for
обращение chemical products.
12.
Информация по окружающей среде
12.1
Toxicity:
12.1.1 - EC50 тест (mg/l):
Рыбы (G.Affinis)(B) 5600 mg/l
Классификация: Очень токсично
Plants (B) 1 mg/l
Классификация: Extr. токсично
12.1.2. - Воздействие на окружающую среду:
Риск для водной среды
Средний
Риск для земли
Средний
12.1.3. - Наблюдения:
Acute экотоксичность в the dumping area.
12.2
Persistence и Период Распада :
12.2.1 - Тест:
12.2.2. - Классификация биотического периода распада:
BOD5/COD
Биоразложение
12.2.3. - Абиотический период распада зависит от рН:
12.2.4. - Наблюдения:
12.3
Bioaccumulative potential:
12.3.1. - Тест:
12.3.2. - Биоаккумуляция:
Риск
12.3.3. - Наблюдения:
12.4
Мобильность в soil :
Нет данных.
12.5 Assessment PBT и MPMB :
Нет данных.
12.6
Другие возможные воздействия на окружающую среду:
Вода-Продукт загрязнения.
Reacts с водой.
13.
Правила утилизации
13.1
Вещество или препарат:
В the Европейск. Union, there are no homogeneous standards established for
elimination chemical waste, which is waste a special nature, и treatment
и elimination same is subject до the domestic legislation в each country.
В view this, в each case, you should contact the competent authority или those
companies legally authorized for elimination waste.
2001/573/EC: Council Decision 23 July 2001 amending Commission Decision
2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18
March 1991 amending Directive 75/442/EEC on waste.
.
13.2
Загрязненные контейнеры:
Загрязненные контейнеры и packaging dangerous соединения или preparations
must be treated в the same manner как the actual products contained в them.
Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on
packaging и packaging waste.
.
14.
Информация относительно транспорта
Автотранспорт (ADR):
Техническое название: Натрия борогидрид
UN 1426 Класс: 4.3 Группа: I (E)
Морской транспорт (IMDG):
Техническое название: Натрия борогидрид
UN 1426 Класс: 4.3 Группа: I
Авиа транспорт (ICAI-IATA):
Техническое название: Натрия борогидрид
UN 1426 Класс: 4.3 Группа: I
Инструкция по упаковке: CAO 487 PAX F
15.
Regulatory information
This safety datasheet complies с the requirements Regulation (EC) No.
1907/2006.
16.
Дополнительная информация
Др. precautionary statements
P301+P310 При попадании внутрь: Immediately call a POISON CENTER или
doctor/physician.
P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту.
P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all
contaminated clothing. Rinse skin с водой/shower.
P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes.
Remove contact lenses, if present и easy до do. Continue rinsing.
P310 Immediately call a POISON CENTER или doctor/physician.
P321 Specific treatment (see on this label).
P330 Rinse mouth.
P338 Remove contact lenses, if present и easy до do. Continue rinsing.
P363 Wash contaminated clothing before reuse.
P370+P378 В case fire: Use for extinction.
P402+P404 Store в a безводн. place. Store в a closed container.
P405 Store locked up.
P501 Выбросить contents/container в соответствии с Directive 94/62/CE или
2008/98/CE.
Labelling (65/548/CEE или 1999/45/CE)
R-phrase(s):
R34 Может вызвать ожоги.
R25 Токсично При попадании внутрь.
R15 Contact с водой liberates extremely
воспламеняем gases.
S-phrase(s):
S43f В case fire, use sand. Never use вода.
S36/37/39 Wear suitable protective clothing,
gloves и eye/face protection.
S26 В case contact с глаза, rinse
immediately с plenty вода и seek
medical advice.
S14b Keep away from Окислители и
кислоты, соединен. Тяжелые металлы.
S45 В case accident или if you feel unwell,
seek medical advice immediately (show the lable
where possible).
The information included в this Safety Data Sheet is based on our most up-до-date
knowledge, и is solely intended до inform regarding aspects safety; the
properties и characteristics indicated herein are not guaranteed.
В respect the previous review, changes have been made до the following
sections: 2, 3, 15
Date published: 3.11.10
Номер рецензии и дата: 3 3.11.10