S a f e t y D a t a S h e e t
According to Regulation (EC) 1907/2006
1457
Pyridine
1.
Identification of the substance/preparation and of the
company or firm
1.1 Identification of the substance or preparation
Name:
Pyridine
Synonym:
REACH Registration Number: 01-2119493105-40-XXXX
1.2 Use of the substance/preparation:
For laboratory utilisation, analysis, research and fine chemistry.
1.3 Identification of the company or firm:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail:
1.4 Emergency telephone:
Single telephone number for emergency calls: 112 (EU)
Tel.: (+34) 937 489 499
2.
Identification of dangers
Classification of the substance or the mixture.
Classification Regulation (CE) nº 1272/2008.
Flam. Liq. 2
Acute Tox. 4
Acute Tox. 4
Acute Tox. 4
Hazard Pictograms
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.
P242 Use only non-sparking tools.
P501 Dispose of contents/container according to Directive 94/62/CE or
2008/98/CE.
Classification (67/548/CEE or 1999/45/CE).
Xn Harmful
F Highly flammable
R20/21/22
R11
For the full text of the R-phrases mentioned in this section, see section 16.
3.
Component Composition/Information
Name: Pyridine
Formula: C5H5N M.= 79,10 CAS [110-86-1]
EC number (EINECS): 203-809-9
EC index number: 613-002-00-7
REACH Registration Number: 01-2119493105-40-XXXX
4.
First aid
4.1 General indications:
Never provide drink or induce vomiting in the event of loss of consciousness.
4.2 Inhaling:
Take the person out into the fresh air. In the event of suffocation, proceed to
provide artificial respiration.
4.3 Contact with the skin:
Wash with plenty of water. Remove contaminated clothing.
4.4 Eyes:
Wash with plenty of water (for at least 15 minutes), keeping eyelids open. Seek
medical assistance.
4.5 Swallowing:
Avoid vomiting. Risk of aspiration. Seek medical assistance. Avoid stomach lavage.
Do not drink milk.
5.
Fire-fighting means
5.1 Suitable fire-extinguishing means:
Water. Carbon dioxide (CO2). Foam. Dry powder.
5.2 Fire-fighting means which must NOT be used:
No specific data.
5.3 Special risks:
Flammable. Keep away from sources of ignition. The fumes are heavier than air,
so they may spread at floor level. May form explosive mixtures with the air. Risk
of inflammation due to accumulation of electrostatic charges. In the event of fire,
toxic fumes may form: NOx.
5.4 Protective equipment:
Suitable clothing and footwear.
6.
Measures to be taken in the event of accidental spillage
6.1 Individual precautions:
Do not inhale the fumes.
6.2 Precautions for care of the environment:
Do not allow it to enter the drainage system. Avoid pollution of the soil, water
supplies and drains.
6.3 Methods for collection/cleaning:
Collect up with absorbent materials (Panreac General Absorbent, Kieselguhr, etc.)
or, if none available, dry sand or earth, and deposit in waste containers for
subsequent elimination in accordance with current legislation. Clean any remains
with plenty of water.
7.
Handling and storage
7.1 Handling:
No special indications.
7.2 Storage:
Well sealed containers.Dry atmosphere.In well ventilated premises.Away from
sources of ignition and heat.Room temperature.
8.
Staff exposure/protection controls
8.1 Technical protective measures:
No special indications.
8.2 Exposure limit control:
VLA-ED: 5 ppm - 15 mg/m3
8.3 Respiratory protection:
In the event of fumes forming/aerosols, use suitable respiratory protection. Filter
A. Filter P.
8.4 Hand protection:
Use suitable gloves
8.5 Eye protection:
Use suitable goggles.
8.6 Individual hygiene measures:
Remove contaminated clothing. Use suitable work clothing. Wash hands and face
before breaks and when the job is done.
8.7 Environmental exposure controls:
Fulfill the commitments under local environmental protection legislation.
9.
Physical and chemical properties
Appearance: liquid
Colour: Colourless
Granulometry: N/A
Odour: Unpleasant, characteristic.
pH: 8,5 ((15g/l))
Melting point/freezing point: -41,6 °C
Initial boiling point and boiling range: 115,2 °C
Flash point: 17 °C
Flammability (solid, gas):
N/A
Upper/lower flammability or explosive limits: 10,6 %(V) / 1,7 %(V)
Vapour pressure: 20 hPa (20 °C)
Vapour density: N/A
Relative density: (20/4) 0,9827
Solubility: Miscible with water
Partition coefficient: n-octanol/water:
N/A
Auto-ignition temperature: 550 °C
Decomposition temperature: N/A
Viscosity: N/A
10.
Stability and reactivity
10.1 Conditions which should be avoided:
The product is chemically stable under standar ambient conditions (room
temperature).
10.2 Matter which should be avoided:
Nitric acid. Anhydrides. Fluorine. Halogen halides. Chromates. Perchromates.
Nitrogen oxides. Sulphur oxides.
10.3 Hazardous decomposition products:
No specific data.
10.4 Complementary information:
Hygroscopic. The gases/fumes can form explosive mixtures with the air.
11.
Toxicological information
11.1 Acute toxicity:
LD L0 oral gpg : 4 g/Kg
LD50 oral rat : 891 mg/kg
LD50 skn rbt : 1.121 mg/kg
LC L0 inh rat : 4000 ppm 4h
11.2 Dangerous effects for health:
Upon contact with the skin: Irritations to the skin and mucosae. If swallowed:
nausea vomiting headaches anxiety insomnia In high concentrations:
cardiovascular disorders collapse narcosis Risk of cutaneous absorption. Chronic
effects hepatic problems kidney problems Easily detectable due to its
characteristic unpleasant smell, tolerable at low levels.
12.
Environmental information
12.1
Toxicity:
12.1.1 - EC50 test (mg/l):
Bacteria (Photobacterium phosphoreum) 2120 mg/l
Classification:
Very toxic
Algae (M. aeruginosa) EC0 28
Classification:
Extr. toxic
Algae (Sc. cuadricauda) EC0 120
Classification: Highly toxic
Crustaceans (Daphnia magna) 240 mg/l
Classification: Highly toxic
Fish (Leuciscus Idus) 225 mg/l
Classification: Highly toxic
Protozoa (E. sulcatum) EC0 240
Classification: Highly toxic
12.1.2. - Receptor medium: Risk for the water environment
Medium Risk for the land environment
Low 12.1.3. - Observations:
Ecotoxicity in line with the dumping concentration. Low chronic ecotoxicity.
12.2
Persistence and Degradability :
12.2.1 - Test:
12.2.2. - Biotic degradation classification:
BOD5/COD
Biodegradability
12.2.3. - Abiotic degradation depending on pH:
12.2.4. - Observations:
Data not available.
12.3
Bioaccumulative potential:
12.3.1. - Test:
12.3.2. - Bioaccumulation:
Risk
12.3.3. - Observations:
Product with a low bioaccumulative potential.
12.4
Mobility in soil :
Data not available.
12.5 Assessment PBT and MPMB :
Data not available.
12.6
Other possible effects on the environment:
Pollutant product.
Do not allow it to enter soils or water channels.
Risk of formation of explosive fumes on the surface of the water.
13.
Considerations regarding elimination
13.1
Substance or preparation:
In the European Union, there are no homogeneous standards established for
elimination of chemical waste, which is waste of a special nature, and treatment
and elimination of same is subject to the domestic legislation in each country.
In view of this, in each case, you should contact the competent authority or those
companies legally authorized for elimination of waste.
2001/573/EC: Council Decision of 23 July 2001 amending Commission Decision
2000/532/EC as regards the list of wastes.Council Directive 91/156/EEC of 18
March 1991 amending Directive 75/442/EEC on waste.
.
13.2
Contaminated containers:
Contaminated containers and packaging of dangerous substances or preparations
must be treated in the same manner as the actual products contained in them.
European Parliament and Council Directive 94/62/EC of 20 December 1994 on
packaging and packaging waste.
.
14.
Information concerning transport
Overland (ADR):
Technical name: PYRIDINE
UN 1282 Class: 3 Packaging group: II (D/E)
By sea (IMDG):
Technical name: PYRIDINE
UN 1282 Class: 3 Packaging group: II
By air (ICAI-IATA):
Technical name: Pyridine
UN 1282 Class: 3 Packaging group: II
Packaging instructions: CAO 364 PAX 353
15.
Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
16.
Other information
Other precautionary statements
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly after handling.
P270 Do no eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P322 Specific measures (see on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
Labelling (65/548/CEE or 1999/45/CE)
R-phrase(s):
R20/21/22 Harmful by inhalation, in contact
with skin and if swallowed.
R11 Highly flammable.
S-phrase(s):
S28a After contact with skin, wash immediately
with plenty of water.
S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
Review number and date: 4 15.09.2011
Date published: 15.09.2011
In respect of the previous review, changes have been made to the following
sections: 15
The information included in this Safety Data Sheet is based on our most up-to-date
knowledge, and is solely intended to inform regarding aspects of safety; the
properties and characteristics indicated herein are not guaranteed.
S a f e t y D a t a S h e e t
в соответствии с Regulation (EC) 1907/2006
1457
Пиридин
1.
Identification вещества/preparation и the
company или firm
1.1 Определение вещества или preparation
Название:
Пиридин
Synonym:
REACH Registration Number: 01-2119493105-40-XXXX
1.2 Use вещества/preparation:
Для общелабораторного использования, анализов, исследований и тонкой химии.
1.3 Сведения о компании или фирме:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail:
1.4 Emergency telephone:
Single telephone number for emergency calls: 112 (EU)
Tel.: (+34) 937 489 499
2.
Identification dangers
Классификация вещества или the mixture.
Классификация Regulation (CE) nº 1272/2008.
Flam. Liq. 2
Acute Tox. 4
Acute Tox. 4
Acute Tox. 4
Hazard Pictograms
Signal word
Danger
Hazard statements
H225 Легко воспламеняем жидкость и vapour.
H332 Вредный if inhaled.
H312 Вредный в contact с skin.
H302 Вредный При попадании внутрь.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить.
P233 Keep container tightly closed.
P240 Ground/bond container и receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/.../ equipment.
P242 Use only non-sparking tools.
P501 Выбросить contents/container в соответствии с Directive 94/62/CE или
2008/98/CE.
Классификация (67/548/CEE или 1999/45/CE).
Xn Вредный
F Легко воспламеняем
R20/21/22
R11
For the full text the R-выражения mentioned в this section, see section 16.
3.
Сведения о компонентах и состав
Название: Пиридин
Формула: C5H5N M.= 79,10 CAS [110-86-1]
Номер ЕС (EINECS): 203-809-9
ЕС индекс: 613-002-00-7
REACH Registration Number: 01-2119493105-40-XXXX
4.
Первая помощь
4.1 Общие указания:
Не давать пить и не вызывать рвоту при потере сознания.
4.2 Вдыхание:
Переместить пострадавшего на свежий воздух. В the event suffocation, proceed до
provide artificial respiration.
4.3 Контакт с кожей:
Промыть большим количеством воды. Избавиться от загрязненной одежды.
4.4 Глаза:
Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Seek
medical assistance.
4.5 Попадание Внутрь:
Avoid рвота. Риск aspiration. Обратиться за медицинской помощью. Avoid stomach lavage.
Do not drink milk.
5.
Fire-fighting means
5.1 Пригодные средства пожаротушения:
Вода. Углекислый газ (CO2). Пена. Песок.
5.2 Меры и средства обеспечения пожаро- и взрывобезопасности which must NOT be used:
No specific data.
5.3 Особая опасность:
Воспламеняем. Держать на расстоянии от источников возгорания. The fumes are heavier than air,
so they may spreaD при floor level. Могут образовывать взрывоопасные соединения с воздухом. Риск
inflammation due до аккумуляция electrostatic charges. В the event fire,
токсично fumes may form: NOx.
5.4 Средства индивидуальной защиты:
Специальная одежда и обувь.
6.
Меры по предотвращению и ликвидации чрезвычайных ситуаций
6.1 Индивидуальные меры предосторожности:
Не вдыхать пары.
6.2 Меры по защите окружающей среды:
Не допускайте попадания в канализацию.. Avoid pollution the soil, вода
supplies и drains.
6.3 Методы нейтрализации и очистки:
Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.)
или, if none available, безводн. sand или earth, и deposit в waste containers for
subsequent elimination в соответствии с законодательством. Clean any remains
с plenty вода.
7.
Правила обращения и хранения
7.1 Обращение:
Специальные указания отсутствуют.
7.2 Хранение:
В запечатанных контейнерах.Сухая атмосфера.В хорошо проветриваемом помещении.Away from
sources ignition и heat.Room temperature.
8.
Staff exposure/protection controls
8.1 Технические меры защиты:
Специальные указания отсутствуют.
8.2 Контроль предельно допустимого уровня воздействия:
VLA-ED: 5 ppm - 15 мг/м3
8.3 Защита органов дыхания:
В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр
A. Фильтр P.
8.4 Защита рук:
Использовать защитные перчатки
8.5 Защита глаз:
Использовать защитные очки.
8.6 Индивидуальные средства гигиены:
Избавиться от загрязненной одежды. Использовать специальную одежду. Wash hands и face
before breaks и when the job is done.
8.7 Контроль воздействия на окружающую среду:
Выполнять предписания по охране окружающей среды в соответствии с местным законодательством.
9.
Физико-химические свойства
Внешний Вид: жидкость
Цвета: Бесцветная
Granulometry: N/A
Запах: Unpleasant, характерный.
pH: 8,5 ((15g/l))
точка плавления/Температура замерзания: -41,6 °C
Initial Точка кипения и Интервал температур кипения: 115,2 °C
Точка воспламенения: 17 °C
Flammability (solid, gas):
N/A
Верхний/нижний flammability или explosive показатели: 10,6 %(V) / 1,7 %(V)
Давление пара: 20 hPa (20 °C)
Vapour плотность: N/A
Relative плотность: (20/4) 0,9827
Растворимость: Смешивается с водой
Partition coefficient: н-октанол/вода:
N/A
Auto-ignition temperature: 550 °C
Decomposition temperature: N/A
Вязк.: N/A
10.
Стабильность и реакционноспособность
10.1 Условия, которых следует избегать:
The product is chemically stable under standar ambient conditions (room
temperature).
10.2 Вещества, которых следует избегать:
Азотная кислота. Anhydrides. Fluorine. Halogen галиды. Chromates. Perchromates.
оксиды азота. Sulphur oxides.
10.3 Опасные продукты разложения:
No specific data.
10.4 Общая информация:
Гигроскопичный. The gases/fumes can form explosive mixtures с the air.
11.
Токсикологическая информация
11.1 Высокая токсичность:
LD L0 oral gpg : 4 g/Kg
LD50 oral rat : 891 мг/кг
LD50 skn rbt : 1.121 мг/кг
LC L0 inh rat : 4000 ppm 4h
11.2 Опасное воздействие на здоровье:
Upon Контакт с кожей: Irritations до the skin и mucosae. При попадании внутрь:
тошнота рвота headaches anxiety insomnia В высокий concentrations:
cardiovascular disorders collapse narcosis Cуществует риск попадания в кровоток через кожные покровы. Chronic
effects hepatic problems kidney problems Легко detectable due до its
характерный unpleasant smell, tolerable при low levels.
12.
Информация по окружающей среде
12.1
Toxicity:
12.1.1 - EC50 тест (mg/l):
Бактерии (Photobacterium phosphoreum) 2120 mg/l
Классификация:
Очень токсично
Algae (M. aeruginosa) EC0 28
Классификация:
Extr. токсично
Algae (Sc. cuadricauda) EC0 120
Классификация: Highly токсично
Crustaceans (Daphnia magna) 240 mg/l
Классификация: Highly токсично
Рыбы (Leuciscus Idus) 225 mg/l
Классификация: Highly токсично
Protozoa (E. sulcatum) EC0 240
Классификация: Highly токсично
12.1.2. - Воздействие на окружающую среду: Риск для водной среды
Средний Риск для земли
Low 12.1.3. - Наблюдения:
Экотоксичность в line с the dumping концентрация. Low chronic экотоксичность.
12.2
Persistence и Период Распада :
12.2.1 - Тест:
12.2.2. - Классификация биотического периода распада:
BOD5/COD
Биоразложение
12.2.3. - Абиотический период распада зависит от рН:
12.2.4. - Наблюдения:
Нет данных.
12.3
Bioaccumulative potential:
12.3.1. - Тест:
12.3.2. - Биоаккумуляция:
Риск
12.3.3. - Наблюдения:
Product с a low bioaccumulative potential.
12.4
Мобильность в soil :
Нет данных.
12.5 Assessment PBT и MPMB :
Нет данных.
12.6
Другие возможные воздействия на окружающую среду:
Продукт загрязнения.
Избегать попаданию вещества в почву и воду.
Риск formation explosive fumes on the surface the вода.
13.
Правила утилизации
13.1
Вещество или препарат:
В the Европейск. Union, there are no homogeneous standards established for
elimination chemical waste, which is waste a special nature, и treatment
и elimination same is subject до the domestic legislation в each country.
В view this, в each case, you should contact the competent authority или those
companies legally authorized for elimination waste.
2001/573/EC: Council Decision 23 July 2001 amending Commission Decision
2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18
March 1991 amending Directive 75/442/EEC on waste.
.
13.2
Загрязненные контейнеры:
Загрязненные контейнеры и packaging dangerous соединения или preparations
must be treated в the same manner как the actual products contained в them.
Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on
packaging и packaging waste.
.
14.
Информация относительно транспорта
Автотранспорт (ADR):
Техническое название: PYRIDINE
UN 1282 Класс: 3 Группа: II (D/E)
Морской транспорт (IMDG):
Техническое название: PYRIDINE
UN 1282 Класс: 3 Группа: II
Авиа транспорт (ICAI-IATA):
Техническое название: Пиридин
UN 1282 Класс: 3 Группа: II
Инструкция по упаковке: CAO 364 PAX 353
15.
Regulatory information
This safety datasheet complies с the requirements Regulation (EC) No.
1907/2006.
16.
Дополнительная информация
Др. precautionary statements
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly после обращение.
P270 Do no eat, drink или smoke when using this product.
P271 Use only outdoors или в a well-ventilated area.
P280 Wear protective gloves/protective clothing/Защита глаз/face protection.
P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you
feel unwell.
P302+P352 IF ON SKIN: Wash с plenty soap и вода.
P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all
contaminated clothing. Rinse skin с водой/shower.
P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position
comfortable for breathing.
P312 Call a POISON CENTER или doctor/physician if you feel unwell.
P322 Specific measures (see on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P370+P378 В case fire: Use for extinction.
P403+P235 Store в a well-ventilated place. Keep cool.
Labelling (65/548/CEE или 1999/45/CE)
R-phrase(s):
R20/21/22 Вреден при вдыхании, в contact
с skin и При попадании внутрь.
R11 Легко воспламеняем.
S-phrase(s):
S28a После contact с skin, wash immediately
с plenty вода.
S26 В case contact с глаза, rinse
immediately с plenty вода и seek
medical advice.
Номер рецензии и дата: 4 15.09.2011
Date published: 15.09.2011
В respect the previous review, changes have been made до the following
sections: 15
The information included в this Safety Data Sheet is based on our most up-до-date
knowledge, и is solely intended до inform regarding aspects safety; the
properties и characteristics indicated herein are not guaranteed.