1. Определение the
соединен./preparation и the company или firm
|
1.1
Определение the
Вещество или препарат
Название:
Zenker's Fixing
Synonym:
Zenker, Zenker#s Жидкость
REACH
Registration Number: A registration number is
not available for this соединен. как the соединен. или its use are exempted
from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006,
the annual tonnage does not requiere a registration, the registration is
envisaged for a later registration deadline или it is a mixture.
|
1.2
Use the
соединен./preparation:
|
Для общелабораторного использования, analysis,
research и мелк. chemistry.
|
1.3 Определение
the company или firm:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail: product.safety@panreac.com
|
1.4 Emergency
telephone:
Single telephone number for emergency
calls: 112 (EU)
Tel.: (+34)
937 489 499
|
2. Виды опасного воздействия
|
Классификация вещества или the
mixture.
|
Классификация
Regulation (CE) nº 1272/2008.
Acute Tox. 3
Eye Irrit. 2
Skin Irrit. 2
STOT RE 2
Carc. 1B
Muta. 1B
Aquatic Chronic 2
|
Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H311 Токсично в contact с
skin.
H319 Causes serious eye
irritation.
H315 Causes skin irritation.
H373 May cause damage до
organs <или state all organs affected, if known> through prolonged или
repeated exposure <state route exposure if it is conclusively proven
that no др. routes exposure cause the hazard>.
H350i May cause cancer by
inhalation.
H340 May cause genetic defects
<state route exposure if it is conclusively proven that no др. routes
exposure cause the hazard>.
H411 Токсично до aquatic life
с long lasting effects.
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Precautionary statements
P201 Obtain special
instructions before use.
P202 Do not handle until all
safety precautions have been чтение и understood.
P260 Do not breathe
dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly после
обращение.
P273 Avoid release до the
environment.
P280 Wear protective
gloves/protective clothing/Защита глаз/face protection.
|
|
Классификация
(67/548/CEE или 1999/45/CE).
N Dangerous for the
environment
T Токсично
|
R49
R48/21/22
R36/38
R25
R46
R51/53
|
|
For the full text the R-выражения mentioned в this section, see
section 16.
|
3. Сведения о компонентах и состав
|
|
Название: Zenker's Fixing
|
Состав:
0001: Натрия
Сульфат безводный
Формула: Na2SO4
M.= 142,04 CAS [7757-82-6]
Номер ЕС (EINECS): 231-820-9
Content: <= 2 %
|
No
опасная доза соединен. как specified в Regulation (CE) 1272/2008.
No
опасная доза соединен. как specified в Классификация (67/548/CEE или
1999/45/CE).
Формула: K2Cr2O7 M.= 294,19 CAS [7778-50-9]
Номер ЕС (EINECS): 231-906-6
ЕС индекс: 024-002-00-6
Content: <= 5 %
|
Классификация
Regulation (CE) nº 1272/2008.
Carc. 1B
Muta. 1B
Repr. 1B
Ox. Sol. 2
Acute Tox. 4
Acute Tox. 3
Acute Tox. 2
Skin Corr. 1B
Resp. Sens 1
Skin Sens. 1
STOT RE 1
Aquatic Acute 1
Aquatic Chronic 1
|
Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H350 May cause cancer
<state route exposure if it is conclusively proven that no др. routes
exposure cause the hazard>.
H340 May cause genetic defects
<state route exposure if it is conclusively proven that no др. routes
exposure cause the hazard>.
H360FD May damage fertility. May
damage the unborn child.
H272 May intensify fire;
oxidiser.
H312 Вредный в contact с
skin.
H301 Токсично При попадании внутрь.
H330 Fatal if inhaled.
H314 Causes severe skin ожоги
и eye damage.
H334 May cause allergy или
asthma symptoms или затруднение дыхания if inhaled.
H317 May cause an allergic
skin reaction.
H372 Causes damage до organs
<или state all organs affected, if known> through prolonged или repeated
exposure <state route exposure if it is conclusively proven that no
др. routes exposure cause the hazard>.
H410 Очень токсично до aquatic
life с long lasting effects.
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Precautionary statements
P201 Obtain special
instructions before use.
P202 Do not handle until all
safety precautions have been чтение и understood.
P210 Keep away from
heat/sparks/open flames/hot surfaces. Не курить.
P220 Keep/Store away from
clothing/горючее вещество materials.
P221 Take any precaution до
avoid mixing с combustibles.
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
P260 Do not breathe
dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing
dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly после
обращение.
P270 Do no eat, drink или smoke
when using this product.
P271 Use only outdoors или в a
well-ventilated area.
P272 Contaminated work
clothing should not be allowed out the workplace.
P273 Avoid release до the
environment.
P280 Wear protective
gloves/protective clothing/Защита глаз/face protection.
P281 Use personal protective
equipment как required.
P284 Wear respiratory
protection.
P285 В case inadequate
ventilation wear Защита органов дыхания.
P301+P310 При попадании внутрь: Immediately
call a POISON CENTER или doctor/physician.
P301+P330+P331 При попадании внутрь: rinse
mouth. Do NOT Вызвать рвоту.
P302+P352 IF ON SKIN: Wash с
plenty soap и вода.
P303+P361+P353 IF ON SKIN (или hair):
Remove/Take off immediately all contaminated clothing. Rinse skin с
вода/shower.
P304+P340 IF INHALED: Remove victim
до fresh air и keep при rest в a position comfortable for breathing.
P304+P341 IF INHALED: If breathing
is difficult, remove victim до fresh air и keep при rest в a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse
cautiously с водой for several minutes. Remove contact lenses, if present
и easy до do. Continue rinsing.
P308+P313 IF exposed или concerned:
Get medical advice/attention.
P310 Immediately call a POISON
CENTER или doctor/physician.
P312 Call a POISON CENTER или
doctor/physician if you feel unwell.
P314 Get medical
advice/attention if you feel unwell.
P320 Specific treatment is
urgent (see on this label).
P321 Specific treatment (see
on this label).
P322 Specific measures (see on
this label).
P330 Rinse mouth.
P333+P313 If skin irritation или
rash occurs: Get medical advice/attention.
P338 Remove contact lenses, if
present и easy до do. Continue rinsing.
P342+P311 If experiencing
respiratory symptoms: Call a POISON CENTER или doctor/physician.
P363 Wash contaminated
clothing before reuse.
P370+P378 В case fire: Use for
extinction.
P391 Collect spillage.
P403+P233 Store в a
well-ventilated place. Keep container tightly closed.
P405 Store locked up.
|
Классификация
(67/548/CEE или 1999/45/CE).
T+ Очень токсично
N Dangerous for the
environment
O Oxidizing
|
R45 May
cause cancer.
R46 May
cause heritable genetic damage.
R60 May
impair fertility.
R61 May
cause harm до the unborn child.
R8 Contact
с горючее вещество material may cause fire.
RE21 Also
вредный в contact с skin.
RE25 Also
токсично При попадании внутрь.
RE26 Also
Очень токсично by inhalation.
R34 Causes
ожоги.
R42/43 May
cause sensitisation by inhalation и skin contact.
RE48/23 Also
токсично: danger serious damage до health by prolonged exposure through
inhalation.
R50/53 Very
токсично до aquatic organisms, may cause long-term adverse effects в the
aquatic environment.
|
|
Формула: HgCl2
M.= 271,50 CAS [7487-94-7]
Номер ЕС (EINECS): 231-299-8
ЕС индекс: 080-010-00-X
Content: <= 7 %
|
Классификация
Regulation (CE) nº 1272/2008.
Acute Tox. 2
Skin Corr. 1B
STOT RE 1
Repr. 2
Muta. 2
Aquatic Acute 1
Aquatic Chronic 1
|
Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H300 Fatal При попадании внутрь.
H314 Causes severe skin ожоги
и eye damage.
H372 Causes damage до organs
<или state all organs affected, if known> through prolonged или repeated
exposure <state route exposure if it is conclusively proven that no
др. routes exposure cause the hazard>.
H361f Suspected damaging
fertility.
H341 Suspected causing
genetic defects <state route exposure if it is conclusively proven that
no др. routes exposure cause the hazard>.
H410 Очень токсично до aquatic
life с long lasting effects.
|
Precautionary statements
P201 Obtain special
instructions before use.
P202 Do not handle until all
safety precautions have been чтение и understood.
P260 Do not breathe
dust/fume/gas/mist/vapours/spray.
P264 Wash...thoroughly после
обращение.
P270 Do no eat, drink или smoke
when using this product.
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
P273 Avoid release до the
environment.
P280 Wear protective
gloves/protective clothing/Защита глаз/face protection.
P281 Use personal protective
equipment как required.
P301+P310 При попадании внутрь: Immediately
call a POISON CENTER или doctor/physician.
P301+P330+P331 При попадании внутрь: rinse
mouth. Do NOT Вызвать рвоту.
P303+P361+P353 IF ON SKIN (или hair):
Remove/Take off immediately all contaminated clothing. Rinse skin с
вода/shower.
P304+P340 IF INHALED: Remove victim
до fresh air и keep при rest в a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse
cautiously с водой for several minutes. Remove contact lenses, if present
и easy до do. Continue rinsing.
P308+P313 IF exposed или concerned:
Get medical advice/attention.
P310 Immediately call a POISON
CENTER или doctor/physician.
P314 Get medical
advice/attention if you feel unwell.
P321 Specific treatment (see
on this label).
P330 Rinse mouth.
P338 Remove contact lenses, if
present и easy до do. Continue rinsing.
P363 Wash contaminated
clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
|
Классификация
(67/548/CEE или 1999/45/CE).
N Dangerous for the
environment
T+ Очень токсично
|
R62 Possible
риск impaired fertility.
R48/24/25 Токсично:
danger serious damage до health by prolonged exposure в contact с
skin и При попадании внутрь.
R34 Causes
ожоги.
R28 Very
токсично При попадании внутрь.
R68 Possible
риск irreversible effects.
R50/53 Very
токсично до aquatic organisms, may cause long-term adverse effects в the
aquatic environment.
|
|
|
|
4. Первая помощь
|
4.1 General
indications:
Never provide drink или Вызвать рвоту в
the event loss consciousness.
|
4.2 Вдыхание:
Переместить пострадавшего на свежий воздух. В the event
suffocation, proceed до provide artificial respiration. В the event sickness
persists, Обратиться за медицинской помощью.
|
4.3 Contact
с the skin:
Промыть большим количеством воды. Remove
contaminated clothing.
|
4.4 Глаза:
Промыть большим количеством воды (не менее 15
minutes), Веки постоянно держать открытыми. При раздражении кожи, seek medical
assistance.
|
4.5 Попадание Внутрь:
Выпить большое количество воды или milk. Вызвать рвоту. Обратиться за медицинской помощью.
|
5. Меры и средства обеспечения пожаро- и взрывобезопасности
|
5.1 Suitable
fire-extinguishing means:
Не опасные для окружающей среды.
|
5.2 Fire-fighting
means which must NOT be used:
No specific data.
|
5.3 Special
risks:
Incombustible. В the event fire,
токсично fumes may form:
|
5.4 Protective
equipment:
Специальная одежда и обувь.
|
6. Measures до be taken в the event
accidental spillage
|
6.1 Индивидуальные
precautions:
Avoid Контакт с кожей, глаза или
clothing.
|
6.2 Precautions
for care the environment:
Do not allow it до enter the drainage
system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.
|
6.3 Methods
for collection/cleaning:
Collect up с absorbent materials
(Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand
или earth, и deposit в waste containers for
subsequent elimination в соответствии с законодательством. Clean any remains с
plenty вода.
|
7. Правила обращения и хранения
|
7.1 Обращение:
Специальные указания отсутствуют.
|
7.2 Хранение:
В запечатанных контейнерах.В
well ventilated premises.Room temperature.Restricted access, only authorized
до technicians.
|
8. Требования по охране труда и меры по обеспечению безопасности персонала
|
8.1 Technical
protective measures:
Специальные указания отсутствуют.
|
8.2 Контроль предельно допустимого уровня воздействия:
VLA-ED(Hg): 0,025 мг/м3 dermal resorption
VLA-ED(K2Cr2O7): 0,05 мг/м3
|
8.3 Защита органов дыхания:
В the event fumes forming/aerosols, use
suitable Защита органов дыхания. Фильтр Hg. Фильтр P3. Фильтр P.
|
8.4 Защита рук:
Использовать защитные перчатки neopren nitrile PVC
|
8.5 Защита глаз:
Использовать защитные очки.
|
8.6 Индивидуальные средства гигиены:
Избавиться от загрязненной одежды. Use suitable work
clothing. Wash hands и face before breaks и when
the job is done.
|
8.7 Контроль воздействия на окружающую среду:
Fulfill the commitments under local
environmental protection legislation.
|
|
9. Physical и chemical
properties
|
Внешний Вид: жидкость
|
Цвета: Желт.
|
Granulometry: N/A
|
Запах: Без Запаха.
|
pH:
N/A
|
точка плавления/Температура замерзания: N/A
|
Initial Точка кипения и Интервал температур кипения:
N/A
|
Точка воспламенения:
N/A
|
Flammability (solid, gas):
N/A
|
Верхний/нижний flammability или explosive
показатели:
N/A
|
Давление пара: N/A
|
Vapour плотность: N/A
|
Relative плотность: (20/4) 1,06
|
Растворимость: Смешивается с водой
|
Partition coefficient: n-октанол/вода:
N/A
|
Auto-ignition temperature:
N/A
|
Decomposition temperature: N/A
|
Вязк.: N/A
|
|
10. Стабильность и реакционноспособность
|
10.1 Conditions
which should be avoided:
The product is chemically stable under
standar ambient conditions (room temperature).
|
10.2 Matter
which should be avoided:
Металлы.
|
10.3 Hazardous
decomposition products:
No specific data.
|
10.4 Complementary
information:
No specific data.
|
11. Токсикологическая информация
|
11.1
Acute
toxicity:
LD L0 oral man : 29 мг/кг K2CO3
LD50 oral mus : 6 мг/кг K2CO3
LD50 oral rat : 1 мг/кг K2CO3
LD50 skn rat : 41 мг/кг K2CO3
LD50 ipr mus : 6 мг/кг HgCl2
|
11.2
Dangerous
effects for health:
Mercury соединен. have токсично effects on
cells и protoplasms. Symptoms due до acute intoxication (Hg): Through contact с the
глаза: Serious injuries При попадании внутрь и inhaled: Tissue injuries (mouth,
oesophagus, stomach и intestinal tract). Metallic taste тошнота рвота stomach pains intestinal disorders Ожоги в the digestive
apparatus oedemas в the respiratory tract pneumonia. Causes blood alterations arrhythmia collapse kidney problems Chronic effects Buccal infections,
mercury halo, риск loss teeth. Риск effects on the central
nervous system sensitization sight disorders hallucinations dizziness Pregnant women must not
be allowed до come into contact с the product. Possible риск adverse effects
до the foetus during pregnacy. Др. dangerous characteristics are not
discarded.
|
12. Информация по окружающей среде
|
12.1 Toxicity:
12.1.1 - EC50 тест (mg/l):
Бактерии (Photobacterium phosphoreum) 0,046 mg/l
Классификация:
Extr. токсично
Algae (Sc. cuadricauda) 0,07 mg/l
Классификация:
Extr. токсично
Algae (M. aeruginosa) 0,005 mg/l
Классификация:
Extr. токсично
Рыбы (Salmonidae) 0,05 mg/l
Классификация:
Extr. токсично
Рыбы (P. promelas) 0,19 mg/l
Классификация:
Extr. токсично
Рыбы (Leuciscus Idus) 0,013 mg/l
Классификация:
Extr. токсично
12.1.2. - Воздействие на окружающую среду:
Риск для водной среды
Высокий
Риск для земли
Высокий
12.1.3. - Наблюдения:
The экотоксичность is due до the mercury ion.
Токсично product в any environment.
Экотоксичность acute и chronic.
|
12.2 Persistence и
Период Распада :
12.2.1 - Тест:
12.2.2. - Biotic degradation
классификация:
BOD5/COD
Биоразложение
12.2.3. - Абиотический период распада зависит от
pH:
12.2.4. - Наблюдения:
|
12.3 Bioaccumulative
potential:
12.3.1. - Тест:
12.3.2. - Биоаккумуляция:
Риск = Высокий
12.3.3. - Наблюдения:
The mercury ion is bioaccumulable в the
food chain.
|
12.4 Мобильность в soil :
Нет данных.
|
12.5 Assessment PBT и MPMB :
Нет данных.
|
12.6 Др. possible effects on
the environment:
Продукт загрязнения.
Do not allow it до enter soils или вода
channels.
DATA BASED on the components the
preparation.
|
|
13. Considerations regarding
elimination
|
13.1 Вещество или препарат:
В the Европейск. Union, there are no homogeneous
standards established for elimination chemical waste, which is waste a
special nature, и treatment и elimination same is subject до the
domestic legislation в each country.
В view this, в each case, you should
contact the competent authority или those companies legally authorized for
elimination waste.
2001/573/EC: Council Decision 23 July 2001
amending Commission Decision 2000/532/EC как regards the list
wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive
75/442/EEC on waste.
.
|
13.2 Загрязненные контейнеры:
Загрязненные контейнеры и packaging
dangerous соединения или preparations must be treated в the same manner как
the actual products contained в them.
Европейск. Parliament и Council Directive
94/62/EC 20 December 1994 on packaging и packaging waste.
.
|
14. Информация относительно транспорта
|
Автотранспорт (ADR):
Техническое название:
TOXIC
LIQUID, INORGANIC, N.O.S.
UN 3287 Класс:
6.1 CONTAM. MAR PELIG.M.AMB Группа:
II
(D/E)
|
Морской транспорт (IMDG):
Техническое название:
TOXIC
LIQUID, INORGANIC, N.O.S.
UN 3287 Класс:
6.1 CONTAM. MAR PELIG.M.AMB Группа:
II
|
Авиа транспорт (ICAI-IATA):
Техническое название:
Токсично
жидкость, неорганический, n.o.s.
UN 3287 Класс:
6.1 CONTAM. MAR PELIG.M.AMB Группа:
II
|
Инструкция по упаковке: CAO 662 PAX 654
|
15. Regulatory information
|
The соединен. is subject до Regulation (EC)
No 689/2008 the Европейск. Parliament и the Council 17 June 2008
concerning the export и import dangerous chemicals.
|
|
16. Дополнительная информация
|
Др. precautionary
statements
P281 Use personal protective
equipment как required.
P302+P352 IF ON SKIN: Wash с
plenty soap и вода.
P305+P351+P338 IF IN EYES: Rinse
cautiously с водой for several minutes. Remove contact lenses, if present
и easy до do. Continue rinsing.
P308+P313 IF exposed или concerned:
Get medical advice/attention.
P312 Call a POISON CENTER или
doctor/physician if you feel unwell.
P314 Get medical
advice/attention if you feel unwell.
P321 Specific treatment (see
on this label).
P322 Specific measures (see on
this label).
P332+P313 If skin irritation
occurs: Get medical advice/attention.
P337+P313 If eye irritation
persists: Get medical advice/attention.
P361 Remove/Take off
immediately all contaminated clothing.
P362 Take off contaminated
clothing и wash before reuse.
P363 Wash contaminated
clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
|
Labelling
(65/548/CEE или 1999/45/CE)
|
R-phrase(s):
|
R49 May
cause cancer by inhalation.
R48/21/22 Вредный:
danger serious damage до health by prolonged exposure в contact с
skin и При попадании внутрь.
R36/38 Irritating
до глаза и skin.
R25 Токсично
При попадании внутрь.
R46 May
cause heritable genetic damage.
R51/53 Токсично
до aquatic organisms, may cause long-term adverse effects в the aquatic
environment.
|
S-phrase(s):
|
S60 This
material и its container must be disposed как опасная доза waste.
S53 Avoid
exposure - obtain special instructions before use.
S45 В
case accident или if you feel unwell, seek medical advice immediately
(show the lable where possible).
S36/37/39 Wear
suitable protective clothing, gloves и eye/face protection.
S61 Avoid
release до the environment. Refer до special instructions/safety data
sheets.
|
|
|
The information included в this Safety
Data Sheet is based on our most up-до-date knowledge, и is solely intended
до inform regarding aspects safety; the properties и characteristics
indicated herein are not guaranteed.
В respect the previous review, changes
have been made до the following sections: 2, 3, 15
Date published: 3.11.10
Номер рецензии и дата: 3 3.11.10
|
|