Version and revision date :  5 21.10.2013.         Remplaced:  15.09.2011.        

S a f e t y     D a t a     S h e e t

According to Regulation (EC) 1907/2006

1.      Identification of the substance/mixture and of the company/undertaking

1.1  Product identifier

Name:

Sodium Benzoate

Synonym:

Benzenecarboxylic Acid Sodium Salt, Benzoic AcidSodium Salt, Phenylformic Acid Sodium Salt

CAS: [532-32-1]

REACH Registration Number: 01-2119460683-35-XXXX

1.2  Relevant identified uses of the substance or mixture:

Industrial.

Professional

Version и revision date :  5 21.10.2013.         Remplaced:  15.09.2011.        

S a f e t y     D a t a     S h e e t

в соответствии с Regulation (EC) 1907/2006

1.      Определение the соединен./mixture и the company/undertaking

1.1  Product identifier

Название:

Натрия Бензоат

Synonym:

Benzenecarboxylic Кислота Натриевая соль, Бензойн. КислотаНатриевая соль, Phenylformic Кислота Натриевая соль

CAS: [532-32-1]

REACH Registration Number: 01-2119460683-35-XXXX

1.2  Relevant identified uses вещества или mixture:

Industrial.

Professional

1.3  Определение the company или firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

2.    Виды опасного воздействия

2.1  Классификация вещества или the mixture.

Классификация Regulation (CE) nº 1272/2008.

Eye Irrit. 2

Классификация (67/548/CEE или 1999/45/CE).

2.2  Label элементы:

Hazard Pictograms

Signal word

 Warning

  Hazard statements

H319  Causes serious eye irritation.

  Precautionary statements

P264  Wash...thoroughly после обращение.

P280  Wear protective gloves, protective clothing, Защита глаз или face protection.

P305+P351+P338  IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

P337+P313  If eye irritation persists: Get medical advice/attention.

For the full text the R-выражения mentioned в this section, see section 16.

2.3  Др. hazards:

No further relevant information available.

3.       Состав/information on ingredients

Название: Натрия Бензоат

Формула: C6H5COONa        M.=  144,10    CAS [532-32-1]

Номер ЕС (EINECS): 208-534-8

REACH Registration Number: 01-2119460683-35-XXXX

4.       Первая помощь measures

4.1  General indications:

Never provide drink или Вызвать рвоту в the event loss consciousness.

4.2  Вдыхание:

Переместить пострадавшего на свежий воздух. В case loss consciousness, position the person lying on his/her side. Seek immediate medical assistance. При ухудшении самочувствия, seek medical assistance.

4.3  Contact с the skin:

Промыть большим количеством воды. Remove contaminated clothing. При раздражении кожи, seek medical assistance.

4.4  Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми.

4.5  Попадание Внутрь:

Немедленно промыть ротовую полость. В the event sickness, Обратиться за медицинской помощью.

· Information for doctor:

· Most важно symptoms и effects, both acute и delayed: No further relevant information available.

· Indication any immediate medical attention и special treatment needed:

No further relevant information available.

5.      Firefighting measures

5.1  Suitable extinguishing среда:

Atomized вода. Углекислый газ (CO2). Спирт resistant пена. Песок.

5.2  Unsuitable extinguishing среда:

No specific data.

5.3  Special hazards arising from the соединен. или mixture:

Риск explosion dust.  Auf Rückzündung achten  Prevent the build-up static.  В случае возгорания могут образовываться токсичные пары: CO y CO2. 

5.4  Advice for firefighters:

Use complete Средства индивидуальной защиты. Self-contained breathing equipment.

6.       Accidental release measures

6.1  Personal precautions, Средства индивидуальной защиты и emergency procedures:

Avoid breathing dust, fume, gas, mist, vapours или spray. Use personal Средства индивидуальной защиты как required. Ensure good ventilation и renewal the air в the premises. Avoid sources ignition. Do not smoke.

6.2  Environmental precautions:

Avoid pollution the soil, вода supplies и drains.

6.3  Methods и material for containment и cleaning up:

Collect up безводн. и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода.

7.       Правила обращения и хранения

7.1 Precautions for safe обращение:

Ensure good ventilation и renewal the air в the premises. Не вдыхать пыль. Avoid the formation electrostatic charges. Use personal Средства индивидуальной защиты как required. Avoid sources ignition. Do not smoke. The gases/fumes can form explosive mixtures с the air.

7.2 Conditions for safe хранение, including any incompatibilities:

В запечатанных контейнерах. В a cool, безводн., well ventilated place. Away from sources ignition и heat.

8.       Exposure controls/personal protection

8.1  Exposure controls:

Ensure good ventilation и renewal the air в the premises.

8.2 Control parameters:

Derived No Effect Level (DNEL)

Workers Dermal, long exposure (systemic):   34,7mg/kg bw/24h

Workers Dermal, long exposure (local):   4,5mg/cm2

Workers Inhalation, long term (systemic): 10,4 мг/м3 

Workers Inhalation, long term (local): 6,3 мг/м3 

Population, oral, long term (systemic):   25mg/kg bw/24h

Population Inhalation, long term (systemic): 2,1 мг/м3 

Population, Dermal, long exposure (systemic):   20,8mg/kg bw/24h

Population, Dermal, long exposure (local):   2,7mg/cm2

Population Inhalation, long term (local): 1,3 мг/м3 

8.3 Защита органов дыхания:

If dust forms, use suitable respiratory protection. Фильтр P2.

8.4 Защита рук:

The glove material has до be impermeable и resistant до the product/ the соединен./ the preparation.

Selection the glove material on consideration the penetration times, rates diffusion и the degradation

· Material gloves

The selection the suitable gloves does not only depend on the material, but also on further marks quality и varies from manufacturer до manufacturer.

· Penetration time glove material

The exact break through time has до be found out by the manufacturer the protective gloves и has до be

observed.

· For the permanent contact gloves made the following materials are suitable:

Material: Butyl резина., nitrile, neopren, PVC, Fluorocarbon резина (Viton) Breakthrough time: >= 480 min.

8.5 Eye/face protection:

Use safety glasses.

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Wash hands before breaks и when the job is done.

8.7 Контроль воздействия на окружающую среду:

Fulfill the commitments under local environmental protection legislation.

9.      Physical и chemical properties

Внешний Вид: solid

Цвета: Белый

Granulometry: N/A

Запах: Без Запаха.

pH: 9 ((10% sol.))

точка плавления/Температура замерзания: 436 °C

Initial Точка кипения и Интервал температур кипения: 465 °C 

Точка воспламенения: > 100 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели:

N/A

Давление пара: N/A

Vapour плотность: N/A

Relative плотность:

Insertar Aquí Grupo de repeticion

  1,5 g/ml (20 °C)

Растворимость: 556 г/л в вода ( 20 °C  )

Partition coefficient: n-октанол/вода:   - 2,27   

Auto-ignition temperature:  >500 °C

Decomposition temperature:  N/A

Кинематич. вязк.:  N/A

Динамич. вязк.:

 N/A

10.  Стабильность и реакционноспособность

10.1  Conditions до avoid: 

Humidity.  

10.2   Incompatible materials:

Кислоты. Окислители. 

10.3  Hazardous decomposition products:

 No specific data.

10.4  Chemical stability:

The product is chemically stable under standar ambient conditions (room temperature). 

11.  Токсикологическая информация

11.1          Acute toxicity:

LD50 oral rat  : > 2.000 мг/кг      

LD50 skn rbt  : > 2.000 мг/кг     

LC50 inh rat  : >12,2 mg/l      

11.2          Dangerous effects for health:

Skin corrosion/irritation: Not classified., (OECD 404) Serious eye damage/irritation: Serious injuries, (OECD 405) Respiratory или skin sensitisation: Not classified. Germ кювета mutagenicity: Not classified. Carcinogenicity: Not classified. Reproductive toxicity: Not classified. STOT- single exposure: Not classified. STOT-repeated exposure: Not classified. Aspiration hazard: Not classified.

12.  Информация по окружающей среде

12.1  Toxicity:

Acute toxicity for рыбы: 

LC50  >100 mg/l (96h) (OECD 203)

Acute toxicity for aquatic invertebrates: 

EC50 (Daphnia magna) >100 mg/l (48h) (OECD 202)

Acute toxicity for бактерии: 

EC50  >100 mg/l (24h)

Chronic toxicity for aquatic invertebrates: 

NOEC (Daphnia magna) 51 mg/l (21d) (OECD 211)

Chronic toxicity for Algae: 

EC50  >100 mg/l (72h) (OECD 201)

12.2  Persistence и Период Распада :

Легко biodegradable product.

12.3  Bioaccumulative potential:

log Pow = -2,27

12.4  Мобильность в soil :

Нет данных.

12.5 Assessment PBT и MPMB :

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria for PBT (persistent / bioaccumulative / токсично).

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria vPvB (very persistent / very bioaccumulative).

12.6  Др. adverse effects:

If suitable обращение conditions are maintained, no ecological problems are до be anticipated.

13. Disposal considerations

13.1  Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

 В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste.

.

13.2  Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste.

.

14.  Transport information

Not classified как dangerous в the meaning ТРАНСПОРТНЫЕ ПОЛОЖЕНИЯ.

15.  Regulatory information

This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006.

For this product a chemical safety assessment was carried out.

16.  Дополнительная информация

  Др. precautionary statements

Labelling (65/548/CEE или 1999/45/CE)

Version и revision date : 5 21.10.2013

Remplaced: 15.09.2011

В respect the previous review, changes have been made до the following sections: 2, 8, 11, 12

The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed.