S a f e t y D a t a S h e e t |
According to Regulation (EC) 1907/2006 |
5982 Nickel *standard solution Ni=10,00+-0,02 g/l
1. Identification of the substance/preparation and of the company or firm |
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1.1 Identification of the substance or preparation Name: Nickel *standard solution Ni=10,00+-0,02 g/l Synonym: REACH Registration Number: A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline or it is a mixture.
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1.2 Use of the substance/preparation: |
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For laboratory utilisation, analysis, research and fine chemistry. |
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1.3 Identification of the company or firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com |
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499 |
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2. Identification of dangers |
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Classification of the substance or the mixture.
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Classification Regulation (CE) nº 1272/2008. Eye Irrit. 2 STOT SE 3 Skin Irrit. 2 |
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Hazard Pictograms
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Signal word Warning
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Hazard statements H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. |
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Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P501 Dispose of contents/container according to Directive 94/62/CE or 2008/98/CE. |
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Classification (67/548/CEE or 1999/45/CE).
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For the full text of the R-phrases mentioned in this section, see section 16. |
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3. Component Composition/Information |
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Name: Nickel *standard solution Ni=10,00+-0,02 g/l |
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Composition: 0001: Nitric Acid 69% Formula: HNO3 M.= 63,01 CAS [7697-37-2] EC number (EINECS): 231-714-2 EC index number: 007-004-00-1 REACH Registration Number: 01-2119487297-23-XXXX Content: >= 2S a f e t y D a t a S h e e t |
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в соответствии с Regulation (EC) 1907/2006 |
5982 Никеля *стандартный раствор Ni=10,00+-0,02 г/л
1. Определение the соединен./preparation и the company или firm |
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1.1 Определение the Вещество или препарат Название: Никеля *стандартный раствор Ni=10,00+-0,02 г/л Synonym: REACH Registration Number: A registration number is not available for this соединен. как the соединен. или its use are exempted from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006, the annual tonnage does not requiere a registration, the registration is envisaged for a later registration deadline или it is a mixture.
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1.2 Use the соединен./preparation: |
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Для общелабораторного использования, analysis, research и мелк. chemistry. |
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1.3 Определение the company или firm: PANREAC QUIMICA S.L.U. C/Garraf 2 Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 e-mail: product.safety@panreac.com |
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1.4 Emergency telephone: Single telephone number for emergency calls: 112 (EU) Tel.: (+34) 937 489 499 |
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2. Виды опасного воздействия |
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Классификация вещества или the mixture.
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Классификация Regulation (CE) nº 1272/2008. Eye Irrit. 2 STOT SE 3 Skin Irrit. 2 |
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Hazard Pictograms
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Signal word Warning
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Hazard statements H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. |
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Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P271 Use only outdoors или в a well-ventilated area. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. |
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Классификация (67/548/CEE или 1999/45/CE).
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For the full text the R-выражения mentioned в this section, see section 16. |
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3. Сведения о компонентах и состав |
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Название: Никеля *стандартный раствор Ni=10,00+-0,02 г/л |
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Состав: 0001: Nitric Кислота 69% Формула: HNO3 M.= 63,01 CAS [7697-37-2] Номер ЕС (EINECS): 231-714-2 ЕС индекс: 007-004-00-1 REACH Registration Number: 01-2119487297-23-XXXX Content: >= 2 % <= 5 % |
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Классификация Regulation (CE) nº 1272/2008. Skin Corr. 1A Ox. Sol. 3 |
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Hazard Pictograms
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Signal word Danger |
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Hazard statements H314 Causes severe skin ожоги и eye damage. H272 May intensify fire; oxidiser. |
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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить. P220 Keep/Store away from clothing/горючее вещество materials. P221 Take any precaution до avoid mixing с combustibles. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P301+P330+P331 При попадании внутрь: rinse mouth. Do NOT Вызвать рвоту. P303+P361+P353 IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с вода/shower. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P310 Immediately call a POISON CENTER или doctor/physician. P321 Specific treatment (see on this label). P338 Remove contact lenses, if present и easy до do. Continue rinsing. P363 Wash contaminated clothing before reuse. P370+P378 В case fire: Use for extinction. P405 Store locked up. |
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Классификация (67/548/CEE или 1999/45/CE).
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0002: Никеля(II) Нитрат 6-водный Формула: Ni(NO3)2.6H2O M.= 290,81 CAS [13478-00-7] Номер ЕС (EINECS): 236-068-5 Content: >= 2 % <= 10 % |
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Классификация Regulation (CE) nº 1272/2008. Carc. 1A Repr. 1B Ox. Sol. 2 Acute Tox. 4 Acute Tox. 4 Skin Irrit. 2 Eye Dam. 1 Resp. Sens 1 Skin Sens. 1 STOT RE 1 Muta. 2 Aquatic Acute 1 Aquatic Chronic 1 |
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Hazard Pictograms
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Signal word Danger |
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Hazard statements H350i May cause cancer by inhalation. H360D May damage the unborn child. H272 May intensify fire; oxidiser. H332 Вредный if inhaled. H302 Вредный При попадании внутрь. H315 Causes skin irritation. H318 Causes serious eye damage. H334 May cause allergy или asthma symptoms или затруднение дыхания if inhaled. H317 May cause an allergic skin reaction. H372 Causes damage до organs <или state all organs affected, if known> through prolonged или repeated exposure <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H341 Suspected causing genetic defects <state route exposure if it is conclusively proven that no др. routes exposure cause the hazard>. H410 Очень токсично до aquatic life с long lasting effects. |
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Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been чтение и understood. P210 Keep away from heat/sparks/open flames/hot surfaces. Не курить. P220 Keep/Store away from clothing/горючее вещество materials. P221 Take any precaution до avoid mixing с combustibles. P501 Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash...thoroughly после обращение. P270 Do no eat, drink или smoke when using this product. P271 Use only outdoors или в a well-ventilated area. P272 Contaminated work clothing should not be allowed out the workplace. P273 Avoid release до the environment. P280 Wear protective gloves/protective clothing/Защита глаз/face protection. P281 Use personal protective equipment как required. P285 В case inadequate ventilation wear Защита органов дыхания. P301+P312 При попадании внутрь: Call a POISON CENTER или doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash с plenty soap и вода. P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P304+P341 IF INHALED: If breathing is difficult, remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P308+P313 IF exposed или concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER или doctor/physician. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation или rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER или doctor/physician. P362 Take off contaminated clothing и wash before reuse. P363 Wash contaminated clothing before reuse. P370+P378 В case fire: Use for extinction. P391 Collect spillage. P405 Store locked up. |
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Классификация (67/548/CEE или 1999/45/CE).
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4. Первая помощь |
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4.1 General indications: Never provide drink или Вызвать рвоту в the event loss consciousness. |
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4.2 Вдыхание: Переместить пострадавшего на свежий воздух. В the event sickness persists, Обратиться за медицинской помощью. |
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4.3 Contact с the skin: Wash с plenty soap и вода. Remove contaminated clothing. При раздражении кожи, seek medical assistance. |
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4.4 Глаза: Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью. |
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4.5 Попадание Внутрь: Выпить большое количество воды. Вызвать рвоту. Обратиться за медицинской помощью. |
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5. Меры и средства обеспечения пожаро- и взрывобезопасности |
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5.1 Suitable fire-extinguishing means: Вода. Углекислый газ (CO2). Пена. Песок. |
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5.2 Fire-fighting means which must NOT be used: No specific data. |
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5.3 Special risks: Incombustible. В the event fire, токсично fumes may form: Do not allow extinguishing вода into surface или underground вода courses. |
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5.4 Protective equipment: Специальная одежда и обувь. Self-contained breathing equipment. |
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6. Measures до be taken в the event accidental spillage |
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6.1 Индивидуальные precautions: Avoid Контакт с кожей, глаза или clothing. Обеспечить хорошую вентиляцию Не вдыхать пары. |
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6.2 Precautions for care the environment: Do not allow it до enter the drainage system. Избегайте загрязнения почвы, систем водоснабжения и дренажа. |
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6.3 Methods for collection/cleaning: Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода. Neutralize с diluted Натрия гидроксид. |
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7. Правила обращения и хранения |
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7.1 Обращение: Ensure good ventilation и renewal the air в the premises. |
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7.2 Хранение: В запечатанных контейнерах.В a cool, безводн., well ventilated place.Room temperature.
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8. Требования по охране труда и меры по обеспечению безопасности персонала |
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8.1 Technical protective measures: Ensure good ventilation и renewal the air в the premises. |
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8.2 Контроль предельно допустимого уровня воздействия: VLA-EC(HNO3): 4 ppm - 10 мг/м3 VLA-ED(HNO3): 2 ppm - 5,2 мг/м3
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8.3 Защита органов дыхания: В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр NO. |
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8.4 Защита рук: Использовать защитные перчатки neopren latex |
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8.5 Защита глаз: Использовать защитные очки. |
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8.6 Индивидуальные средства гигиены: Избавиться от загрязненной одежды. Wash hands и face before breaks и when the job is done. Use suitable work clothing. Do not eat, drink или smoke в the workplace. Do not inhale the соединен.. |
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8.7 Контроль воздействия на окружающую среду: Fulfill the commitments under local environmental protection legislation. |
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9. Physical и chemical properties |
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Внешний Вид: жидкость |
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Цвета: Зелен. |
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Granulometry: N/A |
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Запах: Без Запаха. |
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pH: N/A |
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точка плавления/Температура замерзания: -3 °C |
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Initial Точка кипения и Интервал температур кипения: 101 °C |
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Точка воспламенения: N/A |
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Flammability (solid, gas): N/A |
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Верхний/нижний flammability или explosive показатели: N/A |
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Давление пара: N/A |
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Vapour плотность: N/A |
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Relative плотность: (20/4) 1,04 |
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Растворимость: Смешивается с водой |
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Partition coefficient: n-октанол/вода: N/A |
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Auto-ignition temperature: N/A |
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Decomposition temperature: N/A |
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Вязк.: N/A |
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10. Стабильность и реакционноспособность |
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10.1 Conditions which should be avoided: Высокий temperatures.
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10.2 Matter which should be avoided: Металлы и металл alloys. Щелочных hydroxides. |
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10.3 Hazardous decomposition products: оксиды азота. |
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10.4 Complementary information: No specific data. |
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11. Токсикологическая информация |
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11.1 Acute toxicity: : Нет данных.
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11.2 Dangerous effects for health: Taking the preparation' components into account, the likely dangerous characteristics are как follows: If inhaled: Irritations до the mucosae coughing затруднение дыхания Upon contact с the skin: irritations Through contact с the глаза: irritations При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract. (HNO3): If it is absorbed в large quantities: metahemoglobinemia с headaches For никеля соединен. generally: Неорганический никеля соединен. can have an astringent action on the mucosae. Can cause sensitization allergic reaction dermatitis Др. dangerous characteristics are not discarded. Take the usual precautions for обращение chemical products.
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12. Информация по окружающей среде |
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12.1 Toxicity: 12.1.1 - EC50 тест (mg/l): Рыбы (Leuciscus Idus) LC50 570 mg/l(Ni) Рыбы (P. promelas) LD50 27 mg/l(Ni) Crustaceans (Daphnia magna) LC50 11 mg/l(Ni) 12.1.2. - Воздействие на окружающую среду: Риск для водной среды Риск для земли 12.1.3. - Наблюдения: Ecotoxic в воде environment. The экотоксичность is due до the pH deviation. |
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12.2 Persistence и Период Распада : 12.2.1 - Тест: 12.2.2. - Biotic degradation классификация: BOD5/COD Биоразложение 12.2.3. - Абиотический период распада зависит от pH: 12.2.4. - Наблюдения: Нет данных.
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12.3 Bioaccumulative potential: 12.3.1. - Тест: 12.3.2. - Биоаккумуляция: Риск 12.3.3. - Наблюдения: Нет данных.
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12.4 Мобильность в soil : Нет данных. |
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12.5 Assessment PBT и MPMB : Нет данных.
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12.6 Др. possible effects on the environment: Do not allow it до enter soils или вода channels. Do not allow it до enter the sewage system. Продукт почти не загрязнитель для воды. Dangerous for drinking вода. Encourages eotrophy в rivers и вода channels. DATA BASED on the components the preparation.
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13. Considerations regarding elimination |
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13.1Вещество или препарат: В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country. В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste. 2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste. . |
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13.2Загрязненные контейнеры: Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them. Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste. . |
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14. Информация относительно транспорта |
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Автотранспорт (ADR): Техническое название: CORROSIVE LIQUID, N.O.S. UN 1760 Класс: 8 Группа: III (E) |
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Морской транспорт (IMDG): Техническое название: CORROSIVE LIQUID, N.O.S. UN 1760 Класс: 8 Группа: III |
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Авиа транспорт (ICAI-IATA): Техническое название: Коррозионное Вещество жидкость, n.o.s UN 1760 Класс: 8 Группа: III |
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Инструкция по упаковке: CAO 856 PAX 852 |
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15. Regulatory information |
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This safety datasheet complies с the requirements Regulation (EC) No. 1907/2006. |
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16. Дополнительная информация |
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Др. precautionary statements P304+P340 IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing. P312 Call a POISON CENTER или doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing и wash before reuse. P403+P233 Store в a well-ventilated place. Keep container tightly closed. P405 Store locked up. |
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Labelling (65/548/CEE или 1999/45/CE) |
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The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed. В respect the previous review, changes have been made до the following sections: 2, 3, 15 Date published: 3.11.10 Номер рецензии и дата: 3 3.11.10 |
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