1. Определение the
соединен./mixture и the company/undertaking
|
1.1
Product identifier
Название:
Петролейн. Эфир 40-60°C
Synonym:
Ligroin, Naphtha, Петролейн. Benzin
CAS: [64742-49-0]
REACH
Registration Number: A registration number is
not available for this соединен. как the соединен. или its use are exempted
from registration в соответствии с Article 2 REACH Regulation (EC) Nº 1907/2006,
the annual tonnage does not requiere a registration, the registration is
envisaged for a later registration deadline или it is a mixture.
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1.2
Relevant identified uses
вещества или mixture:
|
Для общелабораторного использования, analysis,
research и мелк. chemistry.
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1.3 Определение
the company или firm:
PANREAC QUIMICA S.L.U.
C/Garraf 2
Polígono Pla de la Bruguera
E-08211 Castellar del Vallès
(Barcelona) Spain
Tel. (+34) 937 489 400
e-mail: product.safety@panreac.com
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1.4 Emergency
telephone:
Single telephone number for emergency
calls: 112 (EU)
Tel.: (+34)
937 489 499
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2.
Виды опасного воздействия
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2.1 Классификация
вещества или the mixture.
|
Классификация Regulation (CE) nº 1272/2008.
Flam. Liq. 2
Skin Irrit. 2
Aquatic Chronic 2
Asp. Tox. 1
STOT SE 3
|
Классификация
(67/548/CEE или 1999/45/CE).
F Легко воспламеняем
Xn Вредный
N Dangerous for the
environment
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R11
R38
R51/53
R65
R67
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2.2 Label
элементы:
Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H225 Легко воспламеняем жидкость
и vapour.
H315 Causes skin irritation.
H304 May be fatal При попадании внутрь
и enters airways.
H336 May cause drowsiness или
dizziness.
H411 Токсично до aquatic life
с long lasting effects.
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Precautionary statements
P210 Keep away from
heat/sparks/open flames/hot surfaces. Не курить.
P240 Ground/bond container и
receiving equipment.
P273 Avoid release до the
environment.
P301+P310 При попадании внутрь: Immediately
call a POISON CENTER или doctor/physician.
P331 Do NOT Вызвать рвоту.
P403+P235 Store в a
well-ventilated place. Keep cool.
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For the full text the R-выражения mentioned в this section, see
section 16.
2.3 Др.
hazards:
No further relevant information available.
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3. Состав/information on ingredients
|
Mixture углеводороды, chiefly consisting
:
н-пентан.
2-methylpentane.
|
Название: Петролейн. Эфир 40-60°C
CAS [64742-49-0]
Номер ЕС (EINECS): 265-151-9
ЕС индекс: 649-328-00-1
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Состав:
Формула: C5H12
M.= 72,15 CAS [109-66-0]
Номер ЕС (EINECS): 203-692-4
ЕС индекс: 601-006-00-1
REACH Registration Number: 01-2119459286-30-XXXX
Content: >= 25 % <= 50 %
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Классификация
Regulation (CE) nº 1272/2008.
Flam. Liq. 2
Asp. Tox. 1
STOT SE 3
Aquatic Chronic 2
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Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H225 Легко воспламеняем жидкость
и vapour.
H304 May be fatal При попадании внутрь
и enters airways.
EUH066 Repeated exposure may
cause skin dryness или cracking.
H336 May cause drowsiness или
dizziness.
H411 Токсично до aquatic life
с long lasting effects.
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Precautionary statements
P210 Keep away from
heat/sparks/open flames/hot surfaces. Не курить.
P233 Keep container tightly
closed.
P240 Ground/bond container и
receiving equipment.
P241 Use explosion-proof
electrical/ventilating/lighting/equipment.
P242 Use only non-sparking
tools.
P243 Take precautionary
measures against static discharge.
P261 Avoid breathing dust,
fume, gas, mist, vapours или spray.
P271 Use only outdoors или в a
well-ventilated area.
P273 Avoid release до the
environment.
P280 Wear protective gloves,
protective clothing, Защита глаз или face protection.
P301+P310 При попадании внутрь: Immediately
call a POISON CENTER или doctor/physician.
P303+P361+P353 IF ON SKIN (или hair):
Remove/Take off immediately all contaminated clothing. Rinse skin с
вода/shower.
P304+P340 IF INHALED: Remove victim
до fresh air и keep при rest в a position comfortable for breathing.
P312 Call a POISON CENTER или
doctor/physician if you feel unwell.
P331 Do NOT Вызвать рвоту.
P370+P378 В case fire: Use for
extinction.
P391 Collect spillage.
P403+P233 Store в a
well-ventilated place. Keep container tightly closed.
P403+P235 Store в a
well-ventilated place. Keep cool.
P405 Store locked up.
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
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Классификация
(67/548/CEE или 1999/45/CE).
N Dangerous for the
environment
Xn Вредный
F+ Extremely воспламеняем
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R67 Vapours
may cause drowsiness и dizziness.
R66 Repeated
exposure may cause skin dryness или cracking.
R65 Вредный:
may cause lung damage При попадании внутрь.
R12 Extremely
воспламеняем.
R51/53 Токсично
до aquatic organisms, may cause long-term adverse effects в the aquatic
environment.
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|
Формула: C6H14
M.= 86,18 CAS [64742-49-0]
Номер ЕС (EINECS): 265-151-9
ЕС индекс: 601-007-00-7
Content: >= 50 % <= 100 %
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Классификация
Regulation (CE) nº 1272/2008.
Flam. Liq. 2
Asp. Tox. 1
Высокая токсичность Inhalation cat. 4
Skin Irrit. 2
Aquatic Chronic 2
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Hazard
Pictograms
|
Signal
word
Danger
|
Hazard statements
H225 Легко воспламеняем жидкость
и vapour.
H304 May be fatal При попадании внутрь
и enters airways.
H336 May cause drowsiness или
dizziness.
H315 Causes skin irritation.
H411 Токсично до aquatic life
с long lasting effects.
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Precautionary statements
P210 Keep away from
heat/sparks/open flames/hot surfaces. Не курить.
P240 Ground/bond container и
receiving equipment.
P241 Use explosion-proof
electrical/ventilating/lighting/equipment.
P243 Take precautionary
measures against static discharge.
P242 Use only non-sparking
tools.
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
P280 Wear protective gloves,
protective clothing, Защита глаз или face protection.
P301+P310 При попадании внутрь: Immediately
call a POISON CENTER или doctor/physician.
P303+P361+P353 IF ON SKIN (или hair):
Remove/Take off immediately all contaminated clothing. Rinse skin с
вода/shower.
P352 Wash с plenty soap
и вода.
P331 Do NOT Вызвать рвоту.
P370+P378 В case fire: Use for
extinction.
P304+P340 IF INHALED: Remove victim
до fresh air и keep при rest в a position comfortable for breathing.
P312 Call a POISON CENTER или
doctor/physician if you feel unwell.
P273 Avoid release до the
environment.
P391 Collect spillage.
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Классификация
(67/548/CEE или 1999/45/CE).
F Легко воспламеняем
Xn Вредный
Xi Irritant
N Dangerous for the
environment
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R11 Highly
воспламеняем.
R65 Вредный:
may cause lung damage При попадании внутрь.
R38 Irritating
до skin.
R51/53 Токсично
до aquatic organisms, may cause long-term adverse effects в the aquatic
environment.
R67 Vapours
may cause drowsiness и dizziness.
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4. Первая помощь measures
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4.1 General
indications:
Never provide drink или Вызвать рвоту в
the event loss consciousness.
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4.2 Вдыхание:
Переместить пострадавшего на свежий воздух. В the event
suffocation, proceed до provide artificial respiration.
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4.3 Contact
с the skin:
Wash с plenty soap и вода. Remove
contaminated clothing.
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4.4 Глаза:
Промыть большим количеством воды, keeping eyelids
open. Обратиться за медицинской помощью.
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4.5 Попадание Внутрь:
Do not Вызвать рвоту. Риск aspiration. Call for medical help. Administer Вазелинов. Масло
как a laxative (3 ml/kg). Administer a раствор medical-usage
активн. уголь. Avoid stomach lavage.
· Information
for doctor:
· Most
важно symptoms и effects, both acute и delayed: No further
relevant information available.
· Indication
any immediate medical attention и special treatment needed:
No further relevant information available.
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5. Firefighting measures
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5.1 Suitable
extinguishing среда:
Углекислый газ (CO2). Smother с безводн. earth или
sand. Песок.
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5.2 Unsuitable
extinguishing среда:
Вода.
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5.3 Special
hazards arising from the соединен. или mixture:
Воспламеняем. Keep away from sources
ignition. The fumes are heavier than air, so they may
spreaD при floor level. Auf Rückzündung achten
В случае возгорания могут образовываться токсичные пары.
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5.4 Advice
for firefighters:
Средства индивидуальной защиты дыхательных путей. Use complete protective
equipment. Cool the recipients с водой.
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6. Accidental release measures
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6.1 Personal
precautions, Средства индивидуальной защиты и emergency procedures:
Не вдыхать пары. Use personal protective
equipment как required. Avoid Контакт с кожей, глаза или
clothing. Avoid sources ignition. Do not smoke. Ensure good ventilation
и renewal the air в the premises.
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6.2 Environmental
precautions:
Do not allow it до enter the drainage
system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.
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6.3 Methods
и material for containment и cleaning up:
Collect up с absorbent materials
(Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand
или earth, и deposit в waste containers for
subsequent elimination в соответствии с законодательством. Clean any remains с
plenty вода.
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7. Правила обращения и хранения
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7.1 Precautions for safe обращение:
Avoid the formation electrostatic
charges. Avoid breathing dust, fume, gas, mist,
vapours или spray. Ensure good ventilation и renewal the
air в the premises. Handle с caution. Handle under an extractor
fan.
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7.2 Conditions for safe хранение, including any
incompatibilities:
В запечатанных контейнерах. В a cool, безводн., well ventilated place. Вдали от источников возгорания и тепла. Away from light. Не хранить в пластиковых контейнерах.
Recommended
хранение temperature: Room temperature.
·
Хранение class: 3
Technical
instructions (air): Легко воспламеняем.
7.3
Specific end use(s):
No further relevant information available.
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8. Exposure controls/personal protection
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8.1 Exposure
controls:
Ensure good ventilation и renewal the
air в the premises.
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8.2 Control parameters:
PELn-пентан: 1.000 ppm = 3.000 мг/м3
Derived
No Effect Level (DNEL)
iso-пентан
Population, oral, long term (systemic):
1301mg/kg bw/24h
Population, Dermal, long exposure
(systemic): 1377mg/kg bw/24h
Workers Dermal, long exposure (systemic):
13964mg/kg bw/24h
Population Inhalation, long term (systemic): 1.131 мг/м3
Workers Inhalation, long term (systemic): 5.306 мг/м3
н-пентан
Population, oral, long term (systemic):
214mg/kg bw/24h
Population, Dermal, long exposure
(systemic): 214mg/kg bw/24h
Workers Dermal, long exposure (systemic):
432mg/kg bw/24h
Population Inhalation, long term (systemic): 643 мг/м3
Workers Inhalation, long term (systemic): 3.000 мг/м3
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8.3 Защита органов дыхания:
В the event fumes forming/aerosols, use
suitable Защита органов дыхания. Фильтр AX.
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8.4 Защита рук:
Использовать защитные перчатки The glove material has до
be impermeable и resistant до the product/ the соединен./ the preparation.
Selection the glove material on
consideration the penetration times, rates diffusion и the
degradation
· Material gloves
The selection the suitable gloves does
not only depend on the material, but also on further marks quality и
varies from manufacturer до manufacturer.
· Penetration time glove material
The exact break through time has до be
found out by the manufacturer the protective gloves и has до be
observed.
· For
the permanent contact gloves made the following materials are suitable:
Material: Nitrile резина, NBR Recommended thickness
the material: >= 0,4 mm Breakthrough time: >= 480 min.
· Как
protection from splashes gloves made the following materials are suitable:
Material: Nitrile резина, NBR Recommended thickness
the material: >= 0,11 mm Breakthrough time: >= 30 min
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8.5 Eye/face protection:
Use safety glasses.
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8.6 Индивидуальные средства гигиены:
Избавиться от загрязненной одежды. Use suitable work
clothing. Wash hands before breaks и when the job
is done.
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8.7 Контроль воздействия на окружающую среду:
Avoid pollution the soil, вода supplies
и drains.
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9. Physical и chemical
properties
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Внешний Вид: жидкость
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Цвета: Бесцветная
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Granulometry: N/A
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Запах: Характерный.
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pH:
N/A
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точка плавления/Температура замерзания: N/A
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Initial Точка кипения и Интервал температур кипения: 40 - 60 °C
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Точка воспламенения: - 21 °C
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Flammability (solid, gas):
N/A
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Верхний/нижний flammability или explosive
показатели: 7 %(V) / 1 %(V)
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Давление пара: 350 hPa
(20 °C)
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Vapour плотность: N/A
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Relative плотность:
Insertar Aquí Grupo de
repeticion
0,65 g/ml (15 °C)
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Растворимость: в (
)Не Растворяется в воде
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Partition coefficient: n-октанол/вода:
N/A
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Auto-ignition temperature: 245 °C
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Decomposition temperature: N/A
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Кинематич. вязк.: N/A
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Динамич. вязк.: 0,25 mPa.s (25 °C)
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10. Стабильность и реакционноспособность
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10.1 Conditions
до avoid:
Высокий temperatures.
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10.2 Incompatible
materials:
Strong Окислители.
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10.3 Hazardous
decomposition products:
No specific data.
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10.4 Chemical
stability:
The gases/fumes can form explosive mixtures
с the air.
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11. Токсикологическая информация
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11.1
Acute
toxicity:
LD50 oral rat : 2.000 мг/кг iso-пентан
LD50 oral rat : > 2.000 мг/кг н-пентан
LD50 skn rbt : 4.000 мг/кг iso-пентан
LC50 inh rat : 54 mg/l
iso-пентан 4h
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11.2
Dangerous
effects for health:
Skin
corrosion/irritation: Irritations до the skin и mucosae. Serious eye damage/irritation: Not irritant. Respiratory или skin sensitisation: No evidence. Germ кювета mutagenicity: Нет данных. Carcinogenicity: Нет данных. Reproductive toxicity: Нет данных. STOT- single exposure: Нет данных. STOT-repeated exposure: Нет данных. Aspiration hazard: Нет данных.
·Most
важно symptoms и effects acute: Upon contact с the
skin: Irritations до the skin и mucosae.
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12. Информация по окружающей среде
|
12.1 Toxicity:
May cause long-term adverse effects в the
aquatic environment.
Possibly токсично for рыбы и plankton.
|
12.2 Persistence и
Период Распада :
Нет данных.
|
12.3 Bioaccumulative
potential:
Нет данных.
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12.4 Мобильность в soil :
Нет данных.
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12.5 Assessment PBT и MPMB :
в соответствии с Annex XIII Regulation (EC)
No. 1907/2006 concerning the Registration, Evaluation, Authorisation и
Restriction Chemicals (REACH): Does not meet the criteria for PBT
(persistent / bioaccumulative / токсично).
в соответствии с Annex XIII Regulation (EC)
No. 1907/2006 concerning the Registration, Evaluation, Authorisation и
Restriction Chemicals (REACH): Does not meet the criteria vPvB (very
persistent / very bioaccumulative).
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12.6 Др. adverse effects:
Do not allow it до enter soils или вода
channels.
Вода-Продукт загрязнения.
12.7
General notes:
· Вода
hazard class:
(German
Regulation) (Assessment by list):
2
опасная доза for вода.
(Dutch
Regulation):
6
Токсично до aquatic organisms, may cause long-term adverse effects в the
aquatic environment.
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|
13. Disposal considerations
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13.1 Waste treatment methods:
В the Европейск. Union, there are no homogeneous
standards established for elimination chemical waste, which is waste a
special nature, и treatment и elimination same is subject до the
domestic legislation в each country.
В view this, в each case, you should
contact the competent authority или those companies legally authorized for
elimination waste.
2001/573/EC: Council Decision 23 July 2001
amending Commission Decision 2000/532/EC как regards the list
wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive
75/442/EEC on waste.
.
|
13.2 Загрязненные контейнеры:
Загрязненные контейнеры и packaging
dangerous соединения или preparations must be treated в the same manner как
the actual products contained в them.
Европейск. Parliament и Council Directive
94/62/EC 20 December 1994 on packaging и packaging waste.
.
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14. Transport information
|
Автотранспорт (ADR):
Техническое название:
PETROLEUM
DISTILLATES, N.O.S.
UN 1268 Класс:
3 PELIG.MED.AMB. CONTAM.MAR Группа:
II
(D/E)
|
Морской транспорт (IMDG):
Техническое название:
PETROLEUM
DISTILLATES, N.O.S.
UN 1268 Класс:
3 PELIG.MED.AMB. CONTAM.MAR Группа:
II
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Авиа транспорт (ICAI-IATA):
Техническое название:
Петролейн.
distillates, n.o.s.
UN 1268 Класс:
3 PELIG.MED.AMB. CONTAM.MAR Группа:
II
|
Инструкция по упаковке: CAO 364 PAX 353
|
15. Regulatory information
|
Categorized как hydrocarbon соединен..
For this product a chemical safety
assessment was not carried out.
|
|
16. Дополнительная информация
|
Др. precautionary
statements
P501 Выбросить
contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.
|
Labelling
(65/548/CEE или 1999/45/CE)
|
R-phrase(s):
|
R11 Highly
воспламеняем.
R38 Irritating
до skin.
R51/53 Токсично
до aquatic organisms, may cause long-term adverse effects в the aquatic
environment.
R65 Вредный:
may cause lung damage При попадании внутрь.
R67 Vapours
may cause drowsiness и dizziness.
|
S-phrase(s):
|
S9 Keep
container в a well-ventilated place.
S16 Keep
away from sources ignition - Не курить.
S33 Take
precautionary measures against static discharges.
S43h В
case fire, use sand, Углекислый газ или безводн. chemical порошок. Never use
вода.
S62 If
swallowed, do not Вызвать рвоту: seek medical advice immediately и show
this container или label.
S23 Do
not breathe gas/fumes/vapour/spray (appropriate wording до be specified by
the manufacturer).
S24 Avoid
contact с skin.
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|
|
Version и revision date : 6 07.10.2013
Remplaced: 22.05.2012
В respect the previous review, changes
have been made до the following sections: 2,4,5,6,7,8,10,11,12,15
The information included в this Safety
Data Sheet is based on our most up-до-date knowledge, и is solely intended
до inform regarding aspects safety; the properties и characteristics
indicated herein are not guaranteed.
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