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Version and revision date :  6 07.10.2013.         Remplaced:  10.04.2013.        

 

 

S a f e t y     D a t a     S h e e t

According to Regulation (EC) 1907/2006

 

1090  2-Propanol 

 

1.      Identification of the substance/mixture and of the company/undertaking

1.1  Product identifier

Name:

2-Propanol

 

Synonym:

Dimethylcarbinol, IPA, Isopropanol, iso-Propyl Alcohol, sec-Propyl Alcohol

 

CAS: [67-63-0]

 

REACH Registration Number: 01-2119457558-25-XXXX

 

1.2  Relevant identified uses of the substance or mixture:

 

Raw material for photochemical products.

Raw materials for detergents and disinfectants.

Solvent.

Industrial.

Use as chemical process.

 

1.3  Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Identification of dangers

2.1  Classification of the substance or the mixture.

 

 

 

Classification Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

 

 

Classification (67/548/CEE or 1999/45/CE).

 

F   Highly flammable

Xi   Irritant

 

R11

R36

R67

 

2.2  Label elements:

 

Hazard Pictograms

 

 

Signal word

 Danger

    

 

  Hazard statements

H225  Highly flammable liquid and vapour.

H319  Causes serious eye irritation.

H336  May cause drowsiness or dizziness.

 

 

  Precautionary statements

P243  Take precautionary measures against static discharge.

P261  Avoid breathing dust, fume, gas, mist, vapours or spray.

P271  Use only outdoors or in a well-ventilated area.

P303+P361+P353  IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340  IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

 

 

 

 

For the full text of the R-phrases mentioned in this section, see section 16.

2.3  Other hazards:

 

No further relevant information available.

 

 

3. 

Version и revision date :  6 07.10.2013.         Remplaced:  10.04.2013.        

 

 

S a f e t y     D a t a     S h e e t

в соответствии с Regulation (EC) 1907/2006

 

1090  2-Пропанол 

 

1.      Определение the соединен./mixture и the company/undertaking

1.1  Product identifier

Название:

2-Пропанол

 

Synonym:

Dimethylcarbinol, IPA, Isopropanol, iso-Propyl Спирт, sec-Propyl Спирт

 

CAS: [67-63-0]

 

REACH Registration Number: 01-2119457558-25-XXXX

 

1.2  Relevant identified uses вещества или mixture:

 

Raw material for photochemical products.

Raw materials for detergents и disinfectants.

Растворитель.

Industrial.

Use как chemical process.

 

1.3  Определение the company или firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Виды опасного воздействия

2.1  Классификация вещества или the mixture.

 

 

 

Классификация Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

 

 

Классификация (67/548/CEE или 1999/45/CE).

 

F   Легко воспламеняем

Xi   Irritant

 

R11

R36

R67

 

2.2  Label элементы:

 

Hazard Pictograms

 

 

Signal word

 Danger

    

 

  Hazard statements

H225  Легко воспламеняем жидкость и vapour.

H319  Causes serious eye irritation.

H336  May cause drowsiness или dizziness.

 

 

  Precautionary statements

P243  Take precautionary measures against static discharge.

P261  Avoid breathing dust, fume, gas, mist, vapours или spray.

P271  Use only outdoors или в a well-ventilated area.

P303+P361+P353  IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с вода/shower.

P304+P340  IF INHALED: Remove victim до fresh air и keep при rest в a position comfortable for breathing.

P305+P351+P338  IF IN EYES: Rinse cautiously с водой for several minutes. Remove contact lenses, if present и easy до do. Continue rinsing.

 

 

 

 

For the full text the R-выражения mentioned в this section, see section 16.

2.3  Др. hazards:

 

No further relevant information available.

 

 

3.       Состав/information on ingredients

 

 

Название: 2-Пропанол

Формула: CH3CHOHCH3        M.=  60,10    CAS [67-63-0]

Номер ЕС (EINECS): 200-661-7

ЕС индекс: 603-117-00-0

REACH Registration Number: 01-2119457558-25-XXXX

 

 

4.       Первая помощь measures

 

4.1  General indications:

Never provide drink или Вызвать рвоту в the event loss consciousness. Remove contaminated clothing.

 

4.2  Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed immediately до provide artificial respiration. Seek immediate medical assistance.

 

4.3  Contact с the skin:

Промыть большим количеством воды. Remove contaminated clothing.

 

4.4  Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.

 

4.5  Попадание Внутрь:

Выпить большое количество воды. Do not Вызвать рвоту. Call for medical help.

· Information for doctor:

· Most важно symptoms и effects, both acute и delayed: No further relevant information available.

· Indication any immediate medical attention и special treatment needed:

No further relevant information available.

 

5.      Firefighting measures

 

5.1  Suitable extinguishing среда:

Atomized вода. Углекислый газ (CO2). Спирт resistant пена. Песок.

 

5.2  Unsuitable extinguishing среда:

Running вода.   

 

5.3  Special hazards arising from the соединен. или mixture:

Воспламеняем. Keep away from sources ignition.  Auf Rückzündung achten  В the event fire, токсично fumes may form: CO y CO2. 

 

5.4  Advice for firefighters:

Use complete Средства индивидуальной защиты. Self-contained breathing equipment. Cool the recipients с водой.

 

6.       Accidental release measures

 

6.1  Personal precautions, Средства индивидуальной защиты и emergency procedures:

Не вдыхать пары. Ensure adequate ventilation. Avoid sources ignition. Do not smoke.

 

6.2  Environmental precautions:

Do not allow it до enter the drainage system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

 

6.3  Methods и material for containment и cleaning up:

Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода.

 

7.       Правила обращения и хранения

 

7.1 Precautions for safe обращение:

Ensure good ventilation и renewal the air в the premises. The fumes are heavier than air, so they may spreaD при floor level. Avoid the formation electrostatic charges. The gases/fumes can form explosive mixtures с the air.

 

7.2 Conditions for safe хранение, including any incompatibilities:

В запечатанных контейнерах. В a cool, безводн. place, away from light и well ventilated. Away from sources ignition и heat.

Recommended хранение temperature: Room temperature.

· Хранение class: 3

Technical instructions (air): Легко воспламеняем.

7.3 Specific end use(s):

No further relevant information available.

 

8.       Exposure controls/personal protection

 

8.1  Exposure controls:

Ensure good ventilation и renewal the air в the premises.

 

8.2 Control parameters:

VLA-ED: 200 ppm = 500 мг/м3 

VLA-EC(Spain): 400 ppm = 1.000 мг/м3 

 

Derived No Effect Level (DNEL)

  

Workers Dermal, long exposure (systemic):   888mg/kg

Workers Inhalation, long term (systemic): 500 мг/м3 

Population, Dermal, long exposure (systemic):   319mg/kg

Population Inhalation, long term (systemic): 89 мг/м3 

Population, oral, long term (systemic):   26mg/kg

 

Predicted No Effect Концентрация (PNEC)

  

Freshwater:   140,9mg/l

Marine вода:   140,9mg/l

Freshwater Sediment:   552mg/kg

Marine вода Sediment:   552mg/kg

Soil:   28mg/kg

 

 

 

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A. Фильтр P2. Фильтр ABEK-P2. (в соответствии с EN-141)

 

8.4 Защита рук:

The glove material has до be impermeable и resistant до the product/ the соединен./ the preparation.

Selection the glove material on consideration the penetration times, rates diffusion и the degradation

· Material gloves

The selection the suitable gloves does not only depend on the material, but also on further marks quality и varies from manufacturer до manufacturer.

· Penetration time glove material

The exact break through time has до be found out by the manufacturer the protective gloves и has до be

observed.

· For the permanent contact gloves made the following materials are suitable:

Material: Nitrile резина, NBR. Breakthrough time: >= 480 min. Recommended thickness the material: >= 0,35 mm Butyl резина. Breakthrough time: >= 480 min. Recommended thickness the material: >= 0,5 mm

· Как protection from splashes gloves made the following materials are suitable:

Material: Polychloroprene. Breakthrough time: >= 480 min. Recommended thickness the material: >= 0,5 mm

Inadequate material: PVC Natural резина latex.

 

8.5 Eye/face protection:

Use safety glasses.

 

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use suitable work clothing. Wash hands и face before breaks и when the job is done.

 

8.7 Контроль воздействия на окружающую среду:

Avoid pollution the soil, вода supplies и drains.

 

9.      Physical и chemical properties

 

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH:  

N/A

точка плавления/Температура замерзания: -88,5 °C

Initial Точка кипения и Интервал температур кипения: 82,5 °C 

Точка воспламенения:  11,7 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 12 %(V) / 2 %(V)

Давление пара: 43 hPa  (20 °C)

Vapour плотность: N/A

Relative плотность:

 

Insertar Aquí Grupo de repeticion

 

 (20/20) 0,785 g/ml

Растворимость:    Смешивается с водой, спирт, эфир и трихлорметан.

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:  425 °C

Decomposition temperature:  N/A

Кинематич. вязк.:  N/A

Динамич. вязк.: 2,27 mPa.s (20 °C)

10.  Стабильность и реакционноспособность

 

10.1  Conditions до avoid: 

Adjacent sources heat и temperatures над 35 °C Direct sunlight.  

 

10.2   Incompatible materials:

Щелочных металлы. Железо. Алюминий. Strong Окислители. Сильные кислоты. Амины.

 

10.3  Hazardous decomposition products:

 No specific data.

 

10.4  Chemical stability:

The gases/fumes can form explosive mixtures с the air. 

 

11.  Токсикологическая информация

 

11.1          Acute toxicity:

LD50 oral rat  : > 2.000 мг/кг      

LD50 skn rbt  : > 2.000 мг/кг     

LC50 inh rat  : >20 mg/l      8h

 

11.2          Dangerous effects for health:

Skin corrosion/irritation: Not irritant. Serious eye damage/irritation: Strongly irritant в rabbits. Respiratory или skin sensitisation: No evidence. Germ кювета mutagenicity: The results тест are negative.

 

12.  Информация по окружающей среде

 

12.1  Toxicity:

Algae (Scenedesmus sp) EC50 >100 mg/l (72h)

Crustaceans (Daphnia magna) EC50 >100 mg/l (48h)

Рыбы (Leuciscus Idus) LC50 >100 mg/l (48h)

 

12.2  Persistence и Период Распада :

Легко biodegradable product.

 

12.3  Bioaccumulative potential:

log Pow = <4

Non-bioaccumulable product.

 

12.4  Мобильность в soil :

Нет данных.

 

12.5 Assessment PBT и MPMB :

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria for PBT (persistent / bioaccumulative / токсично).

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria vPvB (very persistent / very bioaccumulative).

 

 

12.6  Др. adverse effects:

If suitable обращение conditions are maintained, no ecological problems are до be anticipated.

 

12.7 General notes:

 

· Вода hazard class:

 

(German Regulation) (Assessment by list):

1  слабо опасная доза for вода.

 

(Dutch Regulation):

10 May cause long-term adverse effects в the aquatic environment.

 

 

13. Disposal considerations

 

13.1  Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

 В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste.

.

 

13.2  Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste.

.

 

14.  Transport information

 

Автотранспорт (ADR):

Техническое название: ISOPROPANOL (ISOPROPYL ALCOHOL)

UN   1219       Класс: 3      Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: ISOPROPANOL (ISOPROPYL ALCOHOL)

UN   1219       Класс: 3      Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Isopropanol

UN   1219       Класс: 3       Группа: II

Инструкция по упаковке:    CAO 364     PAX 353

15.  Regulatory information

 

For this product a chemical safety assessment was carried out.

 

 

16.  Дополнительная информация

 

  Др. precautionary statements

 

 

Labelling (65/548/CEE или 1999/45/CE)

 

R-phrase(s):

R11   Highly воспламеняем.

R36   Irritating до глаза.

R67   Vapours may cause drowsiness и dizziness.

 

S-phrase(s):

S7   Keep container tightly closed.

S16   Keep away from sources ignition - Не курить.

S24/25   Avoid contact с skin и глаза.

S26   В case contact с глаза, rinse immediately с plenty вода и seek medical advice.

 

 

Version и revision date : 6 07.10.2013

Remplaced: 10.04.2013

В respect the previous review, changes have been made до the following sections: 1,4,5,6,7,8,10,11,12,15

The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed.