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Version and revision date :  6 07.10.2013.         Remplaced:  26.04.2013.        

 

 

S a f e t y     D a t a     S h e e t

According to Regulation (EC) 1907/2006

 

1250  Cyclohexane 

 

1.      Identification of the substance/mixture and of the company/undertaking

1.1  Product identifier

Name:

Cyclohexane

 

Synonym:

Hexahydrobenzene, Hexamethylene, Hexanaphtene

 

CAS: [110-82-7]

 

REACH Registration Number: 01-2119463273-41-XXXX

 

1.2  Relevant identified uses of the substance or mixture:

 

Manufacture

Distribution of Substance.

Formulation

Use as laboratory chemicals.

 

1.3  Identification of the company or firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Identification of dangers

2.1  Classification of the substance or the mixture.

 

 

 

Classification Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Skin Irrit. 2

Asp. Tox. 1

STOT SE 3

Aquatic Acute 1

Aquatic Chronic 1

 

 

Classification (67/548/CEE or 1999/45/CE).

 

F   Highly flammable

Xn   Harmful

N   Dangerous for the environment

 

R11

R38

R65

R67

R50/53

 

2.2  Label elements:

 

Hazard Pictograms

 

 

Signal word

 Danger

        

 

  Hazard statements

H225  Highly flammable liquid and vapour.

H315  Causes skin irritation.

H304  May be fatal if swallowed and enters airways.

H336  May cause drowsiness or dizziness.

H410  Very toxic to aquatic life with long lasting effects.

H400  Very toxic to aquatic life.

 

 

  Precautionary statements

P210  Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P243  Take precautionary measures against static discharge.

P280  Wear protective gloves, protective clothing, eye protection or face protection.

P301+P310  IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331  Do NOT induce vomiting.

P303+P361+P353  IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

 

 

 

 

For the full text of the R-phrases mentioned in this section, see section 16.

2.3  Other hazards:

 

No further relevant information available.

 

 

3.       Composition/information on ingredients

 

 

Name: Cyclohexane

Formula: C6H12Version и revision date :  6 07.10.2013.         Remplaced:  26.04.2013.        

 

 

S a f e t y     D a t a     S h e e t

в соответствии с Regulation (EC) 1907/2006

 

1250  Циклогексан 

 

1.      Определение the соединен./mixture и the company/undertaking

1.1  Product identifier

Название:

Циклогексан

 

Synonym:

Hexahydrobenzene, Hexamethylene, Hexanaphtene

 

CAS: [110-82-7]

 

REACH Registration Number: 01-2119463273-41-XXXX

 

1.2  Relevant identified uses вещества или mixture:

 

Manufacture

Distribution Соединен..

Formulation

Use как laboratory chemicals.

 

1.3  Определение the company или firm:

PANREAC QUIMICA S.L.U.

C/Garraf 2

Polígono Pla de la Bruguera

E-08211 Castellar del Vallès

(Barcelona)  Spain

Tel. (+34) 937 489 400

e-mail: product.safety@panreac.com

 

1.4  Emergency telephone:

Single telephone number for emergency calls: 112 (EU)

Tel.: (+34) 937 489 499

 

2.    Виды опасного воздействия

2.1  Классификация вещества или the mixture.

 

 

 

Классификация Regulation (CE) nº 1272/2008.

 

Flam. Liq. 2

Skin Irrit. 2

Asp. Tox. 1

STOT SE 3

Aquatic Acute 1

Aquatic Chronic 1

 

 

Классификация (67/548/CEE или 1999/45/CE).

 

F   Легко воспламеняем

Xn   Вредный

N   Dangerous for the environment

 

R11

R38

R65

R67

R50/53

 

2.2  Label элементы:

 

Hazard Pictograms

 

 

Signal word

 Danger

        

 

  Hazard statements

H225  Легко воспламеняем жидкость и vapour.

H315  Causes skin irritation.

H304  May be fatal При попадании внутрь и enters airways.

H336  May cause drowsiness или dizziness.

H410  Очень токсично до aquatic life с long lasting effects.

H400  Очень токсично до aquatic life.

 

 

  Precautionary statements

P210  Keep away from heat/sparks/open flames/hot surfaces. Не курить.

P243  Take precautionary measures against static discharge.

P280  Wear protective gloves, protective clothing, Защита глаз или face protection.

P301+P310  При попадании внутрь: Immediately call a POISON CENTER или doctor/physician.

P331  Do NOT Вызвать рвоту.

P303+P361+P353  IF ON SKIN (или hair): Remove/Take off immediately all contaminated clothing. Rinse skin с вода/shower.

 

 

 

 

For the full text the R-выражения mentioned в this section, see section 16.

2.3  Др. hazards:

 

No further relevant information available.

 

 

3.       Состав/information on ingredients

 

 

Название: Циклогексан

Формула: C6H12        M.=  84,16    CAS [110-82-7]

Номер ЕС (EINECS): 203-806-2

ЕС индекс: 601-017-00-1

REACH Registration Number: 01-2119463273-41-XXXX

 

 

4.       Первая помощь measures

 

4.1  General indications:

Never provide drink или Вызвать рвоту в the event loss consciousness.

 

4.2  Вдыхание:

Переместить пострадавшего на свежий воздух. В the event suffocation, proceed immediately до provide artificial respiration. Seek immediate medical assistance.

 

4.3  Contact с the skin:

Wash с plenty soap и вода. Remove contaminated clothing.

 

4.4  Глаза:

Промыть большим количеством воды (не менее 15 minutes), Веки постоянно держать открытыми. Обратиться за медицинской помощью.

 

4.5  Попадание Внутрь:

Обратиться немедленно за медицинской помощью. Wash mouth out immediately. Precaution в the event рвота (there is a риск aspiration). Keep respiratory tracts прозрачная.

· Most важно symptoms и effects, both acute и delayed:

See Section 11 for more information.

· Indication any immediate medical attention и special treatment needed:

No further relevant information available.

 

5.      Firefighting measures

 

5.1  Suitable extinguishing среда:

Углекислый газ (CO2). Спирт resistant пена. Песок.

 

5.2  Unsuitable extinguishing среда:

Running вода.  

 

5.3  Special hazards arising from the соединен. или mixture:

Горючее Вещество. Keep away from sources ignition.  The fumes are heavier than air, so they may spreaD при floor level.  Auf Rückzündung achten  В случае возгорания могут образовываться токсичные пары: CO y CO2.  Precipitate fumes formed с водой. 

 

5.4  Advice for firefighters:

Use complete Средства индивидуальной защиты. Self-contained breathing equipment. Cool the recipients с водой.

 

6.       Accidental release measures

 

6.1  Personal precautions, Средства индивидуальной защиты и emergency procedures:

Не вдыхать пары. Use personal protective equipment как required. Avoid sources ignition. Do not smoke. Avoid contact с the skin, глаза или clothing. Обеспечить хорошую вентиляцию

 

6.2  Environmental precautions:

Do not allow it до enter the drainage system. Избегайте загрязнения почвы, систем водоснабжения и дренажа.

 

6.3  Methods и material for containment и cleaning up:

Collect up с absorbent materials (Panreac абсорбент общего назначения, Kieselguhr, etc.) или, if none available, безводн. sand или earth, и deposit в waste containers for subsequent elimination в соответствии с законодательством. Clean any remains с plenty вода.

 

7.       Правила обращения и хранения

 

7.1 Precautions for safe обращение:

Avoid the formation electrostatic charges. Ensure good ventilation и renewal the air в the premises. Avoid breathing dust, fume, gas, mist, vapours или spray. Avoid Контакт с кожей, глаза или clothing. Use personal Средства индивидуальной защиты как required.

 

7.2 Conditions for safe хранение, including any incompatibilities:

Вдали от источников возгорания и тепла. Не хранить в пластиковых контейнерах.

Recommended хранение temperature: Room temperature.

· Хранение class: 3

Technical instructions (air): Легко воспламеняем.

7.3 Specific end use(s):

No further relevant information available.

 

8.       Exposure controls/personal protection

 

8.1  Exposure controls:

Ensure good ventilation и renewal the air в the premises.

 

8.2 Control parameters:

 

 

 

8.3 Защита органов дыхания:

В the event fumes forming/aerosols, use suitable Защита органов дыхания. Фильтр A.

 

8.4 Защита рук:

The glove material has до be impermeable и resistant до the product/ the соединен./ the preparation.

Selection the glove material on consideration the penetration times, rates diffusion и the degradation

· Material gloves

The selection the suitable gloves does not only depend on the material, but also on further marks quality и varies from manufacturer до manufacturer.

· Penetration time glove material

The exact break through time has до be found out by the manufacturer the protective gloves и has до be

observed.

· For the permanent contact gloves made the following materials are suitable:

Material: Nitrile резина, NBR. Recommended thickness the material: >= 0,4 mm Breakthrough time: >= 480 min.

· Как protection from splashes gloves made the following materials are suitable:

Material: Nitrile резина, NBR. Recommended thickness the material: >= 0,11 mm Breakthrough time: >= 30 min

 

8.5 Eye/face protection:

Use safety glasses.

 

8.6 Индивидуальные средства гигиены:

Избавиться от загрязненной одежды. Use suitable work clothing. Wash hands и face before breaks и when the job is done.

 

8.7 Контроль воздействия на окружающую среду:

Avoid pollution the soil, вода supplies и drains.

 

9.      Physical и chemical properties

 

Внешний Вид: жидкость

Цвета: Бесцветная

Granulometry: N/A

Запах: Характерный.

pH:  

N/A

точка плавления/Температура замерзания: 6,47 °C

Initial Точка кипения и Интервал температур кипения: 80,7 °C 

Точка воспламенения:  - 18 °C

Flammability (solid, gas):

N/A

Верхний/нижний flammability или explosive показатели: 8,3 %(V) / 1,2 %(V)

Давление пара: 104 hPa  (20 °C)

Vapour плотность: N/A

Relative плотность:

 

Insertar Aquí Grupo de repeticion

 

 (20/4) 0,7781 g/ml

Растворимость: 0,05 г/л  ( 20 °C  )

Partition coefficient: n-октанол/вода:

N/A

Auto-ignition temperature:  260 °C

Decomposition temperature:  N/A

Кинематич. вязк.:  N/A

Динамич. вязк.: 0,94 mPa.s (20 °C)

10.  Стабильность и реакционноспособность

 

10.1  Conditions до avoid: 

Высокий temperatures.   Direct sunlight.   Humidity.  

 

10.2   Incompatible materials:

Strong Окислители.

 

10.3  Hazardous decomposition products:

 Моноксид углерода.

 

10.4  Chemical stability:

The product is chemically stable under standar ambient conditions (room temperature). 

 

11.  Токсикологическая информация

 

11.1          Acute toxicity:

LD50 oral rat  :  12.705 мг/кг      

LD50 skn rbt  : > 2.000 мг/кг     

LC50 inh rat  :   32880 мг/м3   4h

 

11.2          Dangerous effects for health:

If fumes inhaled: Irritations до the skin, глаза, mucosae и respiratory tracts. kidney problems, hepatic problems, effects on the central nervous system, headaches, vertigo, tiredness, drowsiness В высокий concentrations: loss consciousness, затруднение дыхания, death Контакт с глазами: irritations, blindness (irreversible injury the optic nerve) Upon contact с the skin: irritations Can de-moisturize и dehydrate it, producing irritation и dermatitis. При попадании внутрь: Irritations the mucosae в the mouth, throat, oesophagus и intestinal tract., stomach pains, drowsiness, тошнота, рвота, diarrhoea Риск aspiration upon рвота. Carcinogenicity: No evidence. Germ кювета mutagenicity: No evidence. Reproductive toxicity: Conclusions are lacking regarding evaluation a damaging effect on the foetus., Not classified как токсично for reproduction.

 

12.  Информация по окружающей среде

 

12.1  Toxicity:

Acute toxicity for рыбы: 

LC50  4,5 mg/l (96h) (OECD 203)

Acute toxicity for aquatic invertebrates: 

EC50 (Daphnia magna) 0,90 mg/l (48h) (OECD 202)

Acute toxicity for Algae: 

EC50  3,4 mg/l (72h) (OECD 201)

 

12.2  Persistence и Период Распада :

COD 3421 mg/g

Биоразложение > 70% (28d)

Легко biodegradable product.

 

12.3  Bioaccumulative potential:

log Pow = 3,44

BCF 167 (OECD 305)

Possibly bioaccumulable product.

 

12.4  Мобильность в soil :

Нет данных.

 

12.5 Assessment PBT и MPMB :

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria for PBT (persistent / bioaccumulative / токсично).

в соответствии с Annex XIII Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation и Restriction Chemicals (REACH): Does not meet the criteria vPvB (very persistent / very bioaccumulative).

 

 

12.6  Др. adverse effects:

Dangerous for drinking вода.

Do not allow it до enter soils или вода channels.

 

12.7 General notes:

 

· Вода hazard class:

 

(German Regulation) (Assessment by list):

2  опасная доза for вода.

 

(Dutch Regulation):

4  Очень токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

 

 

13. Disposal considerations

 

13.1  Waste treatment methods:

В the Европейск. Union, there are no homogeneous standards established for elimination chemical waste, which is waste a special nature, и treatment и elimination same is subject до the domestic legislation в each country.

 В view this, в each case, you should contact the competent authority или those companies legally authorized for elimination waste.

2001/573/EC: Council Decision 23 July 2001 amending Commission Decision 2000/532/EC как regards the list wastes.Council Directive 91/156/EEC 18 March 1991 amending Directive 75/442/EEC on waste.

.

 

13.2  Загрязненные контейнеры:

Загрязненные контейнеры и packaging dangerous соединения или preparations must be treated в the same manner как the actual products contained в them.

Европейск. Parliament и Council Directive 94/62/EC 20 December 1994 on packaging и packaging waste.

.

 

14.  Transport information

 

Автотранспорт (ADR):

Техническое название: CYCLOHEXANE

UN   1145       Класс: 3  PELIG.M.AMB      Группа: II (D/E)

Морской транспорт (IMDG):

Техническое название: CYCLOHEXANE

UN   1145       Класс: 3  PELIG.M.AMB      Группа: II

Авиа транспорт (ICAI-IATA):

Техническое название: Циклогексан

UN   1145       Класс: 3  PELIG.M.AMB       Группа: II

Инструкция по упаковке:    CAO 364     PAX 353

15.  Regulatory information

 

Categorized как hydrocarbon соединен..

For this product a chemical safety assessment was not carried out.

 

 

16.  Дополнительная информация

 

  Др. precautionary statements

P332+P313  If skin irritation occurs: Get medical advice/attention.

P273  Avoid release до the environment.

P391  Collect spillage.

P501  Выбросить contents/container в соответствии с Directive 94/62/CE или 2008/98/CE.

 

 

Labelling (65/548/CEE или 1999/45/CE)

 

R-phrase(s):

R11   Highly воспламеняем.

R38   Irritating до skin.

R65   Вредный: may cause lung damage При попадании внутрь.

R67   Vapours may cause drowsiness и dizziness.

R50/53   Very токсично до aquatic organisms, may cause long-term adverse effects в the aquatic environment.

 

S-phrase(s):

S9   Keep container в a well-ventilated place.

S16   Keep away from sources ignition - Не курить.

S25   Avoid contact с глаза.

S33   Take precautionary measures against static discharges.

S51   Use only в well-ventilated areas.

S60   This material и its container must be disposed как опасная доза waste.

S61   Avoid release до the environment. Refer до special instructions/safety data sheets.

S62   If swallowed, do not Вызвать рвоту: seek medical advice immediately и show this container или label.

 

 

Version и revision date : 6 07.10.2013

Remplaced: 26.04.2013

В respect the previous review, changes have been made до the following sections: 1,2,4,5,6,7,8,10,11,12,15

The information included в this Safety Data Sheet is based on our most up-до-date knowledge, и is solely intended до inform regarding aspects safety; the properties и characteristics indicated herein are not guaranteed.

 

 

 

 




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